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61.
The dye-sensitized TiO2 complex films were prepared by the dye coat onto TiO2 surfaces,and the sensitizing mechanism and adsorption properties of the dye-sensitized TiO2 complex films were inverstigated.The influence of the application conditions of dye adsorbed on TiO2 films on the amount of dye adsorption was discussed.Experimental results show that the concentration,the temperature of dye solutions and the dipping time of TiO2 films in the dye solutions have a significant influence on the amount of dye adsorption.Cell test indicates that the conversion efficiency of light to electricity increases with the amount of dye adsorption. 相似文献
62.
含羧基的聚乙烯醇胺肟螯合纤维吸附钯的研究 总被引:4,自引:0,他引:4
研究了含羧基的聚乙烯醇胺肟(PVAAO-AAc)螯合纤维对钯的吸附,讨论了pH、温度、浓度、吸附时间对吸附率及回收率的影响。确定了最佳吸附条件,吸附钯的纤维用5%硫脲+0.10mol/L硝酸溶液可以解吸。 相似文献
63.
64.
吸附制冷循环的热力计算及热力学评价方法探讨 总被引:4,自引:0,他引:4
在化工吸附,吸附热力学及Polanyi吸附位势理论的基础上,介绍吸附制冷基本型循环,推演其参数坐标图,进而分析,给出其主要性能指标的热力计算,然后以热力学的逆卡诺循环和内可逆三热源循环模型为指针,对此制冷循环进行考察。并结合热力计算对其热力学完善性做出评价,从而给出了吸附制冷基本型循环合适的热力学评价方法。 相似文献
65.
PC/PET共混物的非等温结晶动力学 总被引:9,自引:0,他引:9
采用等速变温DSC法对PC/PET共混体系的非等温结晶动力学进行了研究,结果表明,从玻璃态结晶时,随着PC含量的增加,PET组分的结晶速率先增加后降低。耐从熔体结晶时,体系的结晶速率随着PC含量的增加而增加,讨论了PC对PET组分结晶过程的影响。 相似文献
66.
67.
Shihong XU Pengshou XU Mingrong JI Xianming LIU Maosheng MA Jingsheng ZHU Yuheng ZHANG Structure Research Laboratory University of Science Technology of China Hefei ChinaZhenjia XU Institute of Semiconductor Academia Sinica Beijing China 《材料科学技术学报》1993,9(6):437-440
The alkali-metal Na adsorption on Si(100)2×1 surface and its promoted oxidation and Si oxidegrowth have been investigated by means of thermal desorption,work function,Auger electronspectroscopy and photoemission electron spectroscopy.The experimental data showed that therewas a new state,interface electron state,near the Fermi level after the deposition of Na atoms.It wasfound that the presence of Na always caused an increase of the oxygen initial uptake whereas thepromotion of Si oxide growth was observed only at the coverage of Na greater than 0.5 ML.A newmechanism of Na-promoted Si oxide growth is suggested in this paper. 相似文献
68.
César I. Beristain Ebner Azuara Hugo S. Garcia & Eduardo J. Vernon-Carter 《International Journal of Food Science & Technology》1996,31(5):379-386
The water and oil uptake of mesquite and arabic gums in powdered form was studied at temperatures of 23, 35 and 45°C. A previously proposed equation to predict osmotic equilibrium was tested using the experimental data with both gums and a good statistical fit was obtained. Mesquite gum showed the highest water and oil absorption at all temperatures studied. Temperature dependence of the reciprocal of the S1 and WL∞ were determined using an Arrhenius equation. The activation energy for water and oil absorption for gum arabic was 21.98 and 39.57 kJ mol−1 , compared to that of mesquite gum having values of 15.79 and 46.16 kJ mol−1 , respectively. A second order kinetic model was obtained for water and oil absorption for both gums. 相似文献
69.
There is a need for developing low cost, easily and abundantly available, yet efficient, adsorbents for the removal of phosphates during the tertiary treatment of wastewaters. The tamarind nut shell activated carbon (TNSAC) prepared on a laboratory scale has been used to evaluate its performance for phosphate adsorption. This paper describes the laboratory production of this adsorbent material in its various forms, and discusses the effects of the TNSAC process variables (the unrinsed and rinsed forms of the TNSAC and the impregnation ratio) on its performance in adsorbing phosphate. The material has been shown to be a good alternative adsorbent. As much as 95% phosphate removal by the unrinsed TNSAC is possible in about 30 min under the test conditions. The phosphate adsorbing capacity is about two times higher for the unrinsed TNSAC in comparison to the rinsed TNSAC. The adsorption rates, however, transit to extremely low rates towards the end when equilibrium conditions could be attained in about 2 h contact time. The phosphate removal mechanics are adsorption and precipitation/ion exchange when unrinsed TNSAC is used, and adsorption alone for the rinsed TNSAC. The maximum phosphate removal is found to take place at an impregnation ratio of 1.0 for both forms of the TNSAC. 相似文献
70.
Christina Dirk‐Faitakis D Grant Allen 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(7):737-745
This paper describes the development and simulation of an unsteady state biofilter model used to predict dynamic behaviour of cyclically‐operated biofilters and compares it with experimental results obtained from three, parallel, bench‐scale biofilters treating both periodically fluctuating concentrations and constant concentrations of an α‐pinene‐laden gas stream. The dynamic model, using kinetic parameters estimated from the constant concentration biofilter, was able to predict the performance of cyclic biofilters operating at short cycle periods (ie, in the order of minutes and hours). Steady state kinetic data from a constant concentration biofilter can be used to predict unsteady state biofilter operation. At a 24 h cycle period, the dynamic model compared well with experimental results. For long cycle periods (ie, hours and days), removal efficiency decreased after periods of non‐loading: the longer the period of non‐loading, the poorer the biofilter's performance at the re‐commencement of pollutant loading. At longer time scales the model did not effectively predict transient behaviour, as adsorption and changes in kinetic parameters were not accounted for. Modelling results showed that similar biofiltration performance for the cyclic and constant concentration biofiltration of α‐pinene is expected for biofilters operating solely in the first order kinetics regime. Poorer performance for cyclic biofilters following Monod kinetics spanning the entire kinetics range is expected as the cycle amplitude increases. The most important parameters affecting the performance of a cyclically‐operated biofilter with short cycle periods are: amplitude of cyclic fluctuations, Cg, max/Cg, relative value of the half‐saturation constant in the Monod expression, Ks, and effective diffusivity of α‐pinene in the biofilm, De. Copyright © 2005 Society of Chemical Industry 相似文献