中国内蒙古下白垩统白彦华群胜利组的首个同位素年龄

由于丰富的煤炭资源,内蒙古的下白垩统地层具有重要的经济价值.但长期以来相关地层一直缺乏同位素测年研究,影响了区域地层对比工作的开展.本文对内蒙古锡林浩特下白垩统胜利组煤层夹层中的火山灰锆石应用LA-ICP-MS进行U-Pb法测年,结果显示胜利组5煤(层)和6煤(层)形成于大约109-107 Ma(早白垩世阿尔布期).这...     

内蒙古长山壕金矿区花岗岩同位素年代学研究及地质意义

长山壕金矿床是近年来在内蒙古中西段找到的一特大型金矿床。尽管金矿化在中元古界白云鄂博群变质沉积岩内呈层状、似层状和透镜状产出,但是与各类花岗岩类侵入岩具有密切空间分布关系。本次研究采用LA-ICP-MS方法分别对有关花岗岩类侵入岩进行了系统年代学研究,花岗斑岩和二长花岗斑岩样品的锆石U-Pb年龄值分别为290.9±2.8Ma (MSWD=1.4)和287.5±1.9Ma (MSWD=2.4);2件黑云母花岗岩样品的年龄值分别为267.9±1.2Ma (MSWD=0.95)和274.0±2.3Ma (MSWD=1.4)。根据上述同位素年龄数据,同时结合金矿区野外地质调查和岩(矿)相学证据,可以认为,长山壕金矿区花岗斑岩和二长花岗斑岩及相关金矿床的形成时间为早二叠世早期,并且遭受到早二叠世晚期-中二叠世早期构造-岩浆活动的叠加改造,矿区切穿含金矿脉黑云母花岗岩体的存在就是很好的例证。强烈的中酸性岩浆作用为金矿床的形成提供了动力、热力和物质来源,初步研究结果表明,长山壕金矿床是海西期构造-岩浆作用及相关流体活动的产物,属于与侵入岩有关的中温热液脉型金矿床。     

乌拉溪铝质A型花岗岩：松潘—甘孜造山带 早燕山期热隆伸展的岩石记录

乌拉溪岩体位于松潘—甘孜造山带南段,江浪穹隆北部。LA-ICP-MS锆石U-Pb定年获得岩体年龄为159.31±0.9Ma。岩石中出现含钙钠长石和铁叶云母等A型花岗岩典型矿物;岩体具有高SiO2、Na2O和K2O含量,高FeOt/MgO、Ga/Al比值,以及低TiO2、CaO和MgO含量特征;稀土元素配分模式呈右倾海鸥型,Eu负异常明显;微量元素富含Rb、Nb和Ga等高场强元素,原始地幔标准化蛛网图显示出Ba、Sr、P和Ti亏损;岩体中锆石的古核稀少,锆石饱和温度计算显示岩体成岩温度很高(变化在967~984℃之间);岩体还相对富铝,A/CNK=0.97~1.27,分布比较集中,都大于0.95,过碱指数(NK/A=0.74~0.91)较低,均在1之下。以上特征表明乌拉溪二云母花岗岩为铝质A型花岗岩。锆石n(176Hf)/n(177Hf)比值变化于0.282228~0.282749,平均值为0.282586,fLu/Hf为-0.99~-0.10,平均值为-0.90,εHf(t)绝大多数为负值,变化于-15.88~1.77之间,平均值为-3.14,说明岩石形成是壳源物质占主导地位,可能为江浪穹隆核部元古宙变质核杂岩的部分熔融。结合区域构造演化,本文认为乌拉溪二云母花岗岩形成于陆—陆碰撞之后的伸展环境,是甘孜—松潘造山带在燕山早期增厚的地壳因伸展松弛而发生减压熔融的产物。     

河北东坪金矿区水泉沟岩体的地球化学特征

水泉沟岩体主要由二长岩构成。主要矿物是碱性长石和斜长石,它们的含量高达80%以上。石英不多见,暗色矿物含量少。副矿物主要是磁铁矿、石榴石、榍石和锆石。交代结构发育,蚀变现象普遍。主要化学组分和微量元素含量及δ18O值变化范围大。该二长岩体是由老片麻岩经热液碱交代作用而成。     

内蒙古镶黄旗哈达庙金矿杂岩体年代学、地球化学及其形成机制

在中亚造山带东段华北地台北缘,识别出一套原认为是燕山期的晚古生代哈达庙石英闪长岩,其LA-ICP-MS锆石U-Pb年龄为272.9±2.4Ma(MSWD=2.0)。哈达庙石英闪长岩及其相伴出露的哈达庙含金花岗斑岩,都具有高钾钙碱性I型花岗岩的性质,∑REE较低,LREE富集明显,具有中等到弱的铕负异常,与原始地幔相比,都具有大离子亲石元素(LILE)K、Rb、Th、Zr、Hf,轻稀土元素(LREE)La、Ce,相对高场强元素(HFSE)Nb、Ta、Ti、P富集的消减带组分(SZC)特性,并且具有陆缘弧火山岩的特征。从石英闪长岩到含Au花岗斑岩,具有板块碰撞前到同碰撞的岩石特征;通过Sr、Nd、Pb同位素分析,认为哈达庙金矿杂岩主要来源于壳、幔混源,具有新生下地壳(古岛弧带)的特征;石英闪长岩的先期熔出为贫硫化物斑岩型金矿成矿元素在花岗斑岩体内的富集创造了条件;哈达庙含金花岗斑岩异常富集易熔流体相元素(Rb、Ba、Th、U、K)可能是成矿岩体与非成矿岩体的鉴别标志。本文为在中亚造山带东段华北地台北缘寻找与古亚洲洋俯冲增生碰撞有关金矿提供了线索。     

西天山乌孙山一带大哈拉军山组火山岩LA-ICP-MS锆石U-Pb定年

西天山乌孙山一带广泛分布大哈拉军山火山岩,对其下段下部肉红色流纹质玻屑弱熔结凝灰岩和上部褐色英安岩进行LA-ICP-MS锆石U-Pb定年分析,得到(353.3±3.5)Ma、(344±6)Ma年龄,证实了乌孙山一带大哈拉军山组火山岩形成于早石炭世.     

澜沧江南带三叠纪火山岩岩石学、地球化学特征、Ar-Ar年代学研究及其构造意义

滇西三江地区澜沧江南带广泛发育三叠纪火山岩。在北部云县一带,中晚三叠世火山岩出露齐全,自下而上可划分为中三叠统忙怀组(T₂m),上三叠统小定西组(T₃x)和上三叠统芒汇河组(T₃mh)。忙怀组以酸性火山岩为主,为一套流纹岩夹火山碎屑岩组合;小定西组发育为中基性火山熔岩夹火山碎屑岩;芒汇河组具有流纹质火山碎屑岩与玄武岩共存的"双峰式"火山岩特征。地球化学特征表明,南澜沧江带三叠纪火山岩具有弧火山岩与大陆板内火山岩的双重属性,推测其形成环境为过渡型的大陆边缘造山带环境。对南澜沧江带南部景洪附近采集到的石英安山岩样品进行Ar-Ar年龄测试,得到的坪年龄为236.7±2.2Ma,为中三叠世。结合火山岩年代学结果,推测澜沧江洋主碰撞期为早三叠世,中三叠世与晚三叠世早期分别为碰撞后的应力松弛阶段与洋盆继续俯冲期,到晚三叠世末期,俯冲作用结束,澜沧江洋关闭。     

U-Pb Dating of Volcanic Rocks and Granites along the Wuyishan Belt: Constraints on Timing of Late Mesozoic Tectonic Events in Southeast China

Five volcanic rock samples and two granite samples taken from the volcanic basins in western Fujian and southern Jiangxi were dated by using the zircon laser albation-inductively coupled plasma mass spectrometry U-Pb method. Together with previously dated ages, the dates obtained provide important constraints on the timing of late Mesozoic tectonic events in SE China. The volcanic rock samples yield ages of 183.1±3.5 Ma, ca. 141 Ma to 135.8±1.1 Ma, 100.4±1.5 to 97.6±1.1 Ma, confirming three episodes of late Mesozoic volcanic activities, which peaked at 180±5 Ma, 140±5 Ma and 100±5 Ma, respectively, along the Wuyishan belt. Moreover, based on field investigations of these volcano-sedimentary basins, we have recognized two compressional tectonic events along this belt. The early one was characterized by Upper Triassic to Middle Jurassic NNE-trending folds that were intruded by late Jurassic granites; and the late one caused the Lower Cretaceous volcano-sedimentary layer to be tilted. The dated age 152.9±1.4 Ma of the granitic samples from the Hetian granitic pluton in the Changting Basin and that from the Baishiding granitic pluton, 100.2±1.8 Ma, in the Jianning Basin, give the upper boundaries of these two tectonic events respectively. Hence, the late Mesozoic tectonic evolution of SE China was alternated between extension and compression.     

New Evidence for Genesis of the Zoige Carbonate-Siliceous-Pelitic Rock Type Uranium Deposit in Southern Qinling: Discovery and Significance of the 64 Ma Intrusions

The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts due to its scale, high grade and abundant associated ores. Because of the insufficient reliable dating of intrusive rocks, the relationship between mineralization and the magmatic activities is still unknown. In order to study this key scientific issue and the ore-forming processes of the Zoige uranium ore field, the LA-ICP-MS zircon U-Pb dating of magmatic rocks was obtained:64.08±0.59 Ma for the granite-prophyry and ~200 Ma for the dolerite. U-Pb dating results of uraninite from the Zoige uranium ore field are mainly concentrated on ~90 Ma and ~60 Ma. According to LA-ICP-MS U-Pb zircon dating, the ages for the dolerite, porphyry granite and granodiorite are 200 Ma, 64.08 Ma approximately and 226.5-200.88 Ma, respectively. This indicates that the mineralization has close relationship with activities of the intermediate-acidic magma. The ages of the granite porphyry are consistent with those uraninite U-Pb dating results achieved by previous studies, which reflects the magmatic and ore-forming event during the later Yanshanian. Based on the data from previous researches, the ore bodies in the Zoige uranium ore field can be divided into two categories:the single uranium type and the uranium with polymetal mineralization type. The former formed at late Cretaceous(about 90 Ma), while the latter, closely related to the granite porphyry, formed at early Paleogene(about 60 Ma). And apart from ore forming elemental uranium, the latter is often associated with polymetallic elements, such as molybdenum, nickel, zinc, etc.     

华北板块北缘勃隆克A型花岗岩锆石U-Pb定年及其地质意义

内蒙古翁牛特旗勃隆克岩体位于华北板块北缘,侵位于上侏罗系火山岩地层中。详细的岩相学研究显示,勃隆克花岗岩具有粒状结构、蠕虫结构和文像结构,块状构造,部分斜长石已绢云母化、泥化。对勃隆克花岗岩进行了LA-ICP-MS锆石U-Pb定年,获得134.0±1.8Ma和134.9±4.1Ma的侵位年龄,表明其形成于早白垩世。地球化学特征显示,花岗岩属于高钾钙碱性系列,有较高的SO2（74.1%~75.6%）、Na2O+K2O（8.98%~9.2%）、Rb（210×10-6~225×10-6）含量和10000×Ga/Al（2.69~2.80）、Rb/Sr（5.8~18.9）值,具有较低的CaO、MgO、Ba和Sr含量。铝饱和指数A/CNK=0.99~1.03,属于偏铝质或过铝质A型花岗岩。稀土元素球粒陨石标准化图解显示,轻稀土元素相对富集,负Eu异常明显;在原始地幔标准化图解上,Ba、Sr、Nb、Ta、P、T强烈亏损,富集Rb、Th、K、Hf等元素,与华北板块北缘早白垩世A型花岗岩类似。结合区域构造演化,认为勃隆克花岗岩形成于伸展构造背景。晚中生代,华北板块北缘构造体制经历了重大的转变,地壳从挤压体制转为岩石圈减薄和地壳伸展体制,软流圈物质上涌导致上覆地壳长英质物质的部分熔融形成勃隆克A型花岗岩。