Microwave-assisted extraction of organochlorine pesticides from sediments and determination by gas chromatograph with electron capture detection

A simple and rapid procedure to extract organochlorine pesticides （OCPs） from sediments by means of microwave energy is proposed. Sediment samples were irradiated with microwaves in a closed vessel system while immersed in hexane-acetone （1 ： 1, v/v）. The sample extracts were cleaned up using solid phase extraction with Florisil as adsorbent. Pesticides were eluted with hexane-ethyl acetate （80 ： 20, v/v） and determined by gas chromatographic separation with electron capture detection. Three oven programs were assayed with two different solvent mixtures in order to achieve adequate experimental conditions for the complete extraction of organochlorine pesticides from the matrix. Different variables such as the composition of extraction solvent,     

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.     

R＆D投入的区位模式与区域经济发展

基于对中国R＆D投入的区位模式的实证检验，从投入一产出绩效的角度认为集中投入的区位模式具有较强的适宜性。利用聚类分析技术，按照R＆D的投入强度和及其对经济的带动效应、科技化效应、产业化效应将中国各省区划分为6类地区，具有代表性的是科技化模式和产业化模式。其中前者适合于技术存置较高的少数地区，而后者具有较强的借鉴意义。     

龙永煤田危机矿山资源接替的几种勘探模式

通过龙永煤田现有煤矿状况调查分析发现：许多矿井已步入“花甲之年”，接近矿井服务年限。为了保障我省能源安全，应当采用有效勘探方法，方能使它们“返老还童”。研究发现危机矿山延长服务年限的几种勘探模式是：其一为扩大（延伸）勘探模式；其二为小型井田（块段）勘探模式；其三为资料分析研究模式。经探采对比发现，采用这三种勘探模式后，产生了巨大的经济效益，使一大批老矿井青春再度焕发。     

基于GIS/MIS/OA的短周期工业原料林经营模式研究

提出了短周期工业原料林经营模式的概念,探讨了短周期工业原料林经营模式的体系结构、子系统功能和主要林业数表类型,说明其与GIS/MIS/OA系统集成的必然趋势,并以岳阳纸业股份公司的纸浆原料林为例进行了实例分析。     

全球信息栅格与军事地理信息系统

随着信息技术的发展,以信息技术为核心的新军事变革,正在力求使战场上的兵力兵器在总体上实现“作战能力的综合集成”。信息化战争的作战样式也从协同性逐渐向一体化联合作战方向发展。“全球信息栅格”是21世纪信息作战的基础,是作战网络的重要支撑。美军目前致力于通过建设“全球信息栅格”,将200万个用户连接成网,实现从传感器到射手、从总统府到散兵坑的“无缝信息链接”,并强调运用“网络中心     

淄博市洪山、寨里煤矿地下水串层污染形成原因及防治

淄博市洪山、寨里煤矿区隐伏的奥陶系灰岩裂隙岩溶水污染严重。水质污染突发于矿坑全面闭坑以后，污染范围与矿坑水区一致，地下水污染组份与矿坑水的高含量组份相同。水质恶化主要由矿坑水串层污染所致。在此针对串层污染形成原因及影响因素，提出了防治对策。     

一个让数万家庭提前享受美好生活的新机遇——卓达推出“共同开发”低价置业模式

土地资源紧缺，钢材、水泥等主要建材价格持续攀升，房价一路上涨……使每一个人发怔、发呆，心里恐慌，但是总要想办法解决问题……