松辽北部三肇地区泉四段高分辨率层序学研究

三肇凹陷扶余油层是松辽北部重点的油气勘探领域之一,主要为一套河流-浅水三角洲沉积,由于河道砂体单层厚度薄、侧向变化快,因此急需对该区开展精细的沉积微相研究,以指导后期地层-岩性油气藏勘探。以肇35区块为例,运用高分辨率层序地层学原理,结合岩心、录井、测井资料,识别层序界面特征,建立层序地层格架,并以短期基准面旋回为制图单元,编制高分辨率层序地层格架内的沉积微相展布图,阐明了其演化规律并建立沉积模式。研究表明：泉四段整体为一长期上升半旋回,内部分出7个短期基准面旋回(SSC1-SSC7),主要发育三角洲平原、前缘2种亚相,进一步分为(水下)分流河道、(水下)决口扇、天然堤等多种微相。7个短期旋回中,SSC1至SSC2基准面缓慢上升,发育上升为主的不完全对称旋回;SSC3至SSC4基准面迅速上升,发育对称旋回和上升为主的不完全对称旋回;SSC5至SSC7基准面上升至最高,发育上升为主的不完全对称旋回。沉积相展布受基准面升降变化控制明显,泉四段自下而上经历了三角洲平原-平原、前缘过渡-三角洲前缘,局部浅湖的演化过程,整体为一次水体由浅变深的湖侵过程。     

Changes in the Geometry and Volume of Rabots glaciär,Sweden, 2003–2011: Recent Accelerated Volume Loss Linked to More Negative Summer Balances

Terminus geometry, ice margins, and surface elevations on Rabots glaciär were measured using differential GPS during summer 2011 and compared with those similarly measured in 2003. Glacier length over the eight years decreased by ～105 m corresponding to 13 m a^?1, a rate consistent with ice recession over the last several decades. Measured changes in surface elevations show that between 2003 and 2011 the glacier's volume decreased by ～27.6 ± 2.6 × 10⁶ m³, or 3.5 ± 0.3 × 10⁶ m³ a^?1. This compares favorably with an estimate of ?28.1 ± 2.6 × 10⁶ m³ based on a mass‐balance approach. The rate of volume loss appears, however, to have significantly increased after 2003, being substantially greater than rates determined for the intervals 1959–80, 1980–89, and 1989–2003. This increase corresponds to a sustained interval of more negative summer balances. Previous work suggests that as of 2003 Rabots glaciär had not yet completed its response to a ～1°C warming that occurred c. 1900, and thus the current marked increase rate of ice loss might reflect the effect of recent, or accelerated regional warming that occurred during the last decade superimposed on its continued response to that earlier warming.     

黄土高原西部地区黄土地层有机质主要来源分析

黄土有机质的主要来源是决定其稳定碳同位素(δ 13 Corg.)能否应用于重建过去C3/C4相对丰度变化及相应的古气候变化的关键基础科学问题。如若黄土地层当中的有机质主要由粉尘携带而来, 而非当地植被, 显然其δ 13 Corg. 不是一个局地植被过去C3/C4相对丰度变化及古气候变化的良好指示器。本文对黄土高原西部地区(六盘山以西)新获得和已发表的相关数据进行综合分析, 尝试对该地区黄土有机质的主要来源进行定量的分析。结果表明, 总体而言, 该地区黄土地层有机质主要来源于当地植被, 由粉尘携带而来的有机质贡献量不超过8 %, 所造成的有机碳同位素变化幅度不超过1.7 ‰ 。这些结果说明该地区的黄土地层有机质δ 13 Corg. 是可以用来重建过去C3/C4植物相对丰度及相应的古气候变化的。为了更精确的重建, 后续的工作应当更多考虑粉尘搬运过程当中的有机质输入以及粉尘沉积之后的微生物活动的可能潜在影响。     

La3+ 离子掺杂钨酸铅单晶的微结构缺陷

钨酸铅晶体是一种非化学计量化合物,缺陷丰富,蕴含着利用掺杂产生新效应和开发新功能的广泛可能性。探讨了不同浓度La3 掺杂对于钨酸铅晶体发光性能的影响,如热释光、X射线激发发光、光致发光等。La3 掺杂有效地抑制了陷阱中心,使发光受到强烈的抑制,在高浓度掺杂的钨酸铅中,激发机制有所改变,通过XPS测试的结果分析了不同浓度La3 掺杂机制。低浓度掺杂中,La3 取代Pb2 ,形成缺陷复合体[2(La3Pb ).-(VPb)″];高浓度掺杂晶体中,La3 离子不但占据Pb2 位置,而且也会占据W6 位置(La3W ),产生La3 的自补偿机制,形成La3 的自补偿对[(La3W )-(La3Pb ).]-(VO)..或缺陷聚集体[3(LaP3b ).-(La3W )]。     

Heat capacity and phase equilibria of wadeite-type K2Si4O9

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

基于IAP AGCM4的欧亚大陆春季雪水当量可预报性评估

欧亚大陆积雪是重要的气候预测因子,评估其在气候模式中的预测潜力可为季节气候预测和模式发展提供重要参考。本文利用IAP AGCM4的多年集合后报结果,分析了欧亚大陆春季雪水当量的可预报性。结果表明该模式对提前1月后报的欧亚大陆春季雪水当量的空间分布,主要模态及变化趋势具有较好的可预报能力。此外模式对欧亚中高纬积雪的年际异常也具有较高的预报技巧,特别是高纬度区域。可预报性来源分析则表明,大气初始异常对欧亚中高纬积雪可预报性的影响与海温异常相比显得更为重要。     

Abiotic Methane Reservoirs in the Western Tianshan HP–UHP Metamorphic Belt,China

Natural gas, consisting primarily of methane(CH₄), has become a major source of clean energy in modern society in many parts of the globe. Recent experimental observations and discoveries of deep-sourced abiotic CH₄ in cold subduction zones indicate the important ability of cold subducted slabs to generate natural gas reservoirs. However, most CH₄ flux and reservoirs remain unknown and their potential is overlooked in global carbon flux estimations. Massive abiot...     

蓝色翡翠的呈色机制探讨

近期广东市场上出现了一种来自缅甸的蓝色翡翠样品,该样品目前未见相关报道。为了确定其定名,通过常规宝石学测试、红外光谱和X射线粉末衍射测试对样品进行分析,表明样品的主要矿物组成为硬玉,质量分数约97．1％,检测鉴定结论为翡翠。为了对蓝色翡翠呈色机制进行研究,通过紫外一可见吸收光谱测试,表明可见光区480nm以后逐渐增强的吸收带是其产生蓝色的原因;采用电子探针进行化学成分测试,表明蓝色的成因与钒离子有关。根据3d过渡金属离子的晶体场理论和翡翠晶体场理论的研究,可以推测：由于翡翠结构中M1位的Al3＋被过渡金属离子钒（V4＋）替代,目l起八面体结构畸变而导致蓝色的产生,因此,蓝色是过渡金属离子钒（v4＋）产生的原生色。     

福建地区流体对2007年4次4级地震映震特征分析

通过对2007年福建地区4次4级地震的震例分析, 认为福建地区流体对内陆中等地震具有如下映震特征: ① 地震前兆表现为不同测项在时间上呈有规律的层次发展且均以短临、 临震和短期异常为主; ② 模拟观测井孔的映震效能好于数字化观测井孔, 其中水氡、 水质是福建地区的特征灵敏组分; ③ 温泉井孔的映震效能好于普通井孔; ④ 异常台项数取决于震级和震中周围的观测点数目。 同时指出今后要根据区域特征, 有重点地加大映震灵敏井孔和灵敏组分的观测、 科学布网、 合理建点, 使各种前兆观测成场成网; 建立一批符合地震监测预报要求的高质量水观测点, 更有效地为地震分析预报服务。     

华北平原冬麦田土壤CH4的吸收特征研究

利用静态箱/气相色谱(GC)法,对华北平原冬小麦拔节—成熟期间麦田土壤CH4气体通量进行了测定,得出华北平原典型冬麦田土壤是大气CH4的弱吸收汇。试验期间土壤CH4通量存在明显的季节变化和日变化,麦田拔节—成熟期间土壤CH4通量日平均值为-18.3μg.m-2.h-1,波动范围为-4.3~-24.4μg.m-2.h-1;在土壤CH4通量的日变化中,观测到麦田土壤在午间和夜间都有一个吸收峰,峰值出现的时间因生育期不同而有所不同。试验期间CH4通量日平均值与土壤温度关系不明显,而与土壤水分呈负相关(α=0.01);日变化中土壤CH4通量与地表温度的相关性较差,而与5 cm地温相关密切。麦田拔节—成熟期间土壤CH4通量日平均值随NH4 -N施用量的增加呈递减规律,农田秸秆还田后不利于土壤对CH4的吸收。