鄱阳湖湿地溶解性有机质的光化学属性对水体光活性中间体(PPRIs)季节性变化的影响

湿地的水文和水化学在时空尺度上会呈现显著差异,进而会引发光化学反应的变化,光活性中间体(PPRIs)是水体间接光反应的产物,具有极强的氧化性,对水环境中有机物和污染物的归驱具有重要的影响,因此迫切需要探究湿地中PPRIs的产生过程。本研究通过捕获剂法监测了鄱阳湖湿地4个季节水体中3种PPRIs(¹O₂、·OH及³CDOM^*)的产生速率和稳态浓度的变化,并通过紫外吸收光谱、三维荧光光谱、以及傅立叶变换离子回旋共振质谱等技术对水体中可溶性有机质(DOM)组分的化学特征进行分析,揭示了鄱阳湖湿地不同季节水体中的DOM的光化学反应特性及与PPRIs产生的相关性。结果发现:鄱阳湖夏季和秋季水体的pH值、溶解有机碳(DOC)浓度较高,相反,硝酸盐、亚硝酸盐浓度在夏季和秋季较低。夏季和秋季的DOM中芳香族化合物丰度较高,并且木质素丰度明显高于冬季和春季。不同季节鄱阳湖水体有色可溶性有机物产生能力依次为秋季>夏季>冬季>春季。夏季和秋季水体中¹O₂和·OH产生速率和稳态浓度显著高于春季和冬季水体。pH、DOC、E2/E3、脂类、蛋白类及木质素类与PPRIs产生速率展现出了良好的正相关关系,尤其是其中的DOC与木质素类组分;另外在三维荧光指标结果中,荧光指数(FI)和新鲜度指数(β/α)与PPRIs呈现负相关关系,证明FI值越低即DOM陆源性越高、非新生DOM比例越高,则PPRIs产生速率越高。综上,PPRIs的光化学产生与植物源DOM密切相关。与春季和冬季相比,夏季和秋季鄱阳湖水体的有机质高,而其中DOM组分中芳香族化合物丰度较高,主要来自陆生植物和土壤有机质,其有机质的腐殖化水平较高,而在春季和冬季水体有机质主要来自湖泊本身和微生物产生的有机质,属于内源。淹水植物残体降解过程释放的有机组分,对夏、秋季DOM的来源和组成有着极易被忽视的影响和作用,而其中光化学活性较强的有机组分如木质素是造成其PPRIs产率更高的主要原因。     

黄河上游近60年水沙变化特征及其影响因素

由于受人类活动及气候变化影响,黄河上游干流水沙特征发生显著变化。为探究黄河上游水沙变化情况,基于黄河上游5个水文站1964-2019年水沙、遥感影像等数据,利用Mann-Kendall检验法、滑动t检验法、累积距平曲线和双累积曲线等突变检验方法和小波分析法,对黄河上游水沙变化特征进行研究。利用水沙关系曲线及线性回归法等方法估算人类活动和气候对水沙变化的贡献率,并着重讨论梯级水库建设及土地利用变化对水沙的影响。结果表明:1)黄河上游玛曲-小川段流域内降雨量和径流量变化幅度不明显,贵德站、循化站、小川站1986-2019年年均输沙量分别减至1964-1985年的9.8%、24.6%、38.8%,输沙量大大减少。黄河上游玛曲-小川段径流量突变多在1986年,输沙量突变多在1969、1986、2004年,径流量存在8、16、22 a周期,输沙量存在4~8、18~21、27 a周期。2)1969年后,河流输沙能力增强,水沙关系显著改变。在不同时段内,人类活动对径流量变化在1987-2019年贡献率为66.3%,对输沙量变化在1970-1986、1987-2004、2005-2019年的贡献率为72.96%、70.73%、69.7%。人类活动对黄河上游干流水沙影响占据主导因素。3)刘家峡水库淤积最为严重,单库运行期水库淤积量为2.39亿t,排沙比变化范围为1.39%~10.7%。梯级水库联调使得径流量在1964-2004年间减少47.8%,1964-2019年间梯级水库减沙94.8%,梯级水库对输沙量影响远大于对径流量的影响。4)1980-2020年间,草地面积增加了1880.03 km²,增幅3.1%,有利于减少输沙量,草地拦沙效益大于截流效益。     

广州空气污染指数特征及其与地面气压型的关系

根据1950～2000年50多年的降水资料,用Z指数作为旱涝等级划分标准,把雨涝情况划分成4个等级,并在此基础上计算了雨涝发生的范围。通过研究雨涝范围覆盖率变化趋势和特征,诊断我国华南雨涝发生发展趋势和变化程度。研究发现我国华南地区近50年来雨涝覆盖范围有轻微的下降趋势并具有明显的年代际变化特征;冬半年雨涝覆盖范围有较大的增长趋势,特别是1990年代以来这种趋势更强烈;夏半年雨涝范围趋于减少,呈下降态势,但夏季的雨涝范围在扩大,特别是1990年代以来,夏季雨涝范围扩大的趋势较为明显;前汛期雨涝范围有减少的趋势,而后汛期雨涝范围有明显的扩大趋势。     

热带太平洋-印度洋相互关系的年代际改变

用Nino3指数、印度洋单极指数、偶极子指数表示热带太平洋．印度洋SST的年际异常,发现1978年以后ENSO在热带印度洋的信号减弱了,可以解释如下：1978年之前,印度洋和太平洋纬向垂直环流的异常在海洋性大陆附近作齿轮式耦合;1978年以后,由于热带太平洋的上升支的东移,导致两洋的纬向垂直环流异常的耦合减弱。     

A parametric study of the required seating length for bridge decks during earthquake

During the recent major earthquakes, some bridges suffered severe damage due to the pull-off-and-drop collapse of their decks. This is due to the large differential movements of the adjacent spans of bridges during strong shaking compared to the seating lengths provided. The differential movements are primarily due to the different vibration properties of adjacent spans and non-uniform ground excitations at the bridge supports. This paper analyses the effects of various bridge and ground motion parameters on the required seating lengths for bridge decks to prevent the pull-off-and-drop collapse. The random vibration method is used in the analysis. A two-span bridge model with different span lengths and vibration frequencies and subjected to various spatially varying ground excitations is analysed. Non-uniform spatial ground motions are modelled by the filtered Tajimi–Kanai power spectral density function and an empirical coherency function. Ground motions with different intensities, different cross-correlations and different site conditions are considered in the study. The required seating lengths for bridge decks are calculated. Numerical results are presented and discussed with respect to different bridge vibration and ground motion properties. © 1998 John Wiley & Sons, Ltd.     

Effect of urbanization on runoff characteristics of the On-Cheon Stream watershed in Pusan,Korea

This study investigated the effect of urbanization on runoff from the On-Cheon Stream watershed in Pusan, Korea. This watershed has been experiencing considerable urbanization since the 1960s. There are two gauging stations in the watershed. For one of the stations there are recent flow data and for the other flow data were observed in the past. A linear reservoir model was chosen and runoff was analysed for several flood events. The linear reservoir model has been found to generate flood hydrographs accurately for both gauging stations, and its applicability to the study area has also been established. Using two methods of computing effective rainfall or rainfall excess (ϕ-index and constant percentage method), the results of runoff analyses were investigated. The ϕ-index method yielded better results than the constant percentage method. A comparison of hydrographs observed in the past with the simulation results at the Ie-Sup bridge site revealed that the peak discharge increased and the mean lag time of the study area decreased owing to urbanization over the past two decades. It is also possible to evaluate the effect of urbanization quantitatively. © 1998 John Wiley & Sons, Ltd.     

Runoff quality prediction from small urban catchments using SWMM

The RUNOFF block of EPA's storm water management model (SWMM) was used to simulate the quantity and quality of urban storm water runoff from four relatively small sites (i.e. 5·97–23·56 ha) in South Florida, each with a specific predominant land use (i.e. low density residential, high density residential, highway and commercial). The objectives of the study were to test the applicability of this model in small subtropical urban catchments and provide modellers with a way to select appropriate input parameters to be used in planning studies. A total of 58 storm events, measured by the US Geological Survey (USGS), provided hyetographs, hydrographs and pollutant loadings for biological oxygen demand (BOD₅), total suspended solids (TSS), total Kjeldahl nitrogen (TKN) and lead (Pb), and were used for calibration of the model. Several other catchment characteristics, also measured or estimated by USGS, were used in model input preparation. Application of the model was done using the Green–Ampt equation for infiltration loss computation, a pollutant accumulation equation using a power build-up equation dependent on the number of dry days, and a power wash-off equation dependent on the predicted runoff rate. Calibrated quantity input parameters are presented and compared with suggested values in the literature. The impervious depression storage was generally found to be the most sensitive calibration parameter, followed by the Manning's roughness coefficients of conduit and overland flow, the Green–Ampt infiltration parameters and, finally, the pervious depression storage. Calibrated quality input parameters are presented in the form of regression equations, as a function of rainfall depth and the number of antecedent dry days. A total of 16 independent rainfall events were used for verification of the model, which showed a good comparison with observed data for both hydrographs and pollutant loadings. Average model predictions for the four constituent concentrations from the verification runs also showed good agreement with NURP published values in Florida and US sites. © 1998 John Wiley & Sons, Ltd.     

Simulation of the direct runoff hydrograph at basin outlet

A simple model describing the transformation of effective rainfall to direct runoff through the overland flow mechanism is presented. The model is based on the classical representation of a watershed by a combination of planes and channels. The dynamics of overland flow in each plane is simulated by the non-linear kinematic wave, but the outflow from a given plane is concentrated in the middle of the corresponding drainage channel. The water routing in the channels is carried out by a piece-wise linearized formulation in space of the kinematic wave approximation. Using synthetic events on 10 watersheds, the model was tested by comparing it with results obtained by applying the non-linear kinematic wave to all the elements of the watershed. The model was found to be adequate, even in a form that simplifies the geometric features of the planes through an averaging procedure based on the Horton–Strahler ordering scheme of the watershed. © 1998 John Wiley & Sons, Ltd.     

多点地质统计学建模研究进展

从精细油藏描述中地质建模的意义和现状入手,介绍了多点地质统计学建模研究现状及其与传统地质建模方法的差 异。以辽河盆地西部凹陷某蒸汽驱试验区为例,分析了多点地质统计学建模中建模的基础、训练图像的建立、多点地质统计学 建模与传统地质建模相比所具有的优势等内容。指出多点地质统计学在井间预测方面具有明显优于其他传统建模方法的特 点。在文献调研基础上,结合自身工作实践,探讨了多点地质统计学建模目前存在的问题和未来的发展方向。指出未来多点 地质统计学建模的发展方向主要包括多信息综合地质成因分析基础上的训练图像获取、多点地质统计学算法进行改进和完善 和多点地质统计学建模方法应用领域的扩大等。     

1961-2014年石家庄地区降水量的时空变化特征

利用石家庄地区5个代表站1961-2014年的逐日降水资料,采用多种统计分析方法,分析了石家庄地区降水量的时空变化特征,结果表明石家庄地区年降水量从20世纪70年代开始下降,80年代达到最低,90年代有所增加,但也没有明显的上升趋势,21世纪初又开始下降.20世纪70年代降水量的减少春季和秋季贡献最大,80年代降水量的减少和90年代降水量的增加主要是夏季的贡献.石家庄地区年降水量起伏较大,1963年降水量最多,为1038.4 mm,2014年最少,仅为276.2 mm.近54年石家庄年降水量在波动中呈现下降趋势,线性趋势为-11.0 mm/（10 a）,但下降趋势并不明显.石家庄北部年降水量呈上升趋势,市区及东部、南部和西部年降水量均呈下降趋势,变化趋势均不明显.近54年,石家庄春季降水量呈上升趋势,线性趋势为0.9 mm/（10 a）,夏季、秋季和冬季降水量均呈下降趋势,线性趋势分别为-11.9,-1.1和-0.3 mm/（10 a）,上升或下降趋势均不明显.夏季降水减少是导致石家庄年降水减少的主要原因.石家庄四季降水量变化趋势的空间分布具有明显的季节特征和区域特征.石家庄四季降水量均存在显著周期变化.