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31.
(E)-2-壬烯酸是有机合成的一种重要中间体,我们利用Knoevenagel反应机理,改进了(E)-2-壬烯酸的合成工艺,在不使用脱水剂条件下,使用少量吡啶作催化剂,获得了83%的反应收率。  相似文献   
32.
You-Yi Xia 《Materials Letters》2007,61(21):4321-4324
This paper describes a solution-phase approach to the synthesis of selenium nanoparticles by reducing selenious acid solution with ascorbic acid in the presence of silk fibroin. The monodispersed spherical selenium colloid particles obtained were very stable in silk fibroin solution and characterized by Atomic force microscopy and X-ray techniques. The influences of temperature and ultrasonication on the morphology of selenium nanoparticles were also discussed. The experiments showed that the selenium nanoparticles with various morphologies could be obtained under different temperatures and the appropriate ultrasonication time was 60 min. This result indicated that the silk fibroin molecules intimately associated with the surface of the selenium particles and controlled the growth particles.  相似文献   
33.
A semianalytical model is developed for computing drawdowns in and around a partially penetrating large diameter well. The new model can take into account an unsteady pumping discharge and thus drawdowns during recovery can be computed. This model can also yield the unsteady contributions from well and aquifer storages to the pumped discharge. While developing the model, the flow from the bottom of the well is also accounted.  相似文献   
34.
Multicomponent mass transfer accompanied by instantaneous chemical reactions in a small drop has been modeled and simulated for the case where two different solutes diffuse from a continuous phase into the drop and react rapidly with a third reactant in the drop. The computational results obtained by Galerkin’s finite element method are reported in terms of concentration profiles, the locations of reaction front, the cumulative mass flux, and the enhancement factor. The effects of physical parameters, such as diffusivities of the solutes and the reactant, the interfacial concentration of solutes, and the relative amount of the reactant, on the calculated quantities are discussed.  相似文献   
35.
研究了Zr-2/Cr扩散偶在1023-1123K范围内的反应扩散,用扫描电镜观察反应宽度,用能谱仪(EDS)测定了反应层Zr,Fe和Cr沿扩散方向的浓度分布,研究了反应层的生长动力学,结果表明,反应层生长基本符合抛物经规律,生长过程受扩散控制,用Boltzman-Matano-Heumann模型计算了Cr在反应层Zr(Fe,Cr)2中的互扩散系数D,得到了互扩散系数D与温度的Arrhenius方程,由计算的扩散数据与Cr在Zr中形成稀固溶体时Cr的扩散数据比较可知,Cr在金属间化合物Zr(Fe,Cr)2中的扩散比在稀因溶体中的扩散快5个数量级。  相似文献   
36.
37.
This paper introduces results on placement and communications minimization for systems of affine recurrence equations. We show how to classify the dependences according to the number and nature of communications they may result in. We give both communication-free conditions and conditions for an efficient use of broadcast or neighbor-to-neighbor communication primitives. Since the dependences of a problem can generally not be all communication-free, we finally introduce a heuristic to globally minimize the communications based on the classification of dependences.  相似文献   
38.
张更新 《电信科学》1996,12(7):55-60
本文首先给出了VSAT和VSAT卫星通信网的基本概念和VSAT的特点,发展背景及主要类型;然后着重介绍了VSAT的主要关键技术和VSAT在ISDN、个人通信和互连LAN中的应用;在本文最后对VSAT的主要发展趋势进行了展望。  相似文献   
39.
Reorganisation and evolution of class hierarchies is important for object-oriented system development and has received considerable attention in the literature. The contributions of this paper are: (1) a formal study of a set of extension relations and transformations on class hierarchies; (2) a presentation of a small set of primitive transformations which form a minimal and complete basis for the extension relations; and (3) an analysis of the impact of these transformations at the object level.The study leads to a better understanding of evolution and reuse of object-oriented software and class hierarchies. It also provides a terminology and a means of classification for design reuse. The theory presented in this paper is based on the Demeter data model, which gives a concise mathematical foundation for classes and their inheritance and part-of relationships. Parts of the theory have been implemented in the Demeter System TM C++, a CASE tool for object-oriented design and programming.  相似文献   
40.
Fast and accurate methods for predicting traffic properties and trend are essential for dynamic network resource management and congestion control. With the aim of performing online and feasible prediction of network traffic, this paper proposes a novel time series model, named adaptive autoregressive (AAR). This model is built upon an adaptive memory‐shortening technique and an adaptive‐order selection method originally developed by this study. Compared to the conventional one‐step ahead prediction using traditional Box–Jenkins time series models (e.g. AR, MA, ARMA, ARIMA and ARFIMA), performance results obtained from actual Internet traffic traces have demonstrated that the proposed AAR model is able to support online prediction of dynamic network traffic with reasonable accuracy and relatively low computation complexity. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
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