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This review focuses on fluorescence spectroscopy techniques for the investigation of electrophoretic separations. Fluorescence has been used as a sensitive detector for capillary, gel, and microchip electrophoresis for decades. However, advanced fluorescence methods can be used to study transport, interfacial phenomena, intermolecular and affinity interactions, and other processes that occur during separation. This so‐called spectroscopic toolkit can be implemented to understand fundamental behavior in electrophoresis and electrokinetic chromatography. Techniques such as fluorescence recovery after photobleaching, fluorescence correlation spectroscopy, and fluorescence anisotropy are discussed in relation to electrophoretic separations. Newer methods such as super‐resolution microscope are also introduced. 相似文献
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Reduction of nitrobenzene by excess organic electron donor, 12, affords diphenylhydrazine in a reaction where azobenzene oxide and azobenzene are likely intermediates. No cleavage of the N-N σ-bond is seen under photoactivation conditions, whereas traces are seen under thermal activation. Hydrazone derivatives were prepared to explore the cleavage of N-N σ-bonds; the results show that a low-lying LUMO assists the transition state for accepting an electron, and the stabilisation that the potential fragments from N-N bond cleavage afford to the fragments is important in determining whether cleavage is observed. 相似文献
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Synthesis,Single Crystal Growth and Crystal Structure of Ta7Cu10Ga34 – a 8 × 4 × 2 Super Structure of CsCl
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Single crystals of Ta7Cu10Ga34 were grown from the elements in a Cu/Ga melt. Ta7Cu10Ga34 represents the first ternary compound of the system Ta/Cu/Ga. The crystal structure (Cmmm, oC102, Z = 2, a = 23.803(1), b = 12.2087(4), c = 5.7487(2) Å, 1291 refl. 78 parameters, R1 = 0.037, wR2 = 0.070). The crystal structure is characterized by rods of pentagonal prisms MGa10, which are alternatingly occupied by Ta and Cu. Four of these rods are connected to columns running in direction (001). These columns are linked by cubic units TaGa8, CuGa8, and GaGa8. According to the characteristic structural elements and the size of the unit cell Ta7Cu10Ga34 represents a 8 × 4 × 2 super structure of CsCl or bcc. With respect to the underlying CsCl structure the formula can be written as [Ta7Cu10Ga2□13]Ga32, i.e. a cubic primitive packing of 32 Ga atoms with Ta, Cu, and Ga in cubic voids and 13 vacancies. The pentagonal‐prismatic coordination of Ta and Cu can formally be obtained from the cubic primitive packing of Ga atoms by a 45° rotation of a part of the Ga8 cubes. There is a close similarity to the binary compounds Ta8Ga41 and Ta2–xGa5+x. The first one is also related to a CsCl‐like structure, the latter one contains rods of pentagonal prisms, which form the same columns. There are also relations to the ternaries V2Cu3Ga8 and V11Cu9Ga46, whose cubic structures are more or less complex variants of CsCl. 相似文献
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SOME CENTRAL LIMIT THEOREMS FOR SUPER BROWNIAN MOTION 总被引:1,自引:0,他引:1
李增沪 《数学物理学报(B辑英文版)》1999,(2)
1IntroductionLimittheoremsconstituteanimportantpartofthebranchingprocesstheory.Itisalwaysinterestingtofindconditionsunderwhichanon-degeneratelimitlawexists.SinceGaltonWatsonprocessesareunstable,peoplehavederivedlimittheoremsforthemthroughdevicessucllasmodifyingfactors,conditioning,immigration,etc.AunifiedtreatmentofthelimittheoryofGallon--WatsonprocessesisgiveninAthreyaandNey(1972).Someoftheabovementionedtechniqueshavealsobeenusedinthemeasure-valuedsettingtogetlimittheoremsforDawson-Watana… 相似文献
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Li Zenghu 《数学物理学报(B辑英文版)》1999,19(2):121-126
The author proves a central limit theorem for the critical super Brownian motion, which leads to a Gaussian random field. In the transient case the limitingfield is the same as that obtained by Dawson (1977). In the recurrent case it is aspatially uniform field. The author also give a central limit theorem for the weightedoccupation time of the super Brownian motion with underlying dimension numberd 3, completing the results of Iscoe (1986). 相似文献
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鲍玉芳 《数学物理学报(A辑)》1999,19(1):94-100
证明了分支特征为ψ(z)=z^2,底过程为d≤3的暂留Ornstein-Uhlenbeck(O.U.)过程的超过程Xt的占位时过程Y(t)=∫^t0Xsds关于Lebesgue测度绝对连续,且其密度过程Y(t,x)关于t≥0,x∈R^d联合连续。 相似文献
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