钢铁表面黑色转化膜处理技术

黑色转化膜技术是目前较为先进的钢铁表面处理技术 ,本文试验研究了一种新工艺 ,提出了TB值的概念 ,通过控制TB值即可控制处理液的质量 ,获得性能优良的转化膜。此工艺性能可靠 ,可操作性强 ,并可应用于激光热处理前的预处理。     

空分设备的酸性腐蚀及预防

以切换式换热器空分设备为例 ,分析了空分设备酸性腐蚀的原因、可能造成的危害 ,提出了预防措施。     

新型哈氏合金G—30的耐蚀性能与工业应用

文章叙述了新型镍基耐蚀哈氏合金G-30在不同介质中的耐蚀性能以及工业应用,综合分析了该合金应用的经济性及前景。     

Pit to crack transition in stress corrosion cracking of a steam turbine disc steel

Long term exposure tests have been carried out on a 3 NiCrMoV steam turbine disc steel in the form of cylindrical tensile test specimens self-loaded to 90% of σ_0.2 and exposed to three environmental conditions, viz. deaerated pure water, aerated pure water, and aerated water containing 1.5 ppm of chloride ion. Pitting occurred in all environments but the density and depth of pits in the chloride-containing medium was markedly greater. No cracking was observed in deaerated pure water but cracks initiated in aerated water between 13 and 19 months and in less than 7 months in aerated 1.5 ppm Cl⁻ solution. The probability of a crack initiating from a pit of specific depth in aerated solution could be described well by a Weibull function. Profiling of pits and cracks in the disc steel tested in aerated 1.5 ppm Cl⁻ solution showed that there while there were many cracks with a depth greater than that of the corresponding pit the depth of some cracks was smaller than that of the corresponding pit, suggesting that cracks do not necessarily initiate from the bottom of the pits. The growth rate of short cracks emerging from pits appeared greater than that of long cracks in fracture mechanics specimens.     

含腐蚀凹坑尿素合成塔的安全评定与分析

对尿素合成塔上封头腐蚀凹坑采用中国SAPV-95和美国API579规范分别进行安全评定，给出安全裕度，简略分析安全评定的结果。     

湿H2S环境中金属材料腐蚀的研究

介绍了在湿H2S环境中金属材料的腐蚀试验标准、方法和手段并重点强调了在H2S试验过程中常遇到的一些问题的处理方法.最后,指出了应加强H2S腐蚀的基础性和系统性研究的研究方向.     

The rate of corrosion of concrete reinforcement and possibilities of its mathematical modelling

The paper describes a method for the mathematical modelling of steel reinforcement corrosion rate. This method is based exclusively on experimental results and expression of the influence of significant corrosion factors in the form of functional relations. The method takes into account the reality of the effects of corrosion factors, their contigency and complexity, and various circumstances occurring in practice. It represents one way towards the development of methods for the prediction of service life of reinforced concrete and structures.     

高强度钢的Zn—Ti合金新镀层

本文研究了一种Ｚｎ－Ｔｉ合金新镀层，经盐水浸泡、中性盐雾和大气暴露试验结果试验，其耐蚀明显超过镀Ｚｎ层，并与镀Ｃｄ层相近，用缺口持久拉伸试验检验氢脆性，拉伸持续时间超过２００ｈ，达到原航空部部颁标准（ＨＢ５０６７－８５），该镀层适用于高强度钢防护。     

Electrosynthesis and impedance studies on zinc selenide

Electrochemical impedance measurements have been used to characterize zinc selenide films prepared by electrochemical co-deposition at a platinum rotating disk electrode. Estimations of capacitance and polarization resistance of variously prepared electrodeposits have been carried out to determine charge carrier density and corrosion rates.     

The influence of NaCl and CO2 on the atmospheric corrosion of magnesium alloy AZ91

The influence of NaCl and CO₂ on the atmospheric corrosion of magnesium alloy AZ91 is studied in the laboratory. Samples were exposed under carefully controlled air and flow conditions; the relative humidity was 95%, the temperature was 22.0°C and the concentration of CO₂ was < 1 ppm or 350 ppm. Different amounts of sodium chloride (0–70 μg/cm²) were added before exposure. The corrosion products were analyzed by gravimetry, ion chromatography, X‐ray diffraction and scanning electron microscopy. Mass gain and metal loss results are reported. The combination of high humidity and NaCl is very corrosive towards AZ91. However, the NaCl‐induced corrosion is inhibited by ambient concentrations of CO₂. Exposure in the absence of CO₂ gives rise to heavy pitting, with brucite, Mg(OH)₂, being the dominant corrosion product. In the presence of CO₂ a layer of hydrated magnesium hydroxy carbonate, Mg₅(CO₃)₄(OH)₂ · 5 H₂O forms. A tentative corrosion mechanism is presented that explains the behavior in the two environments.