The process window for diamond deposition from the vapor phase with sulfur in the C–H–O feed gas mixtures

Theoretical predictions using a modified radical species ternary diagram for C–H–O system indicate that addition of sulfur expands the C–H–O gas phase compositional window for diamond deposition. Sulfur addition to no-growth domain increases the carbon super-saturation by binding the oxygen and the addition of sulfur to the non-diamond domain reduces the heavy carbon super-saturation by decreasing C_nH_m species concentration in the gas phase. The overall effect of sulfur addition to gas phase mixtures is characterized as that of oxygen addition to the C–H system, i.e. expansion of the compositional window over which diamond can be deposited from the gas phase. In addition, the increasing sulfur concentration to diamond domain feed gases beyond 2000 ppm did not affect the steady state gas phase composition but the quality of diamond was reduced.     

中国冷库的现状与发展趋势

本文从的设计建造、制冷工艺和管理维护这三个方面，介绍了近三年来中国冷库的现状，说明中国冷库正朝着灵活、自动化、节能和环保的方向进一步发展。     

Temperature Oscillation Calorimetry: Robustness analysis of different algorithms for the evaluation of the heat transfer coefficient

Applicability of different temperature oscillation calorimetry algorithms, previously proposed in the literature, for the evaluation of the heat transfer coefficient during the course of the reaction, is analysed by referring to the experimental data from a methyl methacrylate polymerisation reactor.Results are coincident in the nominal case (no errors on data), while differences appear in the elaboration of real data. The effect of uncertainty in the experimental data has been simulated in terms of error on the amplitude and on the phase of reactor and jacket temperature profiles.This approach allows to indicate algorithms having the best robustness properties and to give an explanation of phase errors in terms of a lumped parameter which accounts for different phenomena, not included in the basic hypotheses of the method. Based on this observation, a procedure to eliminate this source of errors from experimental data is proposed for the more general algorithm presented to handle oscillating temperature profiles generated by different techniques.     

Kinetics of catalytic reactions with two types of sites: nonuniform surfaces

Several aspects of heterogeneous catalytic kinetics over induced nonuniform surfaces are considered. The reaction mechanism is thought to occur through a surface collision of species, adsorbed on two distinct surface sites, which display nonuniform behavior. The expressions for rates of elementary reactions have been deduced within the framework of the surface electronic gas model, which accounts for the case of inhomogeneous surface. Equations for catalyst activity in the range of medium coverage have been derived and compared with the power-law model.     

钨系延期药预点火反应机理研究

通过程控升温模拟点火条件，根据ＤＳＣ图谱分析，找出主要反应区的温度范围。研究结果表明，钨系延期药预点火反应是一个真正的固－固反应。     

抗盐降滤失剂SDX的研究与应用

介绍了抗盐降滤失剂SDX的合成方法与现场应用简况,评价了SDX的抗温、抗盐、防塌及配伍性能。试验结果表明,SDX能耐150℃以上的高温,可抗盐至饱和,具有良好的降滤失和抑制性能,与其它处理剂的配伍性好,适用于各种水基泥浆。     

铌酸对酯化反应催化性能的研究

研究了新型固体酸催化剂铌酸对乙醇及异戊醇与乙酸酯化反应的催化性能、研究表明热处理温度对水洗法制备的铌酸催化剂的催化活性有显著影响,在350℃处理时活性达到极大值.与HZSM-5相比,铌酸催化剂不仅在乙醇和乙酸的气相酯化反应中表现出良好的催比性能,而且在异戊醇和乙醇的液相酯化反应中亦表现出较好的催化活性和稳定性.     

Simulation of toxic gases and vapours removal by activated carbon filters

The system ASC carbon filter/cyanogen chloride was studied by simulation. Three filter configurations and several models, taking into account Langmuir adsorption and second-order reaction between the adsorbed toxic vapour and the active metal on the surface, were developed.The effects of axial dispersion, number of reaction units, film mass transfer units and intraparticle mass transfer resistance on the breakthrough time were studied.Simulation results show that a complex model should be used in order to predict with reasonable accuracy the protection imparted by these filters.     

激光激活化学反应分离同位素反应池参数确定及其影响

在气体分子运动论、碰撞理论、流体力学和光化学反应、热化学反应及高斯光束理论基础上建立了位于激光器腔内外的反应池的设计尺寸同各相关参量和同位素产物产率、同位素分离系数间的关系，并给出了一些计算结果。