圆柱壳弹性波超材料分级排列的带隙拓宽方法研究

圆柱壳弹性波超材料的弯曲波带隙拓宽问题限制其满足实际工程中的宽频隔振要求,针对该问题,本文首先研究了基于局域共振机理的圆柱壳弹性波超材料弯曲波带隙特点,研究局域谐振器质量和弹簧劲度系数的关系,然后将周期分级排列的组合方式应用于圆柱壳类弹性波超材料的带隙拓宽中,并利用有限元法进行能带结构和振动传输特性计算.研究结果显示：该方法可实现弯曲波带隙的拓宽;利用组合法构建的轴向周期分级排列圆柱壳弹性波超材料可实现705-1226Hz频率范围内弯曲波的高效衰减,带隙拓宽至分别为单一谐振器的2.55倍,这表明该方法在宽频减振方面具有明显优势,应用前景广阔.     

Plasmon‐Enhanced Spectroscopies with Shell‐Isolated Nanoparticles

Shell‐isolated nanoparticle‐enhanced Raman spectroscopy (SHINERS), due to its versatility, has been able to break the long‐term limitations of the material‐ and substrate‐specific generalities in the traditional field of surface‐enhanced Raman spectroscopy. With a shell‐isolated work principle, this method provides an opportunity to investigate successfully in surface, biological systems, energetic materials, and environmental sciences. Both the shell material and core morphology are being improved continuously to meet the requirements in diverse systems, such as the electrochemical studies at single crystal electrode surfaces, in situ monitoring of photoinduced reaction processes, practical applications in energy conversion and storage, inspections in food safety, and the surface‐enhanced fluorescence. Predictably, the concept of shell‐isolated nanoparticle‐enhancement could be expanded to the wider range for the performance of plasmon‐enhanced spectral modifications.     

Large‐Scale Fabrication of Core–Shell Structured C/SnO2 Hollow Spheres as Anode Materials with Improved Lithium Storage Performance

Due to the high theoretical capacity as high as 1494 mAh g^?1, SnO₂ is considered as a potential anode material for high‐capacity lithium–ion batteries (LIBs). Therefore, the simple but effective method focused on fabrication of SnO₂ is imperative. To meet this, a facile and efficient strategy to fabricate core–shell structured C/SnO₂ hollow spheres by a solvothermal method is reported. Herein, the solid and hollow structure as well as the carbon content can be controlled. Very importantly, high‐yield C/SnO₂ spheres can be produced by this method, which suggest potential business applications in LIBs field. Owing to the dual buffer effect of the carbon layer and hollow structures, the core–shell structured C/SnO₂ hollow spheres deliver a high reversible discharge capacity of 1007 mAh g^?1 at a current density of 100 mA g^?1 after 300 cycles and a superior discharge capacity of 915 mAh g^?1 at 500 mA g^?1 after 500 cycles. Even at a high current density of 1 and 2 A g^?1, the core–shell structured C/SnO₂ hollow spheres electrode still exhibits excellent discharge capacity in the long life cycles. Consideration of the superior performance and high yield, the core–shell structured C/SnO₂ hollow spheres are of great interest for the next‐generation LIBs.     

复合材料基镂空网壳结构的建模与仿真

为进一步挖掘复合材料构件的轻量化和成型形态等结构特性,提出了突破传统满铺结构的曲面镂空等厚度网壳构件的数学模型,并对其成型表面的形态和效果进行了实验验证.运用三维空间曲面映射法建立笛卡尔参数坐标系,在单位球面上建立并推导了网壳构件曲面测地线弧及测地线交角的高斯第I基本型模型,利用MATLAB对该模型的正交编织算例进行了仿真和构型验证.结果表明:除仿真构件边缘平齐一致性不足外,该仿真构型与预期结果构型轮廓相符.为进一步验证该模型用于实际生产制造的可行性,采用预浸纤维复合材料带为基材,经编织、固化生产出该模型的5×5网壳结构成品试件.该研究为复合材料壳体超轻化且低成本结构成型提供了新思路,可为网壳类结构制件的支撑筋/骨架设计提供建模新方法.     

基于喉部出口流场的核电机组凝汽器壳侧蒸汽流场数值研究

对凝汽器喉部流动进行数值模拟并提取数据,将喉部出口流场数据作为入口边界条件,对凝汽器壳侧蒸汽流场进行了更准确的数值模拟和研究。结果表明,入口蒸汽均匀分布情况下,蒸汽在4个管束模块区域均呈现向心式的流动趋势;蒸汽入口不均匀分布情况下,蒸汽在两侧蒸汽通道内和中间蒸汽通道内有下冲流动,形成了对管束模块的包绕流动。因此,对于开展与凝汽器壳侧蒸汽流场分布相关性能的研究,建议基于喉部出口流场对凝汽器壳侧蒸汽流动进行数值模拟。     

Mesoporous Hollow Sb/ZnS@C Core–Shell Heterostructures as Anodes for High‐Performance Sodium‐Ion Batteries

Combining the advantage of metal, metal sulfide, and carbon, mesoporous hollow core–shell Sb/ZnS@C hybrid heterostructures composed of Sb/ZnS inner core and carbon outer shell are rationally designed based on a robust template of ZnS nanosphere, as anodes for high‐performance sodium‐ion batteries (SIBs). A partial cation exchange reaction based on the solubility difference between Sb₂S₃ and ZnS can transform mesoporous ZnS to Sb₂S₃/ZnS heterostructure. To get a stable structure, a thin contiguous resorcinol‐formaldehyde (RF) layer is introduced on the surface of Sb₂S₃/ZnS heterostructure. The effectively protective carbon layer from RF can be designed as the reducing agent to convert Sb₂S₃ to metallic Sb to obtain core–shell Sb/ZnS@C hybrid heterostructures. Simultaneously, the carbon outer shell is beneficial to the charge transfer kinetics, and can maintain the structure stability during the repeated sodiation/desodiation process. Owing to its unique stable architecture and synergistic effects between the components, the core–shell porous Sb/ZnS@C hybrid heterostructure SIB anode shows a high reversible capacity, good rate capability, and excellent cycling stability by turning the optimized voltage range. This novel strategy to prepare carbon‐layer‐protected metal/metal sulfide core–shell heterostructure can be further extended to design other novel nanostructured systems for high‐performance energy storage devices.     

Nanoconfined Nickel@Carbon Core–Shell Cocatalyst Promoting Highly Efficient Visible‐Light Photocatalytic H2 Production

The realization of large‐scale solar hydrogen (H₂) production relies on the development of high‐performance and low‐cost photocatalysts driven by sunlight. Recently, cocatalysts have demonstrated immense potential in enhancing the activity and stability of photocatalysts. Hence, the rational design of highly active and inexpensive cocatalysts is of great significance. Here, a facile method is reported to synthesize Ni@C core–shell nanoparticles as a highly active cocatalyst. After merging Ni@C cocatalyst with CdS nanorod (NR), a tremendously enhanced visible‐light photocatalytic H₂‐production performance of 76.1 mmol g^?1 h^?1 is achieved, accompanied with an outstanding quantum efficiency of 31.2% at 420 nm. The state‐of‐art characterizations (e.g., synchrotron‐based X‐ray absorption near edge structure) and theoretical calculations strongly support the presence of pronounced nanoconfinement effect in Ni@C core–shell nanoparticles, which leads to controlled Ni core size, intimate interfacial contact and rapid charge transfer, optimized electronic structure, and protection against chemical corrosion. Hence, the combination of nanoconfined Ni@C with CdS nanorod leads to significantly improved photocatalytic activity and stability. This work not only for the first time demonstrates the great potential of using highly active and inexpensive Ni@C core–shell structure to replace expensive Pt in photocatalysis but also opens new avenues for synthesizing cocatalyst/photocatalyst hybridized systems with excellent performance by introducing nanoconfinement effect.