Effects of Trace Zinc on Toughening and Strengthening of Steels

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Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

Production and properties of micro‐porous glas bubble zinc and aluminium composites

Micro‐porous syntactic foams were produced by means of integration of glass bubbles into aluminium and zinc matrices. Preforms of glass bubbles were pressure infiltrated with the alloys AlSi9Cu9 ans ZnAl4Cu using squeeze casting. The preforms were sintered thermically without the use of bonding agents. Using the combination of different sintering steps syntactic foams with locally different densities could be produced. The mechanical properties of the foams were tested indicating a high compression strength of the foams and a very good compression energy absorption. Furthermore, corrosion behaviour and behaviour at higher temperatures were investigated.     

添加高效粘结剂的氧化锰矿粉冷固成团

以氧化锰矿粉为原料，添加ＺＢ粘结剂进行冷固成团，所得冷固团块不仅具有足够的机械强度，而且具有良好的耐湿性，适用于长距离运输和露天堆存，是一种可与块矿性能相媲美的优质炉料，为充分利用矿山及冶炼厂的锰矿粉找到了一条良好的途径．     

Vinyl acetate monomer—a pilot plant study

The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid.     

乳胶厚度对卤化银反射全息图衍射特性的影响

实验研究了自制的超细颗粒卤化银乳剂SDUF－1分别在AAC显影、改进的R－10漂白处理及改进的GP－8溶解物理显影处理条件下，其乳胶厚度对反射全息图衍射特性的影响。实验结果表明，在这两种不同处理条件下衍射效率与胶厚的关系有相当大的差别，合适的乳胶厚度分别为12μm和6μm左右。     

醋酸铅在离子液体中溶解机理的研究

通过[bmim]Cl和Pb(OAc)2混合反应后析出PbCl2沉淀,制备得到溶解有醋酸铅的离子液体[bmim]OAc。实验发现,即使使用过量的醋酸铅,PbCl2仍然不能沉淀完全,这表明离子液体中的Pb2+离子并不是以游离形式存在的,而是以配位的形式存在,并且由离子液体包裹着。因此,醋酸铅在离子液体[bmim]OAc中的溶解度得到增加,平均溶解度达到1 1mmol/ml,最大溶解度达到3 0mmol/ml。     

云南锰矿选矿现状与前景分析

云南锰矿资源丰富,具有品位高、低磷低铁、易选等特点。文章概述了斗南、鹤庆、建水等锰矿的选矿科研进展情况,三个锰矿均可采用强磁选或磁-重选流程选别,可提高品位8—12％;精矿含锰可达33—35％,锰回收率在80％以上的好结果。     

常减压蒸饱装置几起典型硫腐蚀事例分析

随着高（含）硫原油加工量的增加,硫腐蚀事故也时有发生。通过对常减压装置硫腐蚀事例进行分析,指出合理的混炼比,加强“一脱三注”管理,材料升级和实施腐蚀监测是防止腐蚀事故发生的有效措施。     

全面留矿法采场顶板支护和落矿爆破工艺的研究

本文介绍的接杆锚杆护顶技术和上向眼大孔距多排微差爆破落矿技术，解决了逐昌金矿全面留矿法采矿工艺中存在的采场顶盘围在面积冒落和采场落矿爆破效果差、效率低这两个问题。