Homogeneous Plastic Flow of Fully Amorphous and Partially Crystallized Zr_(41.2)Ti_(13.8)Cu_(12.5)Ni_(10)Be_(22.5) Bulk Metallic Glass

The homogeneous plastic flow of fully amorphous and partially crystallized Zr(41.2)Ti(13.8)Cu(12.5)Ni(10)Be(22.5) bulk metallic glass (Vitl) has been investigated by compression tests at high temperatures in supercooled liquid region. Experimental results show that at sufficiently low strain rates, the supercooled liquid of the fully amorphous alloy reveals Newtonian flow with a linear relationship between the flow stress and strain rate. As the strain rate is increased, a transition from linear Newtonian to nonlinear flow is detected, which can be explained by the transition state theory. Over the entire strain rate interval investigated, however, only nonlinear flow is present in the partially crystallized alloy, and the flow stress for each strain rate is much higher. It is found that the strain rate-stress relationship for the partially crystaltized alloy at the given temperature of 646 K also obeys the sinh law derived from the transition state theory, similar to that of the initial homogeneous amo     

Kinetics of AuSn4 migration in lead-free solders

The relatively fast diffusion of Au atoms in eutectic PbSn matrix is considered one of the contributing factors to the Au embrittlement problem. In this study, we further investigated the Au embrittlement problem in high-Sn solders. Experimentally, Sn3.5Ag (wt.%) spheres with 500-μm diameter were soldered over the Au/Ni soldering pads. It was found that some of the AuSn₄ needles that formed after reflow inside the solder migrated back to the solder/pad interface during thermal aging. However, the migration kinetics in high-Sn solders was slower compared to that in eutectic PbSn. The difference in migration kinetics of AuSn₄ in eutectic PbSn and SnAg was ascribed to the difference in the magnitudes of the Au flux and the Ni flux. In eutectic PbSn, the Au flux was much greater than that of the Ni flux, and the Au and Ni flux were in the same order of magnitude in eutectic SnAg. The relative magnitude of the Au and Ni flux changed in eutectic PbSn and SnAg because the homologous temperatures of PbSn and SnAg were different.     

屈服损伤对高压容器用Ni3V钢力学性能的影响

对高压容器用Ni3V钢进行了屈服极限Rp0 .2 损伤的单向拉伸试验 ,分析其在损伤后对常规力学性能的影响     

Syngas production via combined oxy-CO2 reforming of methane over Gd2O3-modified Ni/SiO2 catalysts in a fluidized-bed reactor

In this research, Ni/SiO₂ catalyst was modified with different amount of Gd₂O₃ and characterized with temperature-programmed desorption of CO₂ (CO₂-TPD) and NH₃ (NH₃-TPD), temperature-programmed reduction with H₂ (H₂-TPR) and X-ray diffraction (XRD). It was found that Gd₂O₃-modified Ni/SiO₂ catalysts possessed higher CO₂ adsorption and activation ability due to the formation of surface carbonate species. H₂-TPR and XRD characterizations found that the strong interaction among nickel, Gd₂O₃ and SiO₂ took place, which improved the dispersion of Ni. Gd₂O₃-modified Ni/SiO₂ catalysts exhibited higher activity and stability for the combined oxy-CO₂ reforming of methane in fluidized-bed reactor. The H₂/CO ratio in produced syngas could be controlled via controlling reaction temperature and CO₂/O₂ ratio in feed.     

Microstructure evolution of nanostructured Ni3Al during annealing

A nanocrystalline layer was produced on the surface of Ni3Al intermetallic by means of surface mechanical attrition treatment. The surface nanocrystallites were annealed at 250-750 ℃ for 30 min. Microstructure evolution of nanocrystallites during annealing was studied by X-ray diffraction （XRD） and transmission electronic microscope （TEM）. The experimental results show that long-rang order recovers rapidly when annealing temperature is below 250℃ and changes slowly at 350-550 ℃, and then it increases rapidly at 750℃. The grain size of nanocrystallites of Ni3Al keeps stable and crystal defects recover when they are annealed below 550℃. The grains grow normally in low temperature annealing and abnormal growth occurs at 750℃.     

天然高分子吸附剂研究Ⅱ．镍离子模板壳聚糖树脂的合成及特性

以镍离子为模板剂，合成了乙醇双环氧丙基醚交联的壳聚糖树脂，研究了其对Ｃｕ（Ⅱ）、Ｎｉ（Ⅱ）、Ｃｏ（Ⅱ）离子的吸附性能。结果表明，该法合成的树脂对Ｎｉ（Ⅱ）离子具有较强的“记忆”和“识别”能力，其对Ｃｕ（Ⅱ）、Ｎｉ（Ⅱ）、Ｃｏ（Ⅱ）的吸附量分别达２．２１、２．１３、１．４０ｍｍｏｌ／ｇ树脂。     

Pre-bainitic Transformation in Fe-Ni Alloy

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Thermal expansion of Pyros from 20 to 1273 K

Pyros, which is a Ni-base alloy (82% Ni, 8% Cr, 4% W, 3% Mn, and 3% Fe), has been used extensively in France since 1926 as a temperature sensor and as a reference material for thermal expansion measurements. In this paper we present recent data on the expansion and expansivity of Pyros from 20 to 1273 K. Expansivity results, obtained by taking the derivative of a cubic-spline polynomial fitting performed to the L/L experimental data, show that Pyros is a stable material in the 20 to 1273 K temperature range. Furthermore, since the expansivity values are similar to those of steels, Pyros should be of special interest to laboratories which are concerned with expansion measurements on steels. Therefore, we suggest that Pyros be considered as a suitable reference material for thermal expansion measurements on steels, and until more accurate results are obtained, we propose our results as reference data between 20 and 1273 K.Paper presented at the Ninth Symposium on Thermophysical Properties, June 24–27, 1985, Boulder, Colorado, U.S.A.