Optimal Control of Solar Sludge Dryers

Optimal control (OC) methodology is used to develop a control policy for a batch-operated solar sludge dryer with ventilation as the dominant control. Batch performance criteria and instantaneous optimization criteria are developed for two economic environments: quota limited and capital limited. The general formulation, as well as simplifications resulting from the multiplicative form of the evaporation (drying) rate model, are presented. The multiplicative form results in a single constant number, called here “control intensity,” which is used to guide the on-line control decisions. These decisions turn out to be independent of the dry solids content (DSC) of the sludge. Further simplification, by assuming a strictly constant weather, is used to demonstrate the general effects of the economic and physical (weather) environment on the solution.

The OC approach is used to address, via simulation under realistic weather conditions, several design, operation, and pricing problems. In particular, the following have been considered: sizing of the ventilation fans, determination of a fair fee for sludge disposal, finding the best final DSC, and evaluating the effect of the price of electricity. Regarding the particular location represented by the data, it has been shown that the installed capacity of the ventilation fans should be increased and that there seems to be sufficient economic incentive for solar drying.     

Acidic and basic hydrolysis of poly(N‐vinylformamide)

Poly(N‐vinylformamide) (PNVF) was synthesized and hydrolyzed to poly(vinylamine) (PVAm) in both HCl and NaOH solutions. The hydrolysis kinetics and the equilibrium hydrolysis were examined experimentally at different temperatures, polymer concentrations, and acid‐ or base‐to‐amide molar ratios. The hydrolysis kinetics strongly depended on temperature, polymer, and HCl or NaOH concentrations, but showed little dependence on PNVF molecular weight. The acid hydrolysis of PNVF exhibited limited conversions because of the electrostatic repulsion among the cationic amine groups generated during hydrolysis and proton hydrates. In the basic hydrolysis, complete amide conversions were observed when the NaOH/amide molar ratios were greater than unity. The effects of temperature and PNVF concentration on the equilibrium amide conversion appeared to be negligible in both acidic and basic hydrolysis. The equilibrium conversions of base hydrolysis were higher than those of acidic hydrolysis under the same reaction conditions. At NaOH/amide ratios of less than unity, the equilibrium hydrolysis experiments revealed that one base molecule could induce the hydrolysis of more than one amide group. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3412–3419, 2002     

碱-碳酸盐反应热力学讨论

应用热力学方法探讨了温度对碱 碳酸盐反应的影响 ,反应温度升高时 ,反应的推动力减弱。对碱与碳酸盐发生反应生成沉淀时所需碱的浓度以及温度的影响进行了讨论。 2 98K ,pH≥ 10 .6时 ,碱 碳酸盐反应能发生 ,反应温度升高 ,碱 碳酸盐反应所需碱的浓度相应增大。对氢氧化锂与碳酸盐反应可能生成碳酸锂沉淀时溶液的碱的浓度作了计算 ,2 98K ,pH≥ 13.1时 ,氢氧化锂与碳酸盐反应除生成水镁石和方解石外还能生成碳酸锂沉淀 ,反应温度升高时 ,反应生成碳酸锂沉淀所需碱的浓度变化不大     

Comparisons of Urban Travel Forecasts Prepared with the Sequential Procedure and a Combined Model

Detailed analyses and comparisons of urban travel forecasts prepared by applying the state-of-practice sequential procedure and the solution of a combined network equilibrium model are presented. The sequential procedure for solving the trip distribution, mode choice and assignment problems with feedback is the current practice in most transportation planning agencies, although its important limitations are well known. The solution of a combined model, in contrast, results from a single mathematical formulation, which ensures a well-converged and consistent result. Using a real network, several methods for solving the sequential procedure with feedback are compared to the solution of the combined model ESTRAUS. The results of these methods are shown to have various levels of instability. The paper concludes with a call for a new paradigm of travel forecasting practice based on an internally consistent model formulation that can be solved to a level of precision suitable for comparing alternative scenarios.     

理性密钥共享的扩展博弈模型

理性密钥共享体制通过引入惩罚策略使得参与者不会偏离协议,常采用的惩罚是一旦发现有人偏离就立即终止协议.这种惩罚策略有时导致惩罚人自身利益严格受损,从而降低了对被惩罚人的威慑.为了克服这一弱点,本文以扩展博弈为模型分析了理性密钥共享体制.首先给出(2,2)门限的理性密钥共享体制,证明了所给的协议是该博弈的一个序贯均衡,即经过任何历史之后坚持原协议仍然是每一个参与者的最优选择.特别地,在发现有人偏离后,协议所给出的惩罚策略既可以有效惩罚偏离者又能够完全维护惩罚人的利益.这是本文对前人设计的理性密钥共享体制的一个重要改进.然后针对将协议扩展到(t,n)门限情形,实现密钥分发人离线,达到计算的均衡等相关问题给出了一般的解决方案.     

基于强化学习的无线传感器网络入侵检测攻防博弈研究

无线传感器网络易遭到各种内部攻击,入侵检测系统需要消耗大量能量进行攻击检测以保障网络安全。针对无线传感器网络入侵检测问题,建立恶意节点（malicious node,MN）与簇头节点（cluster head node,CHN）的攻防博弈模型,并提出一种基于强化学习的簇头入侵检测算法——带有近似策略预测的策略加权学习算法（weighted policy learner with approximate policy prediction,WPL-APP）。实验表明,簇头节点采用该算法对恶意节点进行动态检测防御,使得博弈双方快速达到演化均衡,避免了网络出现大量检测能量消耗和网络安全性能的波动。     

反倾岩质边坡弯曲倾倒-剪切滑移破坏分析方法研究

目前反倾岩质边坡弯曲倾倒破坏分析方法仍以基于极限平衡理论的悬臂梁模型为主,但大多未考虑坡脚岩层的剪切破坏。为准确评价该类边坡的稳定性,建立考虑坡脚岩层剪切破坏的分析计算方法。首先,根据岩层变形破坏特征,将边坡分为后缘稳定区、中部弯曲倾倒区和前缘剪切区3个区域;其次,建立弯曲倾倒-剪切滑移破坏模式的稳定性分析方法;最后,通过工程实例验证,并进行参数分析。研究结果表明:提出的分析方法与工程实际符合性较好;边坡在倾角较陡、坡角较大时稳定性最差,坡角对边坡稳定性影响大于岩层倾角的影响;岩层厚度及层面内摩擦角增加有利于边坡稳定性,且会扩大坡脚剪切区范围。研究成果对反倾岩质边坡破坏的防治具有实践指导意义。     

Solid-liquid phase equilibria of benzene + 2-methyl-2-propanol system under high pressures

Solid-liquid phase equilibria of the benzene + 2-methyl-2-propanol system have been investigated at temperatures from 278 to 323 K and pressures up to 300 MPa using a high-pressure optical vessel. The uncertainties of the measurements of temperature, pressure and composition are within ±0.1 K, ±0.5 MPa, and ±0.001 mole fraction, respectively. The freezing pressure at a constant composition increases monotonously with pressure. The eutectic point shifts to a higher temperature and benzene-rich composition with increasing pressure. In order to describe the pressure-temperature-composition relation of high-pressure solid-liquid phase equilibria, a new simple equation has been proposed as follows:

An experimental study of the thermodynamic properties of 1,1-difluoroethane

Experimental vapor pressures andP--T data of an important alternative refrigerant, 1, 1-difluoroethane (HFC-152a), have been measured by means of a constant-volume method coupled with expansion procedures. SixtyP--T data were measured along eight isochores in a range of temperaturesT from 330 to 440 K, at pressuresP from 1.6 to 9.3 MPa, and at densities from 51 to 811 kg·m^–3. Forty-six vapor pressures were also measured at temperatures from 320 K to the critical temperature. The uncertainties of the temperature and pressure measurements are within ±7mK and ±2kPa, respectively, while the uncertainty of the density values is within ±0.1%. The purity of the sample used is 99.9 wt%. On the basis of the measurements along each isochore, five saturation points were determined and the critical pressure was determined by correlating the vapor-pressure measurements. The second and third virial coefficients for temperatures from 360 to 440 K have also been determined.     

A refined evaluation of the gas-phase water-dimerization equilibrium constant within non-rigid BJH- and MCY-type potentials

The flexible BJH- and flexible or semiflexible MCY-type water-water potentials (4 potential modifications in each nonrigid family, i.e., altogether 12 potentials) are used for evaluation of the gas-phase water-dimerization equilibrium constants. The potential-energy term is adjusted for best reproduction of the available experimental equilibrium constants. An independent test using the experimental steam second-virial coefficient isotopic difference shows that the adjustment also improves the computational evaluation of the difference. A set of dimerization equilibrium constants is suggested over a wide temperature interval (based on the BJH/G, MCY-B, or MCYB potential modifications). The best reproduction of the experimental equilibrium constants (in conjunction with good performance for the second-virial isotopic difference) is produced by the BJH/G potential. The results are applicable to various problems such as the formation of water clusters in large-scale natural and artificial water jets (e.g., hydrogen-oxygen rocket motors, orbital capsule water dumps, water ejection from a comet nucleus) or in atmospheric chemistry.