ZrO2固体电解质用于铝电解的初步研究

本文对YSZ型析氧阳极应用于铝电解进行了初步研究,讨论了导电引出方式,密封性以及均匀电场对电解体系的影响,并且对YSZ型析氧阳极的可行性进行了验证。结果表明:YSZ型析氧阳极用于铝电解是可行的;使用镍铬丝和纳米级La0.7Sr0.3MnO3粉末的导电引出方式是合理的;密封性以及均匀电场对电解体系的稳定性十分重要。     

熔体快淬La1-xNdxFe11．5Si1．5（x=0，0．3，0.5）化合物磁性能和磁熵变

利用熔体快淬法制备了La1-xNdxFe11．5Si1．5（x=0，0．3，0.5）快淬带。通过X射线衍射和振动样品磁强计测试了回火态（1000℃，5h）La1-xNdxFe11．5Si1．5）快淬带的相组成和磁性能。结果表明：不同成分快淬带回火后均可得到稳定的NaZnl，型化合物。和常规的熔炼法相比，用熔体快淬法通过短时间的回火（1000℃，5h）可以制成具有大磁熵变的NaZn13型的化合物。用Nd替代部分的La后，居里温度略有提高，同时保持有大的磁熵变｜△S｜；并且随着Nd含量的增加，有效制冷温区有变宽的趋势。     

Modification effect of pure rare earth metal La on as-cast hypereutectic Al-17%Si alloys

1　INTRODUCTIONImprovedpropertiesandlightweightareincreas inglybecomingthemaingoalsofautomotiveandaerospaceindustries[1] .Forthesakeofachievingthesecharacteristics,manyeffortshavebeenfocusedonaluminumalloysandtheirpropertiesundersevereconditions.Applyingaluminumalloystoautomotivepartssuchaspistons ,cylinderliners ,engineblocksanddifferentpartsofthermalmotors ,combinativeimprovementofthestrengthtomassratio ,wearre sistance,heatresistance ,andlowheatexpansionisanimportantgoal[2 ] .Al Siallo…     

稀土La对45Cr2NiMoVSi热作模具钢力学性能的影响

研究了稀土La对45Cr2NiMoVSi钢的强度、硬度、塑性和冲击韧度的影响。在相同的热处理工艺条件下,分别加入3种不同含量的稀土La,与不添加稀土La的45Cr2NiMoVSi钢的力学性能进行对比。结果表明：稀土La加入量在适当的范围内可显著提高45Cr2NiMoVSi的力学性能,稀土La加入量为0.20%（质量分数）时,45Cr2NiMoVSi钢可获得最好的综合力学性能。     

Microstructures of worn surface and wear debris of as-cast Al-17Si-xLa alloys under unlubricated conditions

1　INTRODUCTIONAl Sialloyshavebeenwidelyusedasthetribo logicalcomponentsininternalcombustionenginesfortheirhighresistancetowearandseizure ,andhighspecificstrength .Therefore ,thewearbehaviorsofAl Sialloysagainstvariouscounterfaces (typicallyacastironcounterface)havebeeninvestigatedexten sively[16 ] .Themutualtransferofmaterialbetweentwoslidingcounterfacesisinvariablyinvolvedinawearprocess ,especiallyunderdryorunlubricatedconditions ,leadingtotheformationofamechanicallymixedlayerattheworn…     

稀土La对3Cr2W8V热作模具钢组织和性能的影响

研究了在3Cr2W8V热作模具钢中分别加入3种不同含量稀土La后,对组织、强度、硬度、冲击韧度和塑性的影响,并在相同的热处理工艺条件下,与不添加稀土La的3Cr2W8V钢进行对比。研究结果表明:稀土La加入量在适当的范围内可使组织得到明显细化,强度、冲击韧度和塑性有显著提高而硬度无明显变化,当稀土La加入量为0.20%时,3Cr2W8V钢可获得最好的综合力学性能。     

Microstructures and properties of Sn-Ag-Cu lead-flee solder alloys containing La

Trace amounts of La were utilized to improve the melting behaviors, microstructures, tensile properties and microhardness of Sn-3.0Ag-0.5Cu lead-free solder alloy. La has little effect on the melting behavior of Sn-3.0Ag-0.5Cu alloy according to the differential thermal analysis （DTA） tests. The X-ray diffraction （XRD） patterns show that β-Sn, Ag3Sn and Cu6Sn5 coexist in the as-cast solder alloys and LaSn3 phases emerge when adding 0.4% La. The microstructures modified by La are more uniform and much finer than that of baseline alloy, and the coarse LaSn3 particles with complex dendrites are observed by optical microscopy （OM） and scanning electron microscopy （SEM） when the addition of La is up to 0.4%. The composition of the LaSn3 phases is identified by energy-dispersive spectroscopy （EDS）. There are considerable improvements in mechanical properties with 0.05% and 0.1% addition, but degenerations by adding 0.4%La. The Vickers microhardness of β-Sn and eutectic area are both enhanced with the addition of La and the microhardness of LaSn3 is much larger than those of β-Sn and eutectic area.     

稀土对ZAlSi12Cu2Mg1陶瓷层性能的影响

通过在Na2SiO2电解液体系中同时添加0．2g／L的Ce^3＋和不同含量的La^3＋以调整电解液组成，研究了Na2SiO3电解液中添加稀土离子对ZAlSi12Cu2Mg1合金微弧氧化陶瓷层相结构和力学性能的影响。结果表明，电解液中添加Ce^3＋和La^3＋，可以显著提高陶瓷层质量，其中添加0．2g／L的Ce^3＋和0．3g／L的La^3＋，所得陶瓷层主要由α—Al2O3、γ-Al2O3、Al2SiO3和非晶相组成，陶瓷层厚为157μm，硬度（HV）为947，经6000r磨损后，ZAlSi12Cu2Mg1合金基体的磨损量为102．2mg，而陶瓷层S1磨损量为19．7mg，仅为铝合金基体的19％。     

热处理对La0．7Mg0．3Ni2．8Co0．5贮氢合金电化学性能的影响

La0．7Mg0．3Ni2．8Co0．5贮氢电极合金经过适当热处理后(1123K)，最大放电容量、循环稳定性、高倍率放电性能(HRD)、交换电流密度(I0)以及极限电流密度(IL)都有明显改善，铸态合金电极的最大放电容量为392mAh／g，放电电流密度，Id=2000mA／g时，HRD2000=74．0％，I0=266．7mA／g，IL=3425．5mA／g；经1123K保温8h退火的合金电极的最大放电容量提高到414mAh／g，HRD2000=76．2％，I0=407．9mA／g，IL=3753．6mA／g。X射线衍射(XRD)分析表明，衍射峰宽度随着退火温度的升高而变窄，其原因是合金经退火处理相结构的变化和成分的均匀化。     

La2O3-Gd2O3-Mo secondary emission material

A new kind of materials La2O3-Gd2O3-Mo has been produced by powder metallurgy method.The composition and microstructure of the material were studied by XRD and SEM.It shows that no chemical reaction takes place among La2O3,Gd2O3,Mo and the rare earth oxides exist along molybdenum grain boundaries and in the pores.The emission property measurement results of this material show that adding rare earth oxide into molybdenum can improve the secondary emission coefficient of the emitter,and the emission property depends on the activation temperature.After La2O3-Gd2O3-Mo was activated at 1360℃,the maximum secondary emission coefficient can be high to 2.62,which has exceeded that for practical uses(2.0).