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21.
Melissa Kurtz 《Journal of Failure Analysis and Prevention》2007,7(3):175-178
Fuel system assemblies used on recreational watercraft failed after a short time in service in a seawater environment. Examination
of the assemblies revealed significant degradation of the polyacetal connectors of the wire subassemblies. Optical and microscopic
evaluations indicated the complete loss of connector material implying decomposition of the resin, along with mud-cracking
and a rough surface morphology signifying chemical attack. An elemental analysis performed on both an intact connector and
degraded connector suggested a potential chemical agent in the form of zinc chloride. At elevated temperatures, concentrated
zinc chloride solutions are known to decompose polyacetal resins. The source of the zinc chloride was established as corrosion
products that resulted during the dezincification of the internal brass connector through exposure to saltwater in the application. 相似文献
22.
Effects of austenitizing treatment temperatures on aqueous corrosion properties of martensitic stainless steels were investigated by electrochemical tests (potentiodynamic test, potentiostatic test and electrochemical impedance spectroscopy), and surface analyses (optical microscopy and XRD). The results of potentiodynamic test revealed that the breakdown potential increased with the increased austenitizing temperature, indicating increased relative resistance to initiation of localized corrosion. EIS measurements showed that MSS3 (1030 °C) exhibits larger polarization resistance value than MSS1 (970 °C) and MSS2 (1000 °C) at passive and breakdown states. This was caused by decreasing the amount of Cr-rich M23C6 carbide which acts as preferential sites for pitting corrosion. 相似文献
23.
复合绝缘子耐电腐蚀特点及其电蚀老化区域性的差异 总被引:6,自引:0,他引:6
为了了解复合绝缘子外绝缘材质电蚀老化状态和区域性的差异,对Al(OH)3耐电腐蚀机理、外绝缘材质中Al(OH)3颗粒分布状态和环境污湿因素的实际情况进行了研究。Al(OH)3颗粒分解成水蒸气、析出白色粉末状氧化铝,并催化生成二氧化碳,将使外绝缘材质逐渐微观减薄和加大表面的粗糙度,而引起电蚀老化的污湿环境因素,近期不可能得到改善,因此必然引起其电蚀老化出现区域性差异。此外,外绝缘憎水表面污珠场强变化引起的电晕也是促使电蚀老化的重要因素。 相似文献
24.
对导热油加热炉炉壁温度升高的原因进行了分析,介绍了新型复合内衬的特点,并对其技术特点、施工工艺及应用效果进行了简单阐述。 相似文献
25.
两栖装甲装备新型防腐材料的研究 总被引:1,自引:0,他引:1
沿海地区特殊海洋环境造成装甲装备的严重腐蚀,为了研制一种新型的耐蚀有机涂层,该文作者研究了有机硅改性环氧树脂的化学反应,并对改性树脂的性能进行了测试分析.结果表明,改性树脂克服了环氧树脂的耐温性差、亲水性强以及盐水渗透率高的性能缺陷,为进一步制备该地区装甲装备防腐涂料奠定基础. 相似文献
26.
H. H. Rehan 《Materialwissenschaft und Werkstofftechnik》2003,34(2):232-237
Water extracts from leaves of date palm, phoenix dactylifera, henna, Lawsonia inermis, and corn, Zea mays, were tested as corrosion inhibitors for steel, aluminum, copper and brass in acid chloride and sodium hydroxide solutions using weight loss, solution analysis and potential measurements. The inhibition action was found to critically depend on metal type and solution composition. Only, date palm and henna extracts were found highly effective in reducing corrosion rate of steel in acid chloride solutions and aluminum in sodium hydroxide solutions. The inhibition efficiency increased with increasing the concentration of the extract. The inhibition was interpreted in terms of chemisorption of some active ingredients in the leaves according to Temkin isotherm. 相似文献
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29.
Copper phthalocyanine as corrosion inhibitor for ASTM A606-4 steel in 16% hydrochloric acid 总被引:2,自引:0,他引:2
A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations. 相似文献
30.
The GILDES computer model, incorporating Stumm's concept of proton- and ligand-promoted dissolution, has been used to simulate the exposure of copper at room temperature to 210 ppb sulfur dioxide and 80% relative humidity. The agreement is good between the calculations and laboratory exposures performed under these exposure conditions. Surface reactions are relatively more important at lower relative humidities and the dominant corrosion products formed are solid state Cu2SO3, CuSO3 and Cu2U. Free-radical redox processes are important participants and control the relative distribution of Cu(I)- and Cu(H)-containing corrosion products. 相似文献