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71.
Fractionation of partly hydrolysed polyvinyl acetate (PVA) was performed by warming of its aqueous solutions. The following properties of the obtained fractions were determined: viscosity, molecular weight and molecular weight distribution, surface tension, and absorbance in the IR range. The blockiness of the polymer molecules, characterized by their behaviour towards iodine-containing systems such as I2,-H3BO3 and I2,-KI, was estimated. Fractionation of the aqueous solutions of PVA by warming is based mainly on the different internal molecular structure of the separated products, i.e. on the length of the vinyl acetate blocks in the PVA molecules and, to a lesser extent, on the degree of hydrolysis and the degree of polymerization. The more blocklike are the PVA molecules, the less compatible are the polymers in the PVA-hydroxypropyl methylcellulose (HPMC)-water system. At phase separation in this sytem the PVA molecules which are not compatible with HPMC are, in the first place, those of the highest blockiness. 相似文献
72.
Wire-shaped zinc samples were resistively volume heated as part of a fast-capacitor discharge circuit. Time-resolved measurements with submicrosecond resolution of the current through the specimen, the voltage drop across it, and the thermal expansion of the specimen as a function of time allow determination of the enthalpy, electrical resistivity, and density at different temperatures up to superheated liquid states of zinc far above the normal boiling point. High static pressures, up to 3800 bar of the ambient medium water, were used. An estimate of the critical pressure for zinc is given by investigations of the stability of the sample with a framing CCD camera, taking pictures of different samples varying the ambient static pressure. The critical volume and the critical temperature are obtained by means of an extrapolation of measured data at different pressures.Paper presented at the Fourth International Workshop on Subsecond Thermophysics, June 27–29, 1995, Köln, Germany. 相似文献
73.
富集孢粉化石的一种方法 总被引:2,自引:0,他引:2
本论述了孢粉,沟鞭藻化石与矿物颗粒相互分离的方法,并与传统的氢氟酸冷处理方法进行实验对比。结果表明,该方法摒弃有毒重液,提高了化石收获率。 相似文献
74.
75.
The bulk modification of SBS rubber with maleic anhydride in a mixing chamber of a Haake rheomixer was studied. The effect of temperature, maleic anhydride, and benzoyl peroxide concentrations on the grafting efficiency was evaluated. High grafting efficiency was achieved when the ratio of peroxide and maleic anhydride concentration was high. On the other hand, on this condition high insoluble fraction was generated. The addition of a diamine, 4,4′‐diaminediphenylmethane to the reaction mixture minimizes the amount of insoluble polymer. However, the grafted MAH content also decreases. The graft copolymer was characterized by infrared spectroscopy and the grafting extension was determined by titration. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2953–2960, 2002; DOI 10.1002/app.10355 相似文献
76.
用毛细管流变仪研究了乙基纤维素(EC)及其高密度聚乙烯(HDPE)复合物,纤维素芳族酯(CAE)及其聚碳酸酯(PC)复合物的剪切流变特性和机理。结果表明,EC对HDPE/EC复合物的粘度影响不大,而少量(5%)CAE的加入使PC/CAE复合物粘度大大下降,且复合物流变曲线呈现新的特征。 相似文献
77.
A two-dimensional model was applied to simulate the liquid core reduction(LCR) technology of bloom CC using ANSYS software.The deformation characteristics of bloom under different liquid fraction and reducing amount are obtained.The results indicate that the main deformation condition of bloom shell is compressive strain,mainly undertaken by the liquid core,which increases with the enhancement of reducing amount.Solidified shell takes minor deformation.The longitudinal section of bloom appears sunken and the narrow side bulges,which grow serious when the liquid fractionincreases. 相似文献
78.
79.
降凝剂对高蜡稠油的改性效果及机理研究 总被引:5,自引:0,他引:5
实验研究了工业品原油降凝剂WHP改善含蜡56.9%、其中96.6%为正构烷烃的胜利郑王庄稠油流动性的效果。WHP含乙烯/醋酸乙烯/乙烯醇嵌段聚醚三元共聚物30%-35%。在60℃将WHP加入稠油中,测定其凝点和32℃、0-42.6 s^-1范围5个剪切速率下的黏度,均随WHP加量的增加(50-300 mg/L)而降低,200 mg/L为最佳加量,在该加量下0.32 s^-1黏度由34.16 Pa·s降至79.2 mPa·s,凝点(℃)、屈服值(Pa)、稠度系数(Pa·s^n)分别由49.0、32.42、31.57降至39.5、0.1297、0.02142,流型指数由0.1176升至0.9790。由黏温曲线求出,加入200mg/L WHP使该稠油析蜡点由65℃降至58℃,反常点由70℃降至50℃。根据空白和加剂原油扫描电镜照片显示的蜡晶形态,利用共晶机理分析讨论了WHP这种高分子表面活性剂的降凝、降黏、改善流动性的作用。图3表3参5。 相似文献
80.
利用FTA方法对脱液机的各种故障进行系统分析,建立了脱液机的故障树,并对故障树进行定性分析.找出了影响脱液机可靠性的主要因素,提出了提高脱液机可靠性的相应措施. 相似文献