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991.
Rangam Rajkhowa Radhika Naik Lijing Wang Suzanne V. Smith Xungai Wang 《应用聚合物科学杂志》2011,119(6):3630-3639
Silk is a structural protein fiber that is stable over a wide pH range making it attractive for use in medical and environmental applications. Variation in amino acid composition has the potential for selective binding for ions under varying conditions. Here we report on the metal ion separation potential of Mulberry and Eri silk fibers and powders over a range of pH. Highly sensitive radiotracer probes, 64Cu2+, 109Cd2+, and 57Co2+ were used to study the absorption of their respective stable metal ions Cu2+, Cd2+, and Co2+ into and from the silk sorbents. The total amount of each metal ion absorbed and time taken to reach equilibrium occurred in the following order: Cu2+ > Cd2+ > Co2+. In all cases the silk powders absorbed metal ions faster than their respective silk fibers. Intensive degumming of the fibers and powders significantly reduced the time to absorb respective metal ions and the time to reach equilibrium was reduced from hours to 5–15 min at pH 8. Once bound, 45–100% of the metal ions were released from the sorbents after exposure to pH 3 buffer for 30 min. The transition metal ion loading capacity for the silk sorbents was considerably higher than that found for commercial ion exchange resins (AG MP‐50 and AG 50W‐X2) under similar conditions. Interestingly, total Cu2+ bound was found to be higher than theoretically predicted values based on known specific Cu2+ binding sites (AHGGYSGY), suggesting that additional (new) sites for transition metal ion binding sites are present in silk fibers. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
992.
993.
解廷秀 《玻璃钢/复合材料》2011,(6):13-19
通过选用含不同官能团的硅烷偶联剂3-甲基丙烯酰氧丙基三甲氧基硅烷(MPS)、γ-氨丙基三甲氧基硅烷(APS)和γ-氯丙基三甲氧基硅烷(CPS)处理玻璃纤维,然后通过原位聚合的方法制造了连续纤维增强的聚甲基丙烯酸甲酯(PMMA)复合材料。研究结果表明,经过这三种偶联剂处理的玻璃纤维与基体树脂在界面分别形成了化学键、范德华力和氢键。红外、动态力学分析和扫描电镜研究表明,复合材料的界面粘接强度顺序为:MPS>CPS>APS。MPS处理的复合材料具有最高的弯曲强度,而CPS处理的复合材料具有最佳的冲击韧性和断裂伸长率。 相似文献
994.
采用连续式蒸汽爆破法对棉皮纤维进行预处理,将其与聚丁二酸丁二醇酯(PBS)进行共混,制备了PBS/棉皮纤维复合材料。利用扫描电镜对棉皮纤维及PBS/棉皮纤维复合材料的微观形貌进行了分析,并研究了棉皮纤维含量对PBS/棉皮纤维复合材料熔融及结晶行为、热降解性能、热变形温度以及力学性能的影响。结果表明:经蒸汽爆破处理后,棉皮纤维直径变小,比表面积变大,在PBS基体中分散均匀;棉皮纤维的存在改变了PBS的熔融峰值温度,提高了其结晶度;与纯PBS相比,PBS/棉皮纤维复合材料在高温条件下的热稳定性得到改善维,卡软化温度和弯曲强度提高。 相似文献
995.
M. Hadjoudja H. A. Mesbah M. Bederina Z. Makhloufi 《Journal of Adhesion Science and Technology》2013,27(21):2307-2328
Technically, the dune sand concrete (DSC) can replace the traditional concrete in some construction cases. Even economically, this material is also cheaper, since dune sand (with its large availability in the Saharan regions), is used as a single aggregate. In addition, the incorporation of steel fibers into this material can remedy its brittle behaviour and limit the microcracking caused by the high shrinkage that typically characterizes the sand concrete. Moreover, the use of the experimental design approach to model the influence of the fibers content [Vb], the filler content [LF] and the Water/Cement ratio [W/C] on the shrinkage is very attractive.For this, tests of endogenous shrinkage (ES) and the free shrinkage (FS) were carried out on various compositions of dune sand concrete reinforced by steel fibers (FRDSC). The results are then compared with those of the dune sand concrete (DSC) taken as a concrete control. Generally, the addition of steel fibers significantly reduces the shrinkage of the dune sand concrete. At the young age, only small differences were observed when fiber contents passed from a dosage to another; however, at the long term, the fibers effect became more marked. In addition, the use of the experimental design theory was very beneficial for modeling the effect of the studied factors on the studied responses. Although [LF] and [W/C] also significantly influenced the total shrinkage of RFDSCs, [Vb] showed the greatest effect. The recorded optimums in the study field were 0.6, 200?kg/m3 and 1% were for [W/C], [LF] and [Vb] respectively. 相似文献
996.
《Journal of Adhesion Science and Technology》2013,27(4):383-394
Interfacial bond strength is often a performance-limiting factor of carbon-fiber-reinforced composites. This limitation is most prevalent when higher-modulus fibers or relatively unreactive matrix resins, such as engineering thermoplastics or high-temperature thermoset resin systems, are used. Radio-frequency (RF) glow discharge plasmas are an effective means of modifying carbon-fiber surface chemical characteristics to promote adhesion. It has been previously shown that oxidizing plasmas are especially effective compared with electro-oxidative treatments for treating carbon fiber surfaces as revealed by titrations, electron spectroscopy, wetting, and inverse gas chromatography measurements. This study evaluated the effectiveness of CO2 plasmas on two experimental high-modulus carbon/graphite fibers and correlated the plasma surface modification with interfacial adhesion in an epoxy matrix composite system. The results show that CO2 plasma treatment increased the surface oxygen content by nearly a factor of 2 over typical electro-oxidation treatments. The increased oxygen is mainly in the form of hydroxyl, ketone, and carboxyl-like moieties. Unidirectional composites were prepared from as-received and plasma-modified versions of each type of experimental fiber. The composites containing plasma-modified filaments exhibited 1.5-3.0 times the strength of composites fabricated with untreated or electro-oxidized filaments in transverse-flexural tests. Short-beam shear strength increased by two times over those with as-produced filaments and is equivalent to that of composites containing electro-oxidized filaments. 相似文献
997.
《Journal of Adhesion Science and Technology》2013,27(2):155-166
Anisotropically conductive adhesives were developed by magnetic alignment of conductive nickel particles in a non-conductive epoxy matrix. Conductivity occurs in the direction of the magnetic field applied to the adhesive film. The effects of magnetic and conducting nickel filler type (i.e. powders, filaments, flakes, and fibers), resin viscosity, and the magnitude of aligning magnetic field on the electrical properties of the resulting anisotropic adhesive were investigated. The electrical resistance of the anisotropic adhesive was measured using the four-point probe method. The resistance of the filled adhesive decreased with increasing viscosity and the intensity of the magnetic field. 相似文献
998.
The effect of polycrystalline mullite fibers (PMFs) on the properties of vitreous bonds and vitrified CBN composites was investigated. The results show that the addition of PMFs can increase the porosity of composites and reduce the fluidity of binders. The vitrified composites incorporating 6.4 wt% PMFs display excellent mechanical strength, which is enhanced by 21.2% compared with that of composites without PMFs sintered at the optimal sintering temperature. Meanwhile the thermal expansion coefficient of vitrified bond reduces from 6.256×10−6 °C−1 to 4.805×10−6 °C−1 with increasing fraction of PMFs. The improvement of mechanical strength is associated with the change of cracking mechanisms of the composites with fibrous crystals and the existence of several observed mechanisms, including fiber pull-out, fiber bridging and rupture. 相似文献
999.
Elisabet Brännvall Disa Tormund Marie Bäckström Jonas Bergström Anna Tubek‐Lindblom 《木材化学与工艺学杂志》2013,33(2):99-112
Abstract Unbleached softwood kraft pulp was fractionated in hydrocyclones into a fine fraction, enriched in earlywood fibers, and a coarse fraction, enriched in latewood fibers. The response to individual bleaching chemicals and the bleachability in bleaching sequences of the pulp fractions was studied. The light absorption coefficient, light scattering coeffient, and brightness were higher in the unbleached fine fraction than in the coarse fraction. Hydrogen peroxide managed to reduce the light absorption coefficient of the earlywood enriched fine fraction more efficiently than that of the latewood enriched fraction. In the TCF‐sequence the light absorption coefficient of the fine fraction was reduced to the level of the coarse fraction at a given consumption of bleaching chemicals. In the ECF‐sequence the difference in light absorption coefficient remained between the fractions. At a given consumption of bleaching chemicals, the fine fraction had higher brightness than the coarse fraction, 2%‐ and 1%‐units on the ISO‐scale in the TCF and ECF bleaching sequence, respectively. 相似文献
1000.
以钛酸四丁酯为钛源、Al(NO3)3为铝盐,采用静电纺丝法在600℃焙烧条件下制备出铝盐掺杂TiO2棒状纤维.利用扫描电子显微镜、透射电子显微镜和X射线衍射仪等对纤维的形貌和组成进行了表征.研究了室温下铝盐掺杂TiO2纤维对NOx的气体敏感性能,并对其气敏机理进行了分析.结果表明:铝盐掺杂TiO2纤维为一维棒状结构,直径约为200nm.在室温条件下对NOx有较好的气敏响应,响应时间最短为6s,最低检测体积分数可达9.7×10-7.锐钛矿相的存在有利于NOx的吸附-脱附.铝盐掺杂TiO2纤维大幅提高了对NOx的气敏响应灵敏度,是一种在室温条件下极具潜力的气敏材料. 相似文献