用纯氧化铕模拟基体AES法测定氧化铥中的钬、饵、镱、镥和钇

用于发射光谱分析的氧化铥基体不但难于寻找,而且价格昂贵.本文用氧化铕模拟氧化标基体的办法,其测定结果与别的方法基本符合.为寻找代替氧化铥基体提供了一条途径.     

Full color white light,temperature self-monitor,and thermochromatic effect of Cu+ and Tm3+ codoped germanate glasses

Lighting sources with full-color visible output are widely preferred in practical applications. In addition, modern lighting sources also tend to be intelligentized, and the intelligentization asks for smart luminescence materials. In this work, we attempt to develop novel full-color emitting material with temperature sensing and thermochromatic ability. To this end, the Cu²⁺ is successfully reduced to Cu⁺ which is incorporated into the germanate glasses. The glasses are prepared via a melt-quenching technique using graphite powders as reducing reagent. The supper-broadening of the excitation and the emission spectra of Cu⁺ in the germanate glasses are observed. Full-color emission is realized by introducing Tm³⁺ as co-dopant to provide the blue component in the spectra. The energy transfer behavior between Cu⁺ and Tm³⁺ is investigated, and it is found that these two luminescence centers are independently existent without energy transfer between them. The chromatic properties of the Cu⁺/Tm³⁺ co-doped glasses are tuned by Tm³⁺ concentration and excitation wavelength. The temperature sensing based on the fluorescence intensity ratio technique is demonstrated, and a constant sensitivity for the temperature detection is obtained. Moreover the thermochromatic property is also investigated, and it is found that the studied Cu⁺/Tm³⁺-doped glasses exhibit excellent thermochromatic performance.     

Bi3+掺杂蓝色荧光粉GdVO4:Tm3+的发光性能

采用共沉淀法制备了Bi3+掺杂的GdVO4:Tm3+荧光粉材料。采用X射线衍射仪(XRD)、扫描电镜(SEM)、荧光光谱仪(PL)对所得荧光粉的晶体结构,颗粒形貌以及发光特性进行了分析。结果表明:Bi3+的掺入不改变GdVO4相的晶体结构,所得的Gd0.99-xVO4:Tm0.013+,Bix3+荧光粉的相结构仍为四方锆型结构。荧光粉体的形貌呈现尺度较均匀的颗粒状,颗粒尺寸约为70 nm。Bi3+的掺入增强了Gd0.99-xVO4:Tm0.013+,Bix3+荧光粉的发光强度,当Bi3+/Tm3+为0.5时,发光强度在波长为476 nm处达到最大值,显示为明亮的篮光。     

低温条件下光学厚度对Tm3+：YAG材料光谱烧孔孔深的影响

通过理论与实验研究了光学厚度对Tm3+：YAG材料光谱烧孔孔深的影响。提出了一种用于分析光学厚度对光谱烧孔孔深影响的新模型。该模型从理论上推导了烧孔孔深与光学厚度的关系。根据提出的理论模型,当温度大于4K时,通过选择合适的光学厚度可以使光谱烧孔孔深得到最大值。最后通过使用合适的激光与Tm3+：YAG材料所形成的光谱烧孔实验证明了实验结果与理论分析是相一致的。     

纵向抽运Tm，Ho：YLF微片激光器激光特性的研究

从速率方程理论出发，得到了抽运功率阈值和激光输出功率的解析表达式。通过钛宝石激光器抽运Tm，Ho：YLF微片，获得90mW的2μm波长激光连续输出。得到了抽运功率和输出功率之间的关系以及抽运光与振荡光之间的转换效率关系。同时也给出了温度对激光输出效率的影响。     

多路Cr,Tm,Ho:YAG激光器合光路的设计

在介绍国外四路Cr,Tm,Ho:YAG激光器的基础上,提出了三种四路Cr,Tm,Ho:YAG激光器合光路经光纤输出的方案,并进行了比较,最终确定了基于平面的四路Cr,Tm,Ho:YAG激光器合光路设计方案。在三路情况下,当单脉冲最大注入能量为100J,重频30Hz时,激光器直接输出功率50.17W,光纤末端输出功率35.65W,耦合效率为71%。经文献调研,目前所达到的输出功率处于国内领先水平。     

2μmTm,Ho∶YLF激光抽运ZnGeP_2光参量振荡技术研究

ZnGeP2晶体具有宽的透明范围(0.7～12μm),较大的非线性系数(d36=75pm/V),最高损伤阈值能量密 度为10J/cm2,较高的热导率(0.18W/(m·K)),因而非常适合作为高功率中红外光参量振荡器(OPO)晶体。理 论上分析了ZnGeP2光参量振荡器相位匹配特性,实现3～5μm连续调谐范围输出的Ⅰ类相位匹配角在52.5～ 55.2°之间。实验上,以15W光纤耦合激光二极管(LD)抽运的2.05μm高重复频率声光调QTm,Ho∶YLF激光 器作为抽运源,其最大平均功率4W,脉冲宽度小于40ns,脉冲重复频率100Hz～10kHz可调。为降低准三能级 系统激光器阈值,提高激光脉冲能量抽取效率,Tm,Ho∶YLF晶体采用液氮制冷方式,工作在77K温度条件下。 非线性频率转换晶体ZnGeP2长15mm,55.7°切割,光参量振荡器谐振腔为平平腔,腔长约20mm。在3.6W的抽 运功率下,脉冲重复频率10kHz,实现了4.1μm附近中红外激光输出,参量光脉冲宽度为20ns,平均输出功率为 0.7W,光 光转换效率为20%,抽运光阈值功率为0.65W。     

掺铥光纤激光器研究进展

介绍了掺铥光纤激光器的基本结构以及工作原理;综述和分析了掺铥光纤激光器的研究国内外进展,阐述了掺铥光纤激光器可以采用几种不同的抽运源进行抽运,即LD抽运源、Nd∶YAG激光器抽运源、掺Yb3+光纤激光器抽运源以及色心、掺铒光纤激光器抽运源等。同时也指出了如何提高激光器输出特性的方法,即进一步改善交叉弛豫率、降低上转换以及热处理等。最后展望了掺铥光纤激光器在生物医学领域的应用前景。     

Effect of heat treatment on crystal phase and photocatalytic activity of Tm doped TiO2 nanoparticles

Abstract

Abstract

Tm doped TiO₂ nanoparticles have been synthesised by hydrolysis-precipitation method. The effect of heat treatment on the crystal phase and photocatalytic activity of Tm doped TiO₂ nanoparticles has been studied. The prepared samples were characterised by transmission electron microscopy, X-ray diffraction, Fourier transformed infrared and diffuse reflection spectrum analysis. The results show that Tm³⁺ doping can effectively inhibit the phase transformation from antase to rutile and decrease the crystallite size of nano-TiO₂ particles. There is an optimal Tm doping (1·4?mol.-%) after calcination at 550°C for the photocatalytic activity of methylene blue degradation.     

2 μm掺铥光纤激光研究进展及其应用

掺铥光纤激光器输出的2 μm波段在医疗、激光雷达、遥感测控和光参量振荡方面有着广泛应用,目前已实现千瓦级的激光输出。文中主要介绍了掺铥光纤激光器的基本结构及工作原理,并综述和分析了国内外掺铥光纤激光器的研究进展,并展望了掺铥光纤激光器的发展。