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101.
102.
针对北京东方化工厂乙烯装置汽油分馏塔、稀释蒸汽发生系统以及急冷水、酸性水pH值等在运行中出现的问题,说明了问题的原因所在。通过优化操作、改造等方式对系统进行了整改,阐述了整改后的效果。 相似文献
103.
Effect of Zn and Pb as alloying elements on the electrochemical behavior of brass in NaCl solutions 总被引:4,自引:0,他引:4
The electrochemical behavior of brasses with various Zn content (5.5–38 mass%) and brass (Cu–38Zn) with different Pb contents (1–3.4 mass%) in 0.6 M NaCl was investigated. The effects of temperature, immersion time, and concentration of chloride ions on the behavior of the different alloys were studied. The pitting corrosion behavior of Cu–Zn alloys and leaded–brass alloys in 0.6 M NaCl solution was also investigated. Open-circuit potential measurements (OCP), polarization techniques and electrochemical impedance spectroscopy (EIS) were used. The results show that the increase in the Zn content increases the corrosion rate of the brass alloys in chloride solutions, while the increase of Pb content in Cu–38Zn–Pb decreases the corrosion rate of the alloy. Long immersion time of the alloys in the aqueous electrolyte improves their stability due to the formation of passive film on the alloy surface. The breakdown potential is shifted to more negative direction with increasing the Zn content, whereas it shifts towards positive values with increasing Pb content. Equivalent circuit model for the electrode/electrolyte interface under different conditions was proposed to illustrate the electrochemical processes taking place at the interface. The electrochemical behavior of the different alloys was discussed in view of the fitting results. 相似文献
104.
Study on corrosion resistance and roughness of micro-plasma oxidation ceramic coatings on Ti alloy by EIS technique 总被引:2,自引:0,他引:2
Micro-plasma oxidation (MPO) technique has been developed quickly in recent years. The produced ceramic coatings are reported to possess fine properties and promising application prospects in many fields. The aim of this work is to study the corrosion resistance and the roughness of the micro-plasma oxidation ceramic coatings on Ti alloy by electrochemical impedance spectroscopy (EIS) technique. Compound ceramic coatings were prepared on Ti-6Al-4V alloy by pulsed bi-polar micro-plasma oxidation in NaAlO2 solution. The phase composition and element distribution in the coating were investigated by X-ray diffractometry and electron probe micro-analyzer. EIS of the coatings was measured through CHI604 electrochemical analyzer in 3.5% NaCl solution. The ceramic coating is composed of a large amount of Al2TiO5 and a little α-Al2O3 and rutile TiO2. The coating is of double-layer structure with the loose outer layer and the dense inner layer. The thickness of the coatings is reduced when the working frequency or the cathode pulse current density is increased, while the thickness is increased when the frequency or the anode current density is increased. The established “equivalent circuit” of the coatings is consistent with the double-layer structure. The electric charge transfer resistance (Rt) in the equivalent circuit can be used to assess the corrosion resistance of the coatings, which is consistent with the result of the polarizing curves test. And the empirical exponent (n1) of the constant phase element (Q1) in the equivalent circuit can be used to assess the surface roughness of the coatings, which is consistent with the surface SEM analysis of the coatings. 相似文献
105.
钼酸盐与其他缓蚀剂协同缓蚀效应的研究 总被引:6,自引:0,他引:6
简要介绍了钼酸盐缓蚀剂的缓蚀机理,并对钼酸盐与其他缓蚀剂协同缓蚀效应的研究作了综述。 相似文献
106.
The influences of the growing process of sulfate-reducing bacteria (SRB) in seawater system on the medium state and corrosion behavior of carbon steel were studied by detecting solution state parameters and using corrosion electrochemical methods. The growing process of SRB in the seawater shows the three stages of growing, death and residual phases. The solution state parameters of the concentration of sulfide, the pH value and the redox potential changed during the three stages of the SRB growing process. And the corrosion rate of D36 carbon steel was accelerated during the growing phase and stable during the death and residual phases. The results indicate that the medium state and the corrosion rate of the steel do not depend on the number of active SRB, but depend on the accumulation of the metabolism products of SRB. 相似文献
107.
108.
In the in situ leaching (ISL) method, pore water ionic content is determined in small cavities drilled in mortar/concrete specimens. Prior investigations have demonstrated the ISL applicability to obtain pH and nitrite ion concentration in concrete/mortar pore water. The application of the method is extended here to determine pore water chloride ion concentration (and pH) within practical test times in mortars and concretes prepared in the laboratory and in concrete cores extracted from a bridge deck in deicing salt service. Spatial resolution for the determination of composition profiles is also illustrated. Modeling of the ISL process indicates that chloride binding accelerates the approach toward a terminal cavity concentration, reducing test duration to practical lengths for moderate permeability concretes. This acceleration can be attributed to maintaining a higher gradient of free chloride near the cavity wall due to the release, during leaching, of previously bound chloride. Consequently, there is a faster chloride buildup in the cavity water compared with the no-binding case. Experimental chloride and pH results obtained by the ISL test in mortar samples show good agreement with those from the pore water expression (PWE) method. Also, examples are presented of application of ISL data to obtain chloride binding isotherms, and pore water chloride to hydroxide ratio relevant to assessing conditions for corrosion of steel reinforcement. The ISL method presents a less costly and less disruptive alternative to PWE for pore water analysis. It is noted, however, that in a few instances ISL could not be implemented because of excessive absorption of cavity water by the surrounding medium. 相似文献
109.
110.
Comparative electrochemical studies of zinc chromate and zinc phosphate as corrosion inhibitors for zinc 总被引:4,自引:0,他引:4
The anticorrosive performance of two inhibitive pigments, zinc chromate and zinc phosphate, was compared using electrochemical impedance spectroscopy (EIS) and the scanning vibrating electrode technique (SVET) in pigment extracts in 0.1 M NaCl. It was observed that zinc was protected from corrosion in both extracts. In tests using hot dip galvanised steel painted with an epoxy primer incorporating the pigments, the SVET detected the anodic and cathodic distribution along the scribes, although no significant differences were observed among the various primers. On the contrary, EIS was able to distinguish processes occurring on the metal surface exposed by the scribe in different samples. For primers with anticorrosive pigment, a time constant at high frequencies was attributed to a layer of protective nature, probably formed by metal ions from the substrate and inhibitive ions leached from the anticorrosive pigments. 相似文献