高温拉曼光谱提高信噪比的途径分析

结合累积时间分辨和空间分辨建成了上海大学高温拉曼谱仪SU-HTRS(T/S).由于高温噪声的不可避免,采用了移动平均方法,傅里叶变换滤波和小波分析的方法对其进行了数据降噪处理.在不同噪声水平上分析了不同处理方式对谱峰中心位置、强度、面积的影响及处理后数据的光滑度的影响.三种方法比较起来,移动平均法快而简单,小波分析的去噪效果最好.     

Low-Threshold High-Temperature Operation of ～7.4μm Quantum Cascade Lasers

We report low-threshold high-temperature operation of 7.4#m strain-compensated InGaAs/lnAIAs quantum cascade lasers （QCLs）. For an uncoated 22-μm-wide and 2-mm-long laser, the low-threshold current densities, i.e. 0.33kA/cm^2 at 81 K in pulsed mode and 0.64kA/cm^2 at 84K in cw mode, are realized. High-temperature operation of uncoated devices, with a high value of 223K, is achieved in cw mode.     

First-Principles Prediction of High-Pressure Phase of CaC6

The lattice dynamics of rhombohedral GaG6 is studied as a function orpressure to probe Its high pressure phase with low superconducting transition temperature using the density functional liner-response theory. The pressureinduced phase transition in CaC6 is attributable to the softening transverse acoustic （TA） phonon mode at the zone boundary X （0.5, 0.0, 0.5） point. The high pressure phase is then explored by performing fully structural optimization in the supercell which accommodates the atomic displacements corresponding to the eigenvectors of the unstable mode of TA（X）. The high-pressure phase is predicted to be a monoclinic unit cell with space group P21/m.     

陶瓷过滤器高温除尘技术的研究进展

对陶瓷过滤元件及结构、滤饼的作用和架桥、过滤器故障安全（CPP）系统及陶瓷过滤器高温气体净化一体化技术等几个方面进行了评述，总结了陶瓷过滤器存在着过滤管破裂、清灰效率下降、管板和器壁的连接及脉冲阀的长期稳定性等几个问题，指出新型陶瓷材料的研究和陶瓷过滤器高温气体净化一体化技术是陶瓷过滤器今后的研究方向．     

回热式多孔介质发动机的多维数值模拟

回热式发动机利用多孔介质回热器在气缸中的往复运动,实现气固之间的热交换,促进均匀混合气的形成,从而实现均质和稳定的燃烧.本文利用改进的KIVA-3V程序对Ferrenberg所提出的回热式发动机模型进行了二维数值模拟.发动机以甲烷为燃料,采用了详细的反应机理.通过数值计算讨论了两个主要的工况参数,孔隙率和燃料喷射量对发动机燃烧温度的影响.计算模拟表明,多孔介质的孔隙率越大,甲烷的喷射量越多,气缸内的高温区域也最大.     

Radiation Vulcanization of Magnetorheological Elastomers Based on Silicone Rubber

The fabrication of magnetorheological （MR） elastomers was studied by two vulcanization methods, including heat vulcanization （HV） and radiation vulcanization （RV）, were employed to fabricate MRE samples. The dynamical mechanical properties were characterized by using a dynamic mechanic analyzer. In particular, both the MR effect and its durability were investigated. The experimental results showed that RV samples have large magnetoinduced modulus, large zero-field modulus, and good durability property of MR effect. To explain these results, cubic deformation and plasticizer migration were analyzed. Large magneto-induced modulus of RV sample results from cubic deformation during vulcanization process. And the plasticizer migration results in better durability of MR effect.     

Al0.2Co1.5CrNi1.5Ti0.5Mox高温耐磨高熵合金的组织结构、力学性能和摩擦学性能

使用真空电弧熔炼技术制备了Al_0.2Co_1.5CrNi_1.5Ti_0.5Mo_x(x=0.0, 0.1, 0.2, 0.3, 0.4)高熵合金，研究了Mo含量对该高熵合金组织结构、力学性能和摩擦学性能的影响规律及其作用机制. Al_0.2Co_1.5CrNi_1.5Ti_0.5高熵合金由FCC相和有序AlNi₃相组成，Mo元素添加后促进形成σ相.较大原子半径的Mo元素引发的晶格畸变效应和σ硬质相析出引起的第二相强化效应赋予高熵合金优良的力学和摩擦学性能.随着Mo含量的提高，合金的硬度增加了40.4%，屈服强度增加了32.1%.对该合金的摩擦磨损性能进行研究，发现Mo元素的添加显著改善了高熵合金的摩擦学性能，尤其是当Mo的摩尔比为0.4时，高熵合金室温磨损率为2.62×10^-6 mm³/(N·m),800℃时的磨损率为6.23×10