A new microsecond pulse-heating system to investigate thermophysical properties of solid and liquid metals

A new discharge system for resistive self-heating has been constructed for the measurement of accurate thermophysical properties. A constant-current pulse is used to heat metals over a time interval of 50 to 100 s, reaching temperatures up to the boiling point. New techniques have been developed to obtain sound speeds in the pulse-heated sample, emissivities, and vapor pressure. A new pyrometer allows the extension of the measured temperature range down to the melting point of copper.     

线性矩阵方程异类约束最小二乘解的迭代算法

多矩阵变量线性矩阵方程(LME)约束解的计算问题在参数识别、结构设计、振动理论、自动控制理论等领域都有广泛应用。本文借鉴求线性矩阵方程(LME)同类约束最小二乘解的迭代算法,通过构造等价的线性矩阵方程组,建立了求多矩阵变量LME的一种异类约束最小二乘解的迭代算法,并证明了该算法的收敛性。在不考虑舍入误差的情况下,利用该算法不仅可在有限步计算后得到LME的一组异类约束最小二乘解,而且选取特殊初始矩阵时,可求得LME的极小范数异类约束最小二乘解。另外,还可求得指定矩阵在该LME的异类约束最小二乘解集合中的最佳逼近解。算例表明,该算法是有效的。     

Thermal expansion of Pyros from 20 to 1273 K

Pyros, which is a Ni-base alloy (82% Ni, 8% Cr, 4% W, 3% Mn, and 3% Fe), has been used extensively in France since 1926 as a temperature sensor and as a reference material for thermal expansion measurements. In this paper we present recent data on the expansion and expansivity of Pyros from 20 to 1273 K. Expansivity results, obtained by taking the derivative of a cubic-spline polynomial fitting performed to the L/L experimental data, show that Pyros is a stable material in the 20 to 1273 K temperature range. Furthermore, since the expansivity values are similar to those of steels, Pyros should be of special interest to laboratories which are concerned with expansion measurements on steels. Therefore, we suggest that Pyros be considered as a suitable reference material for thermal expansion measurements on steels, and until more accurate results are obtained, we propose our results as reference data between 20 and 1273 K.Paper presented at the Ninth Symposium on Thermophysical Properties, June 24–27, 1985, Boulder, Colorado, U.S.A.     

Estimating room temperatures from fires along walls and in corners

Determination of temperatures associated with room fires provides a means of assessing an important aspect of fire hazard: the likelihood of the occurrence of flashover. Layer temperatures in excess of 600°C have been associated with the occurrence of flashover. A data correlation has previously been presented to estimate layer temperatures for fires burning in the center of rooms. For fires in corners and along walls, restricted entrainment results in higher layer temperatures than predicted by the previous correlation. Modification factors for the previous correlation are developed to extend its applicability to wall and corner burning geometries. The present analysis suggests that a fire in a corner may cause flashover with only half the heat release rate necessary for a fire burning in the center of a room. Reference: Frederick Mowrer and Robert Williamson, Estimating Room Temperatures from Fires along Walls and in Corners,Fire Technology, Vol. 23, May 1987, pp. 133–145.     

咪唑啉缓蚀剂工艺条件优化及效果

在减缓金属腐蚀的研究中,为了缓解在酸性溶液、碱性溶液以及大气、土壤等介质中金属腐蚀较为严重的问题,对咪唑啉类缓蚀剂进行了工艺条件优化.采用静态失重法研究了碳钢在加入了缓蚀剂的盐酸溶液中的缓蚀性能.在最佳合成条件下苯甲酸与二乙烯三胺最佳摩尔比为1∶1.3,催化剂质量分数为1.2%,环化时间为1 h,咪唑啉中间体与氯化苄的最佳摩尔比为1∶1.1,季铵化反应时间为1 h,季铵化反应温度为70 ℃,缓蚀剂的最佳质量分数为1%,最终缓蚀率可以达到99.37%.     

Ti-22Nb-6Zr(at%)合金的超弹性和形状记忆效应

用弯曲法和拉伸法测定Ti-22Nb-6Zr（at％）合金的超弹性和形状记忆效应，研究固溶处理温度对Ti-22Nb-6Zr合金组织结构及性能的影响。结果表明：固溶处理后Ti-22Nb-6Zr合金的室温组织为单一的β相，晶粒尺寸随固溶处理温度升高而增大；合金的静态弹性模量小于30GPa；Ti-22Nb-6Zr合金具有良好的超弹性和一定的形状记忆效应。室温下变形，合金的超弹性和形状记忆效应随固溶处理温度升高而提高。900℃固溶处理后的合金在室温下拉伸变形，应变为5％时，总的最大回复应变达4．12％，其中超弹性回复应变为3．91％，记忆回复应变为0.21％。     

简支深梁用和函数法的级数解答

引用和函数法求解弹性力学平面问题, 对简支深梁受三角形荷载作用时的应力进行了分析,同时给出了该问题的付立叶级数解答,该方法不仅将求解弹性力学的偏微分方程组解耦成非耦联的几个偏微分方程,而且其结果与传统的Airy应力函数得到的解答完全一致, 证明了该方法的正确性和适用性,该方法拓展了将经典的弹性力学解析法用于解决工程实际问题的空间。     

轴对称正挤压的简化滑移线解

介绍了一种分析轴对称塑性成形问题的新方法———简化滑移线解法 ,并得到了光滑锥形凹模正挤压问题的简化滑移线解 ,求解所依据的近似应力场满足平衡微分方程和应力边界条件 ,并包含有应力间断面 ,但在某些局部范围内不满足屈服准则。结果表明 ,简化滑移线解高于滑移线解 ,低于上限解 ,比较接近于真实载荷 ,是求解轴对称塑性成形问题变形力的一种简便而实用的新方法     

Effect of ammonia concentrations on SCC of α-brass under mode III loading

Stress corrosion cracking (SCC) of α-brass in ammonia solution was studied under mode III loading. The results showed that SCC occurred on the principal stress planes where shear stresses are zero. No SCC occurred on the maximum shear stress plane. Ammonia concentration affected fracture behaviour. When the concentration was low, many cracks with spacing of 10–150 μm were found on 45 ° planes, i.e., the principal stress planes. When the concentration was high, the cracks on 45 ° planes were not clearly visible because of serious general corrosion.     

变形体温度场和位移场的计算

本文用热源法对简单热传导问题进行了解析解的计算，并应用PDE工具箱求解热传导偏微分方程得到数值解。通过两种温度场的计算结果求出相应的位移场结果，比较可知MATLAB中PDE工具箱对难以用解析法求解的热传导问题有一定的指导作用。