改进催化裂解装置再生立管气固输送状态

荆门分公司催化裂解装置由于使用高堆密度催化剂，再生立管出现了气固输送故障，对反应温度和产品收率影响较大。采取改进措施后取得了显著效果，液化气收率可提高约4个百分点，丙烯收率可提高1－3个百分点。     

已二醇二丙烯酸酯对真丝的接枝改性研究

研究了用二醇二丙烯酸酯为接枝单体、过硫酸铵（APS）为引发剂对真丝的接枝共聚反应，分析了接枝率的影响素，并测试了改性真丝的主要应用性能。结果表明：乳液和乙醇/水为溶剂的2种体系都能在真丝上获得较高接枝率。对于乙醇/水体系v(乙醇）：v(H2O）=1:1，接枝单体20～30g/L,2%甲酸4ml，引发剂APS 0.5g/L,65～70℃接枝60min的接枝率高。改性后真丝的断裂强度、延伸度、吸湿性能都可获得改善，对酸、碱的溶解性提高，但染色性能提高不明显，对泛黄性改善一般。     

Closed-loop automatic tuning of PID controller for nonlinear systems

In this paper, a robust control system is first proposed which is suitable for the control of a class of nonlinear systems. A parallel connection of a relay to a proportional integral derivative (PID) controller collectively forms the robust controller. The relay ensures robust control by providing a high feedback gain, but it also induces a control chattering phenomenon. Instead of viewing chattering as an undesirable yet inevitable feature, the chattering signals are used as natural excitation signals for identifying an equivalent PID controller using the recursive least squares algorithm. No other explicit input signal is required. Analysis is provided on the stability properties of the control scheme. Simulation results for the level control of fluid in a spherical tank using the scheme are presented.     

填料萃取塔的操作性能及设计计算

系统地介绍了填料抽提塔的两相流动及传质特性，设计计算，对填料塔的设计和操作有一定指导意义。     

IFP连续重整新一代催化剂再生技术的改进

介绍了我国引进的采用法国石油研究院 (IFP)三代催化剂连续再生技术的重整装置 ,分析了第二、第三代技术在原有基础上的改进 ,从再生气循环回路、再生操作参数和再生器内部结构三个方面重点介绍了第三代催化剂连续再生技术的特点和优势 :使催化剂的烧焦气循环回路与氧氯化用气、焙烧气循环回路彼此分开 ,烧焦、氧氯化、焙烧的操作参数可分别得到优化 ,使氧氯化及焙烧在高氧条件下进行 ,有利于催化剂金属的再分散 ,保持催化剂的活性。     

分组网与ISDN互连的性能分析

本文研究分组交换数据网与ＩＳＤＮ互连的性能分析，文中考虑了分组肉与窄带ＩＳＤＮ和宽带ＩＳＤＮ互连时信关所应完成的功能，分别给出了两种情况下的信关排队模型；在信关存储容量分别为有限和无限的情况下，对两种模型进行了求解，给出了阻塞概率和平均延迟的表达式。对于与Ｂ－ＩＳＤＮ互连的情况，提出了用开关确定性过程来描述输出排队的分组到达流，并提出了一种小时隙方法分析ＳＤＰ／Ｄ／１排队。     

天然气制液态烃新工艺

丰富的天然气资源,特别是边远地区分散的中小天然气田和油气共生的油气田的天然气,由于产量达不到管线长输的规模效益,又远离消费市场,很难开发利用.为此,作者在天然气两段催化氧化制合成气和费-托合成研究的基础上,提出了一种流程较短、投资和操作费用较低的天然气合成液态烃新工艺,可将丰富的天然气资源,特别适合将边远地区分散的中小天然气田的天然气转化为无硫、无氮、无芳烃、无重金属污染和便于输运的优质石蜡基液态产品.该产品可经轻度加氢改质得到高品质的柴油掺合组分、润滑油基础油高等附加值产品.该工艺副产的燃料气可用于发电,或作为燃料气使用.     

化工防腐蚀涂料应用情况介绍

介绍了氯磺化聚乙烯涂料、改性聚苯乙烯涂料、环氧树脂类涂料、水冷器涂料、抗静电涂料等涂料的性能、用途和在洞庭氮肥厂的使用情况.同时对几种涂料施工方案进行了比较.     

DCS的评价与选择

本文综述了ＤＣＳ（集散控制系统）三代产品的总体水平评价，介绍了ＤＣＳ的总体性能、评价指标和它的选择准则。     

A novel laboratory bench for practical evaluation of catalysts useful for simultaneous conversion of NOx and soot in diesel exhaust

This study deals with the development of a laboratory bench for the practical evaluation of catalysts that are useful for the direct conversion of NO_x and soot in the exhaust of diesel engines. The employed model exhaust is generated by using a diffusion burner with additionally dosing some gaseous components to the burner gas to obtain a realistic feed composition. The produced soot is extensively characterized by employing thermogravimetry, transmission electron microscopy, N₂ physisorption and temperature programmed techniques. The results of the different characterization methods show that the present soot is suitable for the intended catalytic investigations. The simultaneous conversion of NO_x and soot is examined like in practice, i.e. the soot is separated from the tail gas by a diesel particulate filter (DPF) that is coated with the catalyst. The deposited soot is then catalytically converted by NO_x and O₂ to form N₂ and CO₂. The conversions of NO_x and soot are measured by exclusively applying gas analysers, whereby a special experimental procedure is developed to determine the soot removal. Hence, additional soot related analytics are not required. To show the suitability of the constructed bench a Pt/Fe₂O₃/β-zeolite sample is taken as test catalyst that is reported to be very active in NO_x/soot reaction. The measurements performed with and without catalyst clearly show the effect of the used sample in simultaneous NO_x/soot conversion. We therefore consider the constructed laboratory bench to be a useful tool for testing and ranking catalytic materials.