论土壤硒驱动机制——以河南省崤山地区为例

目前天然富硒土壤评价工作多集中在与人类生活居住有密切关系的覆盖区,在硒源驱动研究方面主要有火山岩型、石煤型、燃煤型、湖潮型、大气降尘型、人工污染型等成因认识,土壤富硒的主因聚焦在硒的次生富集作用与人类活动作用影响上,即聚焦于硒表生循环-地球外动力作用研究,忽略了对地球内动力作用的影响研究。本文以河南省寺河山一带富硒土壤调查评价为基础,广泛收集包括寺河山在内的崤山地区以往所有地质资料,从土壤硒驱动的内、外动力作用同时入手,从宏观尺度上对其驱动机制进行探讨。研究认为,崤山地区土壤Se受热液与断裂构造的双重控制,起源于核幔边界的地幔流体,在自身强大驱动力作用下,携带并沿途不断活化萃取Au、Se等成矿元素,当沿深大断裂上涌进入地壳后则会减压降温由超临界态逐渐相变为热液,开始热液作用形成一系列含Se热液矿产;当到达地表,Se等易被富碳等有机质或富硅等粘土质成分吸附捕获形成含硒土壤,继而进入水圈、大气圈、生物圈等开启表生循环,从而构成一个完整的硒循环过程。在覆盖区因隐伏深大断裂构造不易观察识别而往往被忽略,今后工作中应引起注意。     

Telecommunication interactions between microplates and basal mantle LLSVPs.SCIEI北大核心CSCD

基于海洋地质地球物理观测建立的板块构造理论意味着板块和浅部地幔共同演化,然而地幔底部尤其是大型横波低速异常区(LLSVP)与板块(尤其微板块)运动和演化之间是否存在关联仍有争议。一些研究认为LLSVP长期保持稳定,而另一些模型则认为它与各级板块存在相互作用。为此,本文通过总结前人成果,并基于近期发表的板块重建和地幔对流模型进行进一步分析,探讨微板块运动和LLSVP的演化关系。模拟结果表明,微板块与大板块类似,俯冲后通常会下沉至核幔边界。微幔块会推动地幔底部热的物质聚集并形成大的热化学结构。该热化学结构与层析成像揭示的LLSVP基本吻合。下地幔径向流速场和温度场的二阶结构与地表速度场散度的二阶结构随时间的移动轨迹相似,表明深浅部圈层的耦合演化,但是下地幔结构演化一般会滞后于浅表。在微幔块推挤之下,地幔柱优先沿着地幔底部热化学结构的边缘形成,且有时会被推至热化学结构的内部。地幔柱上升至浅部后,能够导致岩石圈弱化甚至裂解或板块边界跃迁,形成微板块。因此,地幔底部LLSVP不是稳定或静止的,而是与微板块动态协同演化,并通过地幔柱与浅表板块边界发生遥相关,从而控制微板块生成场所。     

Petrogenesis of ore-bearing porphyry of a porphyry Cu deposit at Mujicun in the North China Craton and its geological implicationsSCIEI北大核心CSCD

国内外学者对发育于弧环境和碰撞造山环境的斑岩铜矿成岩机制已取得了深刻的理解,但对产出在克拉通内部的斑岩铜矿成岩机制在认识上还有所欠缺。本文报道了侵位于144Ma木吉村斑岩铜矿内的含矿闪长玢岩的岩石地球化学资料,以揭示木吉村斑岩铜矿的含矿斑岩成因。岩石地球化学资料显示:含矿闪长玢岩具有较低的(^(87)Sr/^(86)Sr)i值(0.70599~70690)和εNd(t)值(-19.4~-14.9),富集轻稀土元素(LREEs)和大离子亲石元素(LILEs),相对亏损元素Y和Yb。木吉村含矿斑岩与王安镇杂岩体镁铁质岩(辉石岩、角闪石岩、辉长岩、辉长闪长岩、安山岩)具有相似的微量元素配分模式、Sr-Nd同位素组成及亲EMⅠ地幔特征,这些岩浆岩呈现持续性的成份演化趋势,反映出它们的同源性。木吉村含矿斑岩及相关的镁铁质岩石具有相对较低的(^(87)Sr/^(86)Sr)i值(0.70564~706897)和εNd(t)值(-19.4~-13.8),显著区别于中上地壳同位素区域。含矿斑岩起源于伸展背景下富集地幔部分熔融形成的玄武质岩浆,其上升过程中遭受了一定程度的下地壳混染。玄武质岩浆在深部岩浆房发生堆晶作用形成具典型堆晶结构的角闪石岩等基性岩,随后在浅部岩浆房经历两阶段辉长岩-辉长闪长岩、安山岩-闪长玢岩系列分离结晶作用形成含矿斑岩。此过程可能是形成华北克拉通木吉村斑岩铜矿含矿斑岩的机制和动力诱因。     

New Insights into the Mesozoic Large-scale Intra-plate Magmatism and Mineralization in South China from Seismic Tomography

A great amount of new S-wave data has been combined to image the mantle structure down to lower mantle depth near the southeastern margin of Eurasia and understand the tectonics in South China since the Mesozoic. Our results reveal a large-scale structure beneath the South China Sea, with a prominent, broad low-velocity feature of at least 1500-km wide in and below the mantle transition zone(MTZ) and a pronounced low-velocity feature of nearly 500-km wide in the lowermost mantle. Together these ...     

Effects of Spin Transition and Cation Substitution on the Optical Properties and Iron Partitioning in Carbonate Minerals

The high-pressure behavior of deep carbonate dictates the state and dynamics of oxidized carbon in the Earth’s mantle, playing a vital role in the global carbon cycle and potentially influencing long-term climate change. Optical absorption and Raman spectroscopic measurements were carried out on two natural carbonate samples in diamond-anvil cells up to 60 GPa. Mg-substitution in high-spin siderite FeCO₃ increases the crystal field absorption band position by approximately 1000 cm     

Discovery of Early Tonian Calc-alkaline and Shoshonitic Metamafic Rocks from the North Purulia Shear Zone, Chhotanagpur Gneissic Complex, Eastern India: Implications of Proterozoic Sub-continental Lithospheric Mantle

Reports of shoshonitic rocks in Precambrian terrains are relatively rare. Pl-Grt amphibolites and Hbl-Bt mafic granulites occurring in the migmatitic gneisses of the Chhotanagpur Gneissic Complex(CGC) show calc-alkaline and shoshonitic characteristics. Relict porphyritic, sub-ophitic and poikilitic textures are noted in these rocks. Their parent magma was emplaced during the waning phase of the regional metamorphism. Geochemically, these metamafics are similar to the Group Ⅲ potassic and ultrapo...     

Simulation of location-specific severe thunderstorm events using high resolution land data assimilation

In this study, the impact of different land initial conditions on the simulation of thunderstorms and monsoon depressions is investigated using the Weather Research and Forecasting (WRF) model. A control run (CNTL) and a simulation with an improved land state (soil moisture and temperature) using the High Resolution Land Data Assimilation System (HRLDAS, experiment name: EHRLDAS) are compared for three different rainfall cases in order to examine the robustness of the assimilation system. The study comprises two thunderstorm cases (one in the pre-monsoon and one during the monsoon) and one monsoon depression case that occurred during the Interaction of Convective Organisation, Atmosphere, Surface and Sea (INCOMPASS) field campaign of the 2016 Indian monsoon. EHRLDAS is shown to yield improvements in the representation of location-specific rainfall, particularly over land. Further, it is found that surface fluxes as well as convective indices are better captured for the pre-monsoon thunderstorm case in EHRLDAS. By analysing components of the vorticity tendency equation, it is found that the vertical advection term is the major contributor towards the positive vorticity tendency in EHRLDAS compared to CNTL, hence improving localised convection and consequently facilitating rainfall. Significant improvements in the simulation of the pre-monsoon thunderstorm are noted, as seen using Automatic Weather Station (AWS) validation, whereas improvements in the monsoon depression are minimal. Further, it is found that vertical advection (moisture flux convergence) is the major driver modulating the convective circulation in localised thunderstorm (monsoon depression) cases and these dynamics are better represented by EHRLDAS compared to CNTL. These findings underline the importance of accurate and high resolution land-state conditions in model initial conditions for forecasting severe weather systems, particularly the simulation of localised thunderstorms over India.     

面向四维变分资料同化的NSAS积云深对流参数化方案的简化及线性化研究

GRAPES全球四维变分资料同化系统需要积云深对流参数化方案的线性化与伴随方案,直接采用原始复杂参数化方案进行线性化并不可行,需要发展简化光滑方案来减缓非线性与非连续性特征。GRAPES全球模式采用NSAS积云对流参数化方案,积云深对流对环境的反馈主要通过补偿下沉来实现,研究突出补偿下沉作用,忽略降水蒸发、动量反馈等贡献,形成简化方案。采用输入温、湿度廓线加入不同幅度小扰动方法,评估参数化方案计算的温度、比湿时间倾向对输入扰动的敏感性,检验非线性与非连续特征。提出避免或减缓非连续“开关”的方法,在简化方案的基础上发展了简化光滑方案。简化光滑方案与原始积云深对流方案相比,在对流触发上一致,在对流的位温与比湿倾向、降水的时序模拟等方面相似,而在减缓非线性、避免非连续性方面显著优于原始方案。基于简化光滑方案发展的线性化方案表明,对小于2倍分析增量幅度的扰动,线性化方案可以较好地模拟非线性方案的扰动发展。发展的简化光滑方案具有合理性和实用性。      

EFFECTS OF SST, VWS, AND DCC UPON RAPID INTENSIFICATION OF OFF-SHORE TYPHOONS IN CHINA SEAS

In this study, we employed National Centers for Environmental Prediction(NCEP)/National Center for Atmospheric Research(NCAR) reanalysis data and records from the China Meteorological Administration(CMA)Yearbook of Tropical Cyclones to investigate three factors: sea-surface temperature(SST), vertical wind shear(VWS),and the density of the core convection(DCC), which are responsible for the rapid intensification(RI) of 1949-2013 offshore typhoons. Our analysis results of these composite factors show that in the environmental wind field the typhoons are far away from the outer strong VWS; in the SST field they are in the high SST area; and the core convective activity is robust and takes a bimodal pattern. The difference in RI between typhoons over the East China Sea(ECS) and the South China Sea(SCS) is a smaller VWS for the ECS typhoons, which may be one of the reasons why typhoons in the ECS are more intense than those in the SCS. Our study results indicate that SST, VWS, and DCC can result in an RI after a certain time interval of 36 h, 24 h to 30 h, and 24 h, respectively. The RI indicates a lag in the atmospheric response to oceanic conditions. This lag characteristic makes it possible to predict RI events. In summary, where the SST is high(≥28 ℃), the VWS is small, and the DCC is high, an RI will occur. Where mid-range SSTs occur(26 ℃≤SST≤28 ℃), with small VWS, and high DCC, the RI of typhoons is also likely to occur.     

基于CloudSat、FY-2E资料的中国海域及周边地区深对流和穿透性对流特征

深对流在地-气系统的物质和能量交换中起着至关重要的作用,伴随而来的暴雨、雷电、冰雹等天气会对人类社会产生影响。利用CloudSat/CALIPSO和FY-2E卫星观测数据,研究了中国海域及周边地区非穿透性对流（DCwo）及穿透性对流（CO）的海-陆分布、云顶红外亮温和云团特征（包括对流系统（CS）和对流单体（CC）的面积、活跃性对流比、偏心率、最低亮温、平均亮温梯度）。结果发现:穿透性对流比非穿透性对流的云顶红外亮温更低,垂直高度上的雷达反射率更高;从发生次数来看,非穿透性对流/穿透性对流在海洋比陆地多,低纬度比高纬度多,夏季比其他季节多,冬季海陆差异最大;从云顶亮温的分布来看,海洋比陆地、穿透性对流比非穿透性对流集中分布区间的亮温值更低,穿透性对流的分布区间比非穿透性对流集中;从云团特征来看,对流系统/对流单体的发生频率随面积的增大而降低,穿透性对流比非穿透性对流、海洋比陆地更容易出现较大面积的对流系统/对流单体,海洋穿透性对流的活跃性对流比相对较高;偏心率在0.5以上的发生频率较高,对流系统形状更偏向于圆形,在海洋上更加明显;穿透性对流在海陆上的最低亮温集中分布区间为190-195 K,比非穿透性对流的分布更集中,平均亮温梯度在0.1 K/km以下的发生频率较高。