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991.
矩法评定活塞裙部横截面线轮廓误差 总被引:2,自引:1,他引:2
本文通过组合应用矩法与最小二乘法,提出了求解被测活塞裙部横截面理想线轮廓的方法,并对评定活塞裙部横截面线轮廓误差进行了讨论。 相似文献
992.
HPLC separation and wavelength area ratios of more than 50 phenolic acids and flavonoids 总被引:1,自引:0,他引:1
W. L. Banwart P. M. Porter T. C. Granato J. J. Hassett 《Journal of chemical ecology》1985,11(3):383-395
Relative retention times and wavelength area ratios for over 50 standard compounds were calculated using reverse-phase HPLC. The standard compounds analyzed included benzoic acids, cinnamic acids, benzene carboxylic acids, acetic acids, coumarins, benzaldehydes and a variety of flavonoid compounds including flavanones, flavones, isoflavones, and their glycosides. Each standard compound was chromatographed by three different gradient elutions. Compounds were detected by UV absorption at 254 nm and 280 nm. Relative retention times with respect to two different internal references and the 254nm: 280nm wavelength area ratio was determined for each standard. Soybean root and seed extracts were analyzed for the presence of the standard compounds using the chromatographic conditions described. 相似文献
993.
Preparation of rice husk ash with high specific surface area and chemical reactivity of the product are reported in this paper. The amorphous rice husk ash with high specific surface area of 311 m^2.g^-1 was produced by heating acid treated rice husk at 700~C for 4 h. The isotherms of rice husk ash are similar in shape to type Ⅱ of Brunaner‘s classification with mesopores being predominant. The rice husk ash has a high chemical reactivity, especially that pretreated with acid. This chemical reactivity depends on ashing temperature and pretreatment conditions. There is an exponential relation between the specific surface area of rice husk ash and the change in the conductivity of saturated Ca(OH)2 solution with rice husk ash, from which the specific surface area can be known according to the conductivity change. 相似文献
994.
995.
Two thermal stable phases, Ce0.75Zr0.25O2 and Ce0.16Zr0.84O2, with different surface area were prepared by coprecipitation. The oxygen storage capacity (OSC) measurements were carried
out at 500 °C under both transient (CO–O2 cycle at 0.05, 0.1 and 0.25 Hz) and stationary reaction conditions (CO pulse). In the oxygen storage/release process, the
rate-determine step is surface reactions when the specific surface area is lower than 60 m2/g. When the surface area increases further, the influence of surface area is less important. The increased surface area favors
diesel soot catalytic combustion via providing more redox sites to activate adsorbed oxygen. Nevertheless, this effect is
less important when the specific surface area is larger than 40 m2/g, especially under loose contact condition. 相似文献
996.
《Ceramics International》2017,43(4):3797-3803
High surface area cobalt ferrite (CoFe2O4) powders were synthesized by solution combustion method. The dependence of the adiabatic temperature and the released gases during combustion reaction on the fuel content and cobalt precursor type, cobalt nitrate and cobalt acetate, was thermodynamically calculated. Thermal analysis, infrared spectroscopy, X-ray diffractometry, nitrogen adsorption–desorption, electron microscopy and vibrating sample magnetometer were used for investigation of the phase evolution, surface areas, morphology and magnetic properties of the synthesized CoFe2O4 powders. The specific surface area decreased from 285.4 to 35.7 m2/g with increasing of fuel to oxidant molar ratio, ϕ, from 0.5 to 1.25 for the cobalt nitrate precursor, while the maximum surface area of 182.1 m2/g was attained at ϕ=1 for the cobalt acetate precursor. The synthesized CoFe2O4 powders from the cobalt nitrate precursor exhibited the higher saturation magnetization and coercivity on account of the higher purity and crystallinity. 相似文献
997.
Three‐dimensional modeling of porosity development during the gasification of a char particle 下载免费PDF全文
Kay Wittig Petr A. Nikrityuk Sebastian Schulze Andreas Richter 《American Institute of Chemical Engineers》2017,63(5):1638-1647
This work is devoted to the three‐dimensional, direct modeling of porosity and specific surface development during the gasification of a char particle. The model was developed for heterogeneous reactions occurring inside a char particle in a kinetically controlled regime. The main goal of this work is to analyze the impact of different pore size distributions on the particle carbon conversion rate. In particular, it is shown that under certain conditions the outer particle surface can influence the specific surface area. In this context the possible adaptation of the parameter ψ from the random pore model (RPM) developed by Bhatia and Perlmutter is explained. The results of simulations are compared against the RPM and discussed. Additionally, based on the results of simulations, the physics behind several input parameters used by the RPM are explored. Finally, the possible fragmentation of a chemically reacting char particle during its gasification in dependence of instantaneous porosity was investigated numerically. It was shown that the earliest fragmentation occurs at a carbon conversion of about 0.5–0.6 due to the disaggregation of the pore walls. The results are discussed and compared implicitly with data published in the literature. © 2016 American Institute of Chemical Engineers AIChE J, 63: 1638–1647, 2017 相似文献
998.
999.
In order to analyse agglomerate particles, we have developed a computer method that automates the analysis of spots in electron diffraction patterns. The method isolates the zone axis diffraction pattern in a polycrystalline diffraction image by isolating the spots from other features of the image and then by selecting the spots that belong to a regular array. The method gives the basis vectors for the array which can then be used to identify the particle by comparison with standard diffraction data. 相似文献
1000.
纳米晶复合涂层应用于火星玻璃盖片防尘的探索 总被引:1,自引:0,他引:1
目的制备超微结构的纳米晶复合涂层,降低火星环境中灰尘颗粒在玻璃表面的粘附,并通过翻转操作,最大限度地清除沉积的灰尘,恢复太阳能电池的发电能力。方法采用水热法和表面修饰,制备了纳米晶复合防尘涂层。通过电子显微镜、分光光度计、接触角仪和翻转除尘试验分别对涂层的微观结构、可见-近红外光透过率、表面性质和除尘效率进行了分析。结果由直径大约为27nm的ZnO纳米棒构成的独特涂层结构,使灰尘颗粒与涂层表面的接触面积相比于普通玻璃减小了一个数量级,可见光区的透过率提高了1.1%,近红外区透过率提高了0.4%。用氟化物进行表面修饰后,涂层的水接触角由25°~45°升高至155°~165°。经90°缓慢翻转,纳米晶复合涂层对50~100μm和30~50μm灰尘颗粒的清除效率分别为80%~90%和60%~70%;而在相同测试条件下,普通玻璃的防尘效率仅为37.5%和6.3%。由翻转后涂层表面灰尘的分布情况和倾斜表面上单颗粒的受力分析发现,灰尘颗粒的脱落存在滑落和滚落两种模式,高位落下的颗粒将部分动能传递给低位静止的颗粒,促使更多静止颗粒的滑落或滚落,形成"雪崩"状的特殊形貌。结论 ZnO纳米晶复合涂层不仅可以提高可见光和近红外光的透过率,还可以极大地减小与灰尘颗粒的接触面积,降低颗粒的粘附力,在不使用高压电能的情况下,经过翻转操作,清除效率可达80%以上,这将为火星上灰尘的清除提供一种安全的方式。 相似文献