Influence of zinc on electrochemical discharge activity of Mg-6%Al-5%Pb anode

Mg-6%Al-5%Pb (mass fraction) anodes with different contents of zinc were prepared by melting and casting. The electrochemical discharge behavior of these anodes in 3.5% NaCl solutions was investigated by galvanostatic test and electrochemical impedance spectroscopy (EIS). The microstructures and the corroded surfaces of these anodes were studied by scanning electron microscopy (SEM) and emission spectrum analysis (ESA). The phase structures and the corrosion products of the anodes were analyzed by X-ray diffraction (XRD). The results show that zinc promotes the grain refinement of Mg-6%Al-5%Pb anode and makes the average discharge potential of Mg-6%Al-5%Pb anode more negative during galvanostatic test. Mg-6%Al-5%Pb anode with the addition of 1% (mass fraction) zinc has the best electrochemical performance. The activation mechanism of zinc to Mg-6%Al-5%Pb anode is as follows: The hydrolyzation of dissolved Zn²⁺ ions reduces the pH value of the solution near the surface of the anode and accelerates the dissolution of Mg(OH)₂ film; The precipitated Zn(OH)₂ with similar structure as Mg(OH)₂ combines with Mg(OH)₂ film easily and makes it break down.     

Enhanced electrochemical properties of SnO2 anode by AlPO4 coating

A SnO₂ anode material undergoes severe capacity loss, which is mainly associated with cracking/crumbling of the material by the large volume change between the Li_xSn and Sn phases, and the intensive reactions with the electrolyte solution. However, AlPO₄ nanoparticle coating showed drastically improved electrochemical properties with decreased surface cracks. The AlPO₄-coated SnO₂ exhibited a capacity of 781 mAh/g, approaching its theoretical capacity at the first cycle, with 44% capacity retention after 15 cycles between 2.5 and 0 V at a relatively high C rate of 105 mA/g. In contrast, the bare SnO₂ showed an initial capacity of 680 mAh/g, with only 8% capacity retention after 15 cycles.     

大气压直流双阳极等离子弧脉动特性研究

等离子弧的脉动特性是表征等离子体物理状态和过程的重要参数之一,等离子体射流的非稳定性和阳极斑点在电极上的运动是引起等离子弧脉动的主要原因,是等离子体技术的实际应用和进一步发展的关键。该文介绍了一种大气压直流双阳极等离子发生器,通过对等离子弧电信号进行时域和频域分析,研究了载气成分、载气流量和弧电流等参数的变化对等离子弧脉动特性的影响,结果表明在文中的实验条件下等离子弧的伏安特性呈上升趋势,纯氩气作为载气时等离子弧的脉动特性主要和电源的交流分量有关,氩氮混合气体作为载气时等离子弧的脉动特性除了和电源的交流分量有关,还和弧室内存在的赫姆霍茨共振有关,其共振频率独立于气体流量和弧电流的变化。     

混凝电解气浮-吸附过滤处理洗染废水

采用混凝电解气浮-吸附过滤法处理洗染废水.试验结果表明:混凝电解气浮过程中,采用石墨作阴极,铁作阳极,电解电压一般控制在8~11 V,电能消耗约0.08 kW h/m3,CODC r可去除30%以上;吸附过滤过程选用新鲜粉煤灰作为吸附材料,粒度为0.3 mm,废水在吸附柱中的停留时间为2 h,CODC r可以去除50%以上.     

电解铝生产中优化磷生铁配方的试验研究

针对240kA铝电解槽阳极组的钢爪和碳块之间浇注压降高低不等，造成生产中设备附加电阻大，浪费电能的状况，通过设计正交试验，优化磷生铁配方，降低了浇注压降，节能效果显著。     

锌电积节能措施的研究现状

传统的湿法炼锌过程中，存在着电积能耗大的问题。本文系统综合了当前锌电积的节电措施，并对新型情性阳极材料及锌电积新工艺的研究现状进行了详细阐述。     

大型预焙槽阳极效应管理

在对非正常阳极效应进行分析的基础上,提出和研究了非阳极效应的判断和处理方法,可有效地预防非正常效应的发生,减少效应系数,使效应能够按照设定的间隔发生,维持电解槽的高效平稳运行,从而达到提高铝厂经济效益,减少环境污染的效果.     

回转式精炼炉炉口砌筑工艺改进

针对葫芦岛东方铜业有限公司120吨回转式精炼炉口出现炉口掉砖问题，对耐火材料及其砌筑工艺进行探讨和改进。     

槽管式分酸器在硫酸装置中的应用

叙述了硫酸装置中各种分酸器的特点，着重介绍了槽管式分酸器以及与阳极保护组合槽管式分酸器的实用性。实践证明，具有阳极保护的槽管式分酸器，被越来越广泛运用于有色工业和化工系统的硫酸生产中。     

降低不溶阳极电积镍直流电耗的探讨

对影响不溶阳极电积镍直流电耗的各种因素进行了分析,降低溶液电阻、减少线路损耗可降低槽电压,而稳定阴极液pH、适当提高溶液中镍离子和H3BO3浓度对提高电流效率、降低直流电耗有利,采取相应措施后,取得了良好效果,直流电耗降低了5%,经济效益明显。