Adsorption of H2S or SO2 on an activated carbon cloth modified by ammonia treatment

The aim of this research is to investigate how ammonia treatment of the surface can influence the activity of a viscose-based activated carbon cloth (ACC) for the oxidative retention of H₂S and SO₂ in humid air at 25 °C. Surface basic nitrogen groups were introduced either by treatment with ammonia/air at 300 °C or with ammonia/steam at 800 °C. The pore structure of the samples so prepared was examined by adsorption measurements. Changes in the surface chemistry were assessed by X-ray photoelectron spectroscopy, X-ray absorption spectroscopy and temperature programmed desorption (TPD). The change of ACC activity could not be merely attributed to surface nitrogen groups but to other changes in the support. Ammonia/steam treatment improved ACC performance the most, not only by introducing nitrogen surface groups, but also by extending the microporosity and by modifying the distribution of surface oxygen groups. Successive adsorption-regeneration cycles showed important differences between oxidative retention of H₂S and SO₂ and the subsequent catalyst/support regeneration process.     

纳米材料的力学性能

综述了纳米晶体材料和纳米碳管材料的力学性能研究的最新进展。实验数据表明纳米晶体材料的强度与其晶粒尺寸大小的关系并不遵循Hall-Petch方程。相对于常规晶体材料 ,纳米材料的超塑性发生在更低的温度和更高的应变速率下。理论计算和实验数据表明 :纳米碳管是一种有着高刚性、高强度、高韧性和低密度的材料。纳米晶体材料和纳米碳管的异常的力学性能已经有了一些应用实例     

油气田开发中的CO2腐蚀及防护技术

综述了二氧化碳均匀腐蚀和局部腐蚀的机理，分析了二氧化碳腐蚀的各种影响因素，并对二氧化碳腐蚀的防护技术进行了概括，着重介绍了缓蚀剂防护技术研究进展，并提出了研究CO2腐蚀及其缓蚀剂应注意的几个问题。     

Copper phthalocyanine as corrosion inhibitor for ASTM A606-4 steel in 16% hydrochloric acid

A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10^–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations.     

CZF90测井中子发生器使用寿命浅谈

Ｃ／Ｏ测井中采用同步测量技术来分析非弹性γ与俘获γ，但在一些ＭＳＩ Ｃ／Ｏ测井中发现非弹性γ的一小部分或一大部分超前于非弹性门而进入俘获门，我们把这一问题叫做“错位”。“错位”使得Ｃ／Ｏ的ＣＩ值不正常，测井曲线不合格。这样的仪器不能用来测井。吉林油田测井公司碳氧比维修班成功地解决了Ｃ／Ｏ仪器“错位”等技术难题，在该油田所使用的ＣＺＦ９０－９４－０９发生器已测井８８口，累计打靶时间２３０ｈ，并且至今     

45号钢二次枝晶臂间距与冷却速度的关系

本文利用可控平均冷却速度的单向凝固实验炉测定了４５号钢在不同平均冷却速度下的冷却曲线，由此得到其在凝固期间的平均冷却速度Ｒ，相应地测量了不同平均冷却速度下试样的二次枝晶臂间距Ｓ２，通过回归，得到了如下关系式：Ｓ２＝７２７Ｒ－０．４１，并将引式成功地应用于实际生产中。     

生物降解型聚碳酸顺丁烯二酸亚乙酯 1、合成和表征

用CO_2、环氧乙烷、顺丁烯二酸酐进行三元共聚首次得到聚碳酸顺丁烯二酸亚乙酯(PECM),并用IR、~1H NMR、DSC等进行了表征,共聚物链中CO_2和MA单元随机分布,不饱和单元可在0～0.5mol分数之间调节。共聚过程不发生双键交联和构型转化。环氧乙烷的转化率可高达到93％。控制PECM链上的双键含量并使之发生自由基加成反应,得到对热较稳定的可溶性产物。     

A theory for the formation of tetrahedral amorphous carbon including deposition rate effects

A theoretical model is presented to describe the effect of ion beam bombardment rate on the formation of tetrahedral amorphous carbon (ta-C) films. The critical ion energy, E_c, corresponding to a 50% sp³ content in the films, is found to be dependent on both the effective thermal resistance and the ion beam bombardment rate. In the model, the ‘window’ width in the ion energy scale for the formation of ta-C material increases with decreasing deposition rate and with a reduction in the effective thermal resistance, until limited by lower and upper boundary thresholds. Experimental data are reproduced by the model. The plasmon energy, which correlates with sp³ fraction, is found experimentally of be higher for lower deposition rate and smaller effective thermal resistance. Data points for high sp³ content ta-C films deposited on silicon substrates at room temperature occupy a region in the ion energy-deposition rate (E-r) diagram similar to that predicated from the theory.