Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.     

长江口水域多光谱遥感水深反演模型研究

利用Landsat-7 ETM 遥感影像反射率和实测水深值之间的相关性可以探测水深。该文介绍单波段、双波段比值和多波段3种线性回归模型以及动量BP人工神经网络水深反演模型。选择长江口北港河道上段作为研究区,利用上述模型,分两种情况进行水深反演:一是以河道全部历史样本建模;二是将河道按自然水深划分为浅水区和深水区分别建模。结果表明:神经网络模型预测精度高于线性回归模型;水深分区后线性回归和神经网络模型预测误差均有所减小。     

Ammonium regeneration in intertidal sediments of the Yangtze estuary during air-exposure

The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification rate (˜500 nmol N cm⁻³ day⁻¹), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×10⁵ t N year⁻¹ in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to the estuarine ecosystem.     

大别山造山带前陆深地震反射剖面

在大别山南部和扬子地块前陆实施的深地震反射剖面(140 km)揭示出大别山造山带前陆地壳的精细结构。总体北倾的地壳内部结构与向北缓倾的叠瓦状莫霍面反射揭示出扬子陆块向北俯冲的行迹。莫霍面向北插入大别山造山带下与南大别山地壳内南倾反射震相叠置,构成交叉反射图像,刻画出扬子前陆与大别山造山带的碰撞构造面貌。     

河流形态的分维及与洪水关系的探讨——以长江中下游为例

河流水系形态特征可以通过河流的分形特征来反映,分形维数则是河流分形特征的量化表示,其与河流洪水之间存在着一定的关系。以长江中下游为例,利用网格覆盖法计算出长江中下游河流分维,分析了长江中下游河流的分形特性,并在此基础上结合长江中下游洪水分析不同水系特征下洪水的特点。研究结果表明,一般来说河道分维越大、河网分维越小,洪水发生可能性则越高。     

长江中下游夏季高温灾害机理及预测

利用我国1961-2003年夏季（6—8月）高温资料，建立长江中下游地区主要城市强高温及高温过程较完整的时间序列，探讨了该地区主要城市高温气候特征。分析该地区南京、杭州、南昌等城市夏季高温灾害机理，东亚副热带高压是造成长江中下游地区城市夏季高温的主要影响系统。在此基础上用均生函数-最佳子回归集构造预测模型，预测夏季月高温出现日数，通过42a高温资料预报检验，有较好的预测效果，值得在业务中应用。     

长江三角洲地区水和热通量的时空变化特征及影响因子

文中利用改进的K B模式和牛顿扩散方法及 196 1年以来的长江三角洲 (2 8～ 33°N ,118～ 12 3°E)地区的 4 8个测站的常规气象资料 ,估计了该地区近 4 0a来的蒸散量和感热通量。结合该地区的气温、太阳辐射等气候资料和 196 0年以来该区域土地资源利用变化等有关信息对该地区的潜热通量和感热通量的时 空间变化特征及其可能成因进行了综合分析。结果认为该地区自 2 0世纪 70年代开始平均蒸散量有逐渐减小的趋势 ,与 1980年相比 ,1998年区域年平均蒸散量减小了 2 4mm。区域平均感热通量与蒸散量相比在此期间变化并不明显。通过对该地区的云量、太阳辐射及土地利用变化资料分析认为 ,造成该地区平均蒸散量减少趋势的的原因之一是用于蒸发的能量即太阳辐射的减少 ,而造成太阳辐射减少的可能原因为云量及大气透明度的变化所至 ;原因之二是该地区地表覆盖条件的改变。近 2 0a来 ,该地区的水田、旱地及水域面积占总面积的比率分别减少 1.35 3% ,4 .4 4 2 %和2 .5 97% ,而城镇建设、工矿及其它建设用地面积则增加 3.345 %。耕地及水面的减小和城镇及建设用地面积的增加从整体上使区域平均蒸发量减少。     

长江中游湖泊沉积微结构特征与沉积环境

在长江中游的洪湖、东湖、网湖和大九湖等四个地点取得湖沼沉积物的钻孔样品,用偏光显微镜下和电子显微镜观察微结构特征并以此解释三种湖相粘土的成因和沉积环境的变化。在长江沿岸湖泊中,0.4~ 0.5kaBP以来形成的浅色粘土的微结构类型主要有 :显微层理构造、颗粒的定向性、较大的微孔隙和颗粒粒径,面与面或边与边接触方式。物源主要来自河流带来的泥沙.当时河湖相通,河流入湖水沙量大。 1~ 2.5kaBP期间形成的青色粘土的典型微结构是 :凝胶结构、絮凝结构、细颗粒粒径和小孔隙、低球度和淡水中心冈硅藻。主要是有机质胶体与粘土胶体相互作用形成的。此期间,河流带入湖泊的泥沙少,江汉平原拥有一个开阔、稳定、浮游生物较多的淡水湖泊环境。 0.4~ 1kaBP期间形成的黑色粘土的主要微结构类型是 :凝胶结构、大的圆孔隙和植物纤维的生物框架结构、呈双峰分布的孔隙。它主要是由于维管束植物残体大量积累形成的。当时江汉平原湖泊湖水变浅,大量挺水植物生长,有些湖泊沼已经沼泽化了。鱼骨框架结构证明,在 2.9~ 4kaBP的全新世温暖期山间盆地大九湖出现大量鱼类,但并没有导致喜温鱼类向上游明显迁徙。     

中下扬子区二叠系露头层序地层研究

按新近国际年代地层划分方案（ICS，2000），下扬子区二叠纪地层自下向上分为3统，9阶和相对应的华南传统6阶划分。二叠系从阿瑟尔阶至长兴阶（44Ma)共划分出14个三级层序，每个三级层序平均时限约为3.14Ma，其中“紫松阶”）相当阿瑟尔＋2／3萨克马尔阶）1个（船山组中上部）、“隆林阶、（相当1／3萨克马尔阶＋阿丁斯克阶）2个（分别对应船山组上部和梁山组或镇江组）、“栖霞阶”（相当库班甘德阶＋1／3罗德阶）3个（栖霞组），“茅口阶”（相当于2／3罗德阶＋沃德阶＋卡皮丹阶）4个（孤峰组，茅口组，堰桥组，银屏组和武穴组），吴家坪阶2个（龙潭组或吴家坪组），长兴阶2个（长兴组或大隆组）；共归并为4个层序组（sequence set)。     

运用层序不对称性分析海平面变化特征

目前研究海平面变化的方法尚不能精确确定海平面变化，对记录海平面变化的沉积体或层序物质组成及结构特点的研究尚显薄弱。在分析层序不对称性与海平面变化的关系基础，提出层序不对称系数S0，认为海平面的升降变化对浅水沉积区影响显著，其结果必然造成层序S0的增加；海平面的升降变化对沉水沉积区影响不大，层序S0较为恒定。对进行详细研究中扬子区S0分布特点，运用S0曲线计算了中扬子区海平面变化特点，并与其他方法进行对比，认为可以用S0判断水体相对深浅，分析海平面变化。