TLC／FID方法测定催化裂化原料油的烃族组成

测定了不同来源,不同种类的催化裂化原料油的薄层色谱图,提取了谱图特征变量,以偏最小二乘方法为数学工具,通过经典柱色谱法取得基础数据,建立催化裂化原料油的薄层色谱－烃族组成模型。采用该模型预测待测样品的烃族组成,并与经典柱色谱法的测定结果相比,饱和烃质量分数,芳烃质量分数和胶质质量分数的相关系数分别为0．9614,0．9359和0．9636。对子分析进行t检验的结果表明,本文建立的方法与经典柱色谱法的测定结果相一致。另外,薄层色谱法具有分析速度快,重现性好等优点。     

鲁卜哈里盆地志留系热页岩特征及成熟度演化史

根据钻井资料,分析了鲁卜哈里盆地志留系底部热页岩在盆地内的发育状况。对岩心、岩屑样品进行了TOC测定、热解分析及镜质体反射率测定,认为热页岩演化已达成熟—高成熟阶段,有的甚至是过成熟阶段。对样品干酪根、沥青“A”及其族组分的碳同位素分析,确定了有机质类型为II型。利用PetroMod盆地模拟软件,对3口探井进行埋藏史、热史和成熟度史模拟,并对对外合作区块热页岩进行成熟度演化史模拟,认为该区块志留系底部热页岩由深凹至东部斜坡各阶段的演化时间依次变晚,凹陷区热页岩在早二叠世均已进入成熟演化阶段;而东部斜坡热页岩于早三叠世末—晚侏罗世末期才进入成熟演化阶段。     

我国重点盆地致密油气资源潜力

我国致密油气勘探开发在鄂尔多斯、四川、松辽、准噶尔等盆地取得了一系列新发现和新突破,储量和产量快速增长,是现阶段最现实的非常规油气资源。梳理总结致密油气勘探开发进展,采用三大类七种评价方法,对10个重点含油气盆地致密油气资源进行评价,计算得到致密油地质资源量146.60亿吨,可采资源量14.55亿吨,致密气地质资源量22.88万亿方,可采资源量11.26万亿方。综合分析认为,我国致密油气资源丰富、潜力大,具有良好的勘探开发前景,预计到2020年致密油产量可达300万吨,致密气产量可达550亿方。面对挑战,抓住机遇,要从理论研究、技术攻关等多个方面共同努力,推动致密油气的勘探开发。     

合成气制烃的催化过程和催化剂发展动态

4 合成气直接制烃催化剂提高合成过程竞争力的总趋势是控制选择性,开发定向合成催化过程和催化剂。目的产品是液体燃料汽油、柴油,化工原料乙烯、丙烯、异丁烯等低碳烯烃以及裂解原料低碳烷烃。4.1 合成低碳烯烃     

GC-MS测定纺织品中多环芳烃

以甲苯为萃取溶剂,采用加速溶剂萃取方法,以外标法定量,建立了一种测定纺织品中多环芳烃(PAHs)含量的气相色谱-质谱联用法。该方法检出限为50μg/kg,工作曲线线性范围为5~500μg/L,加标回收率为86.5%~105%,相对标准偏差为1.0%~4.8%。检测结果表明,该方法简便可靠,能够达到纺织品材料中16种多环芳烃的检测需求。     

S－148芳醇不饱和聚酯树脂耐腐蚀机理研究

合成了Ｓ－１４８芳醇不饱和聚酯树脂，研究了Ｓ－１４８树脂浇铸体和玻璃钢于不同温度下在不同介质中的耐酸、碱、盐腐蚀性能，并探讨了其耐腐蚀机理。结果表明，Ｓ－１４８树脂具有优异的耐腐蚀性能，可用作耐腐蚀制品的基体树脂。     

Kynurenine Pathway of Tryptophan Metabolism in Migraine and Functional Gastrointestinal Disorders

Migraine, the leading cause of disability in the population aged below 50, is associated with functional gastrointestinal (GI) disorders (FGIDs) such as functional nausea, cyclic vomiting syndrome, and irritable bowel syndrome (IBS). Conversely, changes in intestinal GI transit may cause diarrhea or constipation and are a component of the autonomic symptoms associated with pre- and post-dorsal phases of migraine attack. These mutual relationships provoke a question on a common trigger in migraine and FGIDs. The kynurenine (l-kyn) pathway (KP) is the major route for l-tryptophan (l-Trp) metabolism and transforms l-Trp into several neuroactive compounds. Changes in KP were reported in both migraine and FGIDs. Migraine was largely untreatable, but several drugs approved lately by the FDA, including monoclonal antibodies for calcitonin gene-related peptide (CGRP) and its receptor, create a hope for a breakthrough in migraine treatment. Derivatives of l-kyn were efficient in pain relief with a mechanism including CGRP inhibition. KP products are important ligands to the aryl hydrocarbon receptor (AhR), whose activation is implicated in the pathogenesis of GI and migraine. Toll-like receptors (TLRs) may play a role in migraine and IBS pathogeneses, and KP metabolites detected downstream of TLR activation may be an IBS marker. The TLR4 signaling was observed in initiating and maintaining migraine-like behavior through myeloid differentiation primary response gene 88 (MyD88) in the mouse. The aim of this review is to justify the view that KP modulation may provide common triggers for migraine and FGIDs with the involvement of TLR, AhR, and MyD88 activation.     

江陵凹陷层序地层充填与油气勘探

在建立江陵凹陷白垩系—下第三系层序序列的基础上．系统研究了目的层新沟嘴组的旋回结构，建立了新沟嘴组浅水湖盆层序地层充填模式，进行了沉积相分析和砂体展布研究．提出了岩性油藏勘探的有利区带．对该凹陷新沟嘴组的油气勘探．尤其是岩性油藏的勘探具有指导作用。     

济阳断陷盆地油气运移优势方向研究

济阳断陷盆地不同区带油气运移的控制因素、输导体系和运聚方向各异。洼陷带深部,油气沿“应压双控”作用产生的裂缝系统———隐蔽输导体系侧向或向上充注于泥岩裂缝圈闭或砂岩透镜体,油气运移的优势方向与成藏期北东向最大水平主应力方向一致;洼陷带上部或两侧,油气通过断裂型输导体系向上运移,平面上亦平行于北东向断裂运移;陡坡带和缓坡带,油气输导体系主要为断裂-砂体复合型,油气运移优势方向为垂直于盆地边缘边界断层的鼻状构造带的展布方向。