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71.
M. Pérez-Luna A. Cosultchi J. A. Toledo-Antonio C. Angeles-Chavez E. M. Arce-Estrada 《Catalysis Letters》2006,107(1-2):103-110
Three Ni/ZrO2–SO4=/Al2O3 catalysts with different concentrations of platinum (0.2, 0.3 and 0.4 wt%) were prepare and tested for n-butane isomerization reaction at 338 K, in absence and in presence of hydrogen. The results shown that, at low temperature,
platinum contributes to the olefin or butyl ion formation and the reaction follows a bimolecular pathway. However, when the
reaction occurs in the presence of hydrogen, the formation of butyl ions is inhibited. The main feature of platinum addition
is the stabilization of the catalytic activity, which is indicated by the slow deactivation constants compared to that of
the unpromoted catalyst. 相似文献
72.
00C r22N i5M o3N不锈钢是双相不锈钢,它的固溶组织中α铁素体相和γ奥氏体相约各占一半。经过试验分析它的击破电位,保护电位,室内化学浸泡试验结果都证明它具有优良的耐点腐蚀性能;通过试验还证明它同时具有优良的耐均匀腐蚀和缝隙腐蚀的性能。 相似文献
73.
Vapor-Phase Alkylation of Toluene with Isopropanol over Mg/Al, Ni/Al and Cu/Al Hydrotalcites (Layered Double Hydroxide) 总被引:1,自引:0,他引:1
Vapor-phase isopropylation of toluene has been carried out over Mg/Al, Ni/Al and Cu/Al calcined hydrotalcites (CHTs). Reaction conditions were optimized for alkylation by varying temperature, weight hourly space velocity and reactant mole ratio. Side-chain alkylation is found to be more predominant than ring alkylation over Mg/Al CHT, while Ni/Al and Cu/Al CHTs favored ring alkylation. The main products were isobutylbenzene and cymene. The combined participation of acidic and basic sites of the materials is found to be crucial for both side-chain and ring alkylation of toluene with isopropanol. An X-ray diffraction pattern of the resulting oxide indicates a diffuse MgO structure. The incorporation of small amounts of Al3+ to MgO generates new surface Lewis acid--base pair sites. 相似文献
74.
甲烷部分氧化制合成气催化剂的研究进展 总被引:12,自引:0,他引:12
综述了甲烷部分氧化制合成气的研究意义和现状,从金属活性组分,载体效应,载量选择,助剂添加和制备方法等因素对催化剂活性的影响及研究进行了系统。结合本课题组的研究结果及文献报道,分析了Ni基催化剂的失活特性,并提出使用等离子体技术对Ni基催化剂进行改笥处理,以提高其催化稳定性的技术展望。 相似文献
75.
丁二酮肟吸光光度法测定陶瓷色釉料中的镍 总被引:2,自引:0,他引:2
当有氧化剂存在时,在氨性溶液中,镍与丁二酮肟生成酒红色的络合物。借此可作镍的比色测定。若离子本身有颜色,则影响测定,但可用空白校正。 相似文献
76.
Z. Benzo T. Zoltan M. Murillo M. Quintal J. Salas E. Marcano C. Gómez 《Journal of the American Oil Chemists' Society》2006,83(5):401-405
An emulsion-based method was developed as an alternative for the introduction of oil-based samples into a graphite furnace
to produce a more rapid, precise, and accurate method of analysis. The combination of emulsion sampling and electrothermal
atomization for atomic absorption spectroscopy was developed and then applied to the determination of Ni and manganese in
neem oil from Venezuela. The optimal concentration of neem oil in the emulsion was 30 and 4% for Ni and Mn, respectively,
based on the metal concentration of the neem oil. The stability of the emulsion as a function of time was evaluated. The use
of aqueous calibration solutions and the accuracy attained using this method make it attractive for the analysis of oil samples.
The metal recovery was between 97 and 101%. Based on the emulsion method, the neem oil samples had 1.39 and 0.21 mg of Mn
and Ni per kg of oil, respectively. The wet digestion method indicated a Mn and Ni concentration in the neem oil sample of
1.42 and 0.24 mg/kg, respectively. 相似文献
77.
阐述了Ni/Al2 O3 复合颗粒在生产中的应用 ,讨论了在Al2 O3 陶瓷颗粒上形成Ni膜的三种方法 ,分析了这些方法的优缺点。 相似文献
78.
A thin film of yttrium Y (150 nm) protected by a 6 nm coating of nickel Ni on a glass substrate was completely hydrogenated in a 1 M NaOH electrolyte at a constant negative current until the transparent Y tri-hydride phase was achieved and hydrogen gas evolution from the electrode began. A series of impedance measurements were performed in situ during the electrochemical experiment to study the properties of the system as dependent on hydrogenation degree and time of relaxation. The equivalent electrical circuit (EEC) simulations were performed with a Randles-like scheme R0[R1CPE1], where R0 is the thin film electrode resistance, R1 the charge transfer resistance and CPE1 is the capacitive constant phase element. The behavior of all the components of the EEC undergoes a clear transition when the hydrogenation degree of the electrode is approximated to its maximum value (H to Y ratio 2.7) and electrochemical process changes from hydrogen uptake to hydrogen evolution. 相似文献
79.
Methane was pulsed over pure CuO and NiO as well as Cu/La2O3 and Ni/La2O3 catalysts at 600° C. Results indicate that the mechanisms for methane activation over copper and nickel are quite different. Over CuO, methane is converted to CO2 and H2O, most likely via the combustion mechanism; whereas metallic copper does not activate methane. Over NiO in the presence of metallic nickel sites, methane activation follows the pyrolysis mechanism to give CO, CO2, H2 and H2O. Similar results were obtained over the Cu/La2O3 and Ni/La2O3 catalysts. XRD investigations indicate that copper and nickel existed as CuLa2O4 and LaNiO3 respectively in the La2O3-supported catalysts. The effect of La2O3 on the activation of methane is discussed. 相似文献
80.
以酸性多孔ZSM-5沸石(HZSM-5-M)和高比表面积的氧化硅(SiO2)为载体,采用等体积浸渍法制备了负载Ni2P催化剂(Ni2P/HZSM-5-M和Ni2P/SiO2),对比研究了它们在苯乙炔选择性加氢反应中的催化性能。采用XRD、N2吸附-脱附、NH3-TPD、H2-TPR、SEM和TEM对载体及其负载的Ni2P催化剂进行了表征。催化剂活性结果为:当反应时间为2 h,苯乙炔在Ni2P/HZSM-5-M催化剂的转化率为98.5%,而在Ni2P/SiO2催化剂上仅为45.6%。说明Ni2P/HZSM-5-M催化剂的加氢活性显著高于Ni2P/SiO2催化剂。这是因为,与Ni2P/SiO2催化剂相比,在Ni2P/HZSM-5-M催化剂上形成了小颗粒的Ni2P活性相。同时,Ni2P/HZSM-5-M催化剂的活性具有良好的重复性。 相似文献