Influence of geometry on galvanic corrosion of AZ91D coupled to steel

The influence of geometric factors on the galvanic current density distribution for AZ91D coupled to steel was investigated using experimental measurements and a BEM model. The geometric factors were area ratio of anode/cathode, insulation distance between anode and cathode, depth of solution film covering the galvanic couple and the manner of interaction caused by two independent interacting galvanic couples. The galvanic current density distribution calculated from the BEM model was in good agreement with the experimental measurements. The galvanic current density distribution caused by the interaction of two independent galvanic couples can be reasonably predicted as the linear addition of the galvanic current density caused by each individual galvanic couple.     

Effect of Fe-Zn alloy layer on the corrosion resistance of galvanized steel in chloride containing environments

In this study, the effect of Fe-Zn alloy layer that is formed during galvanizing process on the corrosion behavior of galvanized steel has been investigated. The galvanostatic dissolution of galvanized steel was carried out in 0.5 M NaCl solution to obtain the Fe-Zn alloy layer on the base steel. The alloy layer was characterized to be composed of FeZn₁₃, FeZn₇ and Fe₃Zn₁₀ intermetallic phases, which constitute the zeta, delta1 and gamma layers of galvanized steel, respectively. It was observed that the alloy layer has similar cathodic polarization behavior but different anodic polarization behavior compared to galvanized steel. The anodic current plateau of alloy layer was up to 100 times lower than that of galvanized coating. Corrosion test performed in wet-dry cyclic condition has shown that the alloy layer has lower corrosion rate as compared to galvanized steel. From the results of corrosion test of alloy layer and base steel, it was concluded that Zn²⁺ has positive effect on the protectiveness of the zinc corrosion products. The measurement of surface potential over the alloy/steel galvanic couple has confirmed the galvanic ability of alloy layer to protect both the alloy layer itself and the base iron during initial stage of atmospheric corrosion.     

Corrosion behaviour of brazed multilayer material AA4343/AA3003/AA4343: Influence of coolant parameters

This paper is the second part of a work devoted to corrosion in brazed AA4343/AA3003/AA4343 materials on the water side of automotive heater cores. In the first part of the study [S. Tierce, N. Pébère, C. Blanc, C. Casenave, G. Mankowski, H. Robidou, Electrochim. Acta 52 (2006) 1092], corrosion initiation in the surface layer (i.e. the residual cladding) has been investigated. It has been associated to defective sites in the passive film covering the alloy. The defective sites are linked to α-Al(Mn,Fe)Si particles built up during brazing process. Interactions between α-Al(Mn,Fe)Si particles and the matrix are responsible for the observed behaviour. The present study focuses on the propagation of corrosion through the material in neutral water–ethylene glycol mixtures with and without chlorides. Comparison of the electrochemical behaviour of the three layers of the brazed material (i.e. the residual cladding, the “band of dense precipitates (BDP)” and the core material) revealed that the residual cladding was nobler than the BDP and the core material and thus that the corrosion should propagate through the inner layers due to galvanic coupling: the inner layers constitute the anode and the residual cladding the cathode. Increasing the ethylene glycol content in the water–ethylene glycol mixture decreased the rate of consumption of the materials whereas addition of chloride ions increased it. Mass variation measurements of brazed material in different solutions containing the degradation products of ethylene glycol showed that only glycolate ions had a slight detrimental effect. Corrosion tests performed in heater core tubes allowed the propagation mechanisms to be confirmed.     

宜春某建筑场地岩溶发育特征

江西省宜春市宜阳新区位于可溶岩区,岩溶作用形成的溶洞、土洞对地基的稳定性存在重要影响.根据对宜春某建筑场地桩基础超前钻获得溶洞、溶蚀带和断裂构造的位置,分析其空间分布规律,对桩基础结构设计及施工具有关键指导作用.     

Understanding the galvanic corrosion of the Q-phase/Al couple using SVET and SIET

The galvanic corrosion of the Q-phase/Al couple in 0.1 M NaCl solutions has been studied using the scanning vibrating electrode technique (SVET), the scanning ion-selective electrode technique (SIET) and energy dispersive X-ray spectroscopy (EDX). The galvanic corrosion of the Q-phase/Al couple was found to be dependent on pH and immersion time. Current density maps obtained by SVET shows that the anodic oxidation processes emerge from Al in a localized manner in pH 2 and 6 solutions but is initiated in a uniform manner in pH 13 solution, whereas, the cathodic processes are more homogeneously distributed over the Q-phase at pH 2, 6 and 13. It is seen that the Q-phase remains cathodic in the Q-phase/Al couple in acidic, neutral and alkaline solutions indicating that the galvanic polarity of the Q-phase is independent of pH. The effect of the galvanic corrosion was largest at pH 2 and 13 compared to pH 6. The pH map obtained by SIET indicates that the galvanic activity of the Q-phase/Al couple proceeds via heavy alkalization of the Q-phase surface with the generation of appreciable amounts of OH⁻ ions. The enrichment of Cu indicated by EDX is responsible for the observed cathodic activity of the Q-phase in the Q-phase/Al couple.     

软土地区群桩效应影响因素的有限元分析

针对天津滨海地区软土地基,利用有限元软件MIDAS进行群桩效应的影响因素分析,讨论了在不同桩长、桩径、桩距以及不同桩数等情况下群桩效应系数以及承台底土分担荷载比例的变化规律,并得出了一些有益的结论,为天津滨海地区桩基设计施工提供参考。     

桩锚与土钉墙联合支护中钉轴检测的探讨

桩锚与土钉墙联合支护形式能发挥桩锚与土钉墙各自特有的长处,使得工程安全而经济。在桩锚与土钉墙联合支护中钉轴检测发挥了重要的积极作用。根据实际施工数据,着重分析桩描与土钉墙联合支护中土钉轴力的一些变化规律,为桩锚与土钉墙联合支护设计理论研究积累了重要的真实数据。     

砼管桩灌注机控制系统设计

介绍了预制砼管桩灌注机的工作过程和控制要求。给出了基于S7-200 PLC和AE80THTD触摸屏的控制系统。对控制系统的硬件组成、I/O配置、软件工作流程和控制功能图做了较详细的阐述。实际运行表明,控制系统具有制造、安装、调试方便,操作简单,运行稳定、可靠等特点。     

Design Strategies for Piled Rafts Subjected to Nonuniform Vertical Loading

The piled raft is a geotechnical composite construction, consisting of the three elements piles, raft, and soil, which is applied for the foundation of tall buildings in an increasing number. In a parametric study, 259 different piled raft configurations have been analyzed by means of three-dimensional elastoplastic finite element analyses. In the study, the pile positions, the pile number, the pile length, and the raft-soil stiffness ratio as well as the load distribution on the raft has been varied. In the scope of this paper, the results of the parametric study are presented and design strategies for an optimized design of piled rafts subjected to nonuniform vertical loading are discussed.     

Development of Downdrag on Piles and Pile Groups in Consolidating Soil

Development of pile settlement (downdrag) of piles constructed in consolidating soil may lead to serious pile foundation design problems. The investigation of downdrag has attracted far less attention than the study of dragload over the years. In this paper, several series of two-dimensional axisymmetric and three-dimensional numerical parametric analyses were conducted to study the behavior of single piles and piles in 3×3 and 5×5 pile groups in consolidating soil. Both elastic no-slip and elasto-plastic slip at the pile–soil interface were considered. For a single pile, the downdrag computed from the no-slip elastic analysis and from the analytical elastic solution was about 8–14 times larger than that computed from the elasto-plastic slip analysis. The softer the consolidating clay, the greater the difference between the no-slip elastic and the elasto-plastic slip analyses. For the 5×5 pile group at 2.5 diameter spacing, the maximum downdrag of the center, inner, and corner piles was, respectively, 63, 68, and 79% of the maximum downdrag of the single pile. The reduction of downdrag inside the pile group is attributed to the shielding effects on the inner piles by the outer piles. The relative reduction in downdrag (Wr) in the 5×5 pile group increases with an increase in the relative bearing stiffness ratio (Eb/Ec), depending on the pile location in the group. Compared with the relative reduction in dragload (Pr), Wr at the corner pile is less affected by the group interaction for a given surcharge load. This suggests that the use of sacrificing piles outside the pile group will be more effective on Pr than on Wr. Based on the three cases studied, the larger the number of piles in a group, the greater the shielding effects on Wr. Relatively speaking, Wr is more sensitive to the total number of piles than to the pile spacing within a pile group.