Electrochemical corrosion properties of metal alloys used in orthopaedic implants

This study concerns an investigation of the corrosion behavior of 316 stainless steel, CoCrMo and Ti6Al4V alloys in simulated body conditions (ringer lactate) at 37 °C by the use of Tafel plots, mixed potential and electrochemical impedance spectroscopy (EIS). Ti6Al4V alloy has the highest corrosion resistance followed by CoCr alloy. Ti6Al4V–CoCrMO was the best couple for galvanic corrosion with the minimum galvanic potential and current values according to mixed potential theory and Tafel method. It was concluded that Ti6Al4V was the most suitable material for implant applications in the human body.     

钻孔灌注桩首批混凝土灌注量之实用计算

为避免钻孔灌注桩因首批混凝土灌注量不足而导致水或泥浆进入导管，影响灌注桩的质量，按《公路桥涵施工技术规范》中公式计算的首批混凝土灌注量应乘以扩孔系数。     

锚杆静压桩用于高层建筑桩基加固

夯扩桩已在桩基工程中得到了广泛应用 ,但是 ,施工中时常发生事故。本文介绍某高层建筑夯扩桩基础出现不合格桩的状况 ,采用锚杆静压桩进行基础加固补强 ,是一项取得成功的实例。     

Bimetallic Pt–Au thin film electrocatalysts with hierarchical structures for the oxidation of formic acid

A series of bimetallic Pt–Au thin films with different Pt/Au ratios were fabricated on glassy carbon (GC) substrates through galvanic replacement reactions between hierarchical Co thin films prepared by cyclic voltammetric deposition and mixed solutions of HAuCl₄ and H₂PtCl₆. The morphologies of the as-prepared Pt–Au thin films resemble those of the sacrificial Co templates, and the Pt/Au ratios in the films are dependent on the HAuCl₄/H₂PtCl₆ molar ratios in the mixed solutions. Because of good stability and excellent synergistic effect of Au and Pt, the bimetallic films with novel structures display unexpected high catalytic activity for the oxidation of formic acid. The as-prepared hierarchical Pt–Au micro/nanostructures are expected to find applications as catalysts in direct formic acid fuel cells (DFAFCs).     

CFG桩施工要求及质量控制措施

CFG桩是水泥、粉煤灰、碎石桩的简称,在施工中已得到广泛应用。为保证CFG桩的施工质量,论文提出了CFG桩的施工要求及常见的质量控制措施。     

桥梁桩基础有限元模型构建思路与应用

为了实现利用通用有限元程序建立桩基础有限元模型进行内力计算的目的,本文以桥梁基础规范的计算理论为指导,介绍了桩基础模型构建的思路。首先根据弹性地基梁理论,提出了用梁单元模拟基桩,把土对基桩的作用用一系列水平土弹簧和两个竖向土弹簧来模拟,并推导了土弹簧刚度的计算公式及公式中有关参数的取值方法。提出多排桩承台与桩顶连接方式的模拟,一定要能正确反应承台底面中心和桩顶的变位关系式。最后,通过一个双排桩实例来介绍这种建模方法的应用,并将模型计算结果与手算结果进行比较,发现两者误差较小,范围不超过1%,从而验证了桩基础的有限元模型构建思路是正确的。     

Copper deposition onto silicon by galvanic displacement: Effect of Cu complex formation in NH4F solutions

Copper was deposited onto rotating Si substrates by galvanic displacement in 6.0 M NH₄F to determine the effects of Cu complex formation on deposition rates. Deposition rates decreased with increasing rotation speed, indicating that Cu(I) intermediates, stabilized by NH₃, diffuse away from the Cu surface before they reduce to Cu(0). UV-visible spectra of contacting solutions and direct measurements of mass changes resulting from Cu deposition and Si removal confirmed this proposal. These findings contrast those reported previously for deposition from HF solutions, in which Cu(I) species are unstable and reduce rapidly to Cu(0). These data and mixed-potential theory were used to develop a reaction-transport model that accurately describes the effects of mass transfer and electrochemical reaction rates on Cu deposition dynamics and open-circuit potential (OCP) values. The effects of ascorbic acid and tartrate additives on film properties and formation rates were also examined. Cu reduction kinetics decreased significantly when ascorbic acid (0.01 M) was present. Adhesion of Cu films was improved when ascorbic acid was used, but internal stresses caused films to distort when their thicknesses exceeded 100 nm. Adding potassium sodium tartrate to solutions containing ascorbic acid decreased film stresses and led to robust films with excellent adhesion.     

镀锡钢丝锡层厚度的测定

介绍利用原电池及失重法相结合测定镀锡钢丝的镀层厚度的方法。     

正确处理综合单价下的桩基工程量争议

本文主要根据参建方对综合单价下桩基工程量计算的争议,从计价规范、05定额及有关权威部门解释等角度出发,提出正确的分析方法和处理意见。     

桩拱结构整治滑坡设计

结合工程应用实例简述桩拱结构整治滑坡的设计方法，以极限平衡反算法成果，综合考虑地勘建议值确定滑动面上的抗剪强度指标，并采用文克尔模型计算抗滑桩的内力。