磷灰石结构通道离子对晶胞参数的影响

磷灰石晶胞参数受其结构中Ca多面体，磷氧四面体及结构通道位置上的类质同角替换的影响，本文探讨了54个磷灰石样吕的晶胞参数与结构通道离子F，OH，Cl相同象替换的影响，本文讨论了54个磷灰石样品的晶胞参数与结构通道离子F，OH，Cl相对含量的关系，发现Cl和取代是影响岩浆型磷灰石晶胞参数的主要因素，每原子／晶胞的Cl使a增大0．121 1（6）nm，c减少0．0633 （3）nm，根据成分与结构的经验关系式，可以验证电子探针对F的分析结果。     

Porewater geochemistry and solute flux from bottom sediments,Devils Lake,North Dakota

Sediment cores were collected for pore-water analysis from the eastern end of Devils Lake, located in northeastern North Dakota, to determine diagenetic reactions occurring in surficial bottom sediments and to evaluate the impact of these reactions on chemical concentrations in the overlying lake water. Sediment pore waters are enriched in major ions and nutrients relative to lake water. The principal sources of major ions to pore water are saline sediments located in the upper 1 m of bottom sediment. The principal source of titration alkalinity and nutrients to pore water is microbial decomposition of sedimentary organic matter by sulfate reduction. Sediment pore waters in the eastern part of Devils Lake have higher major-ion concentrations and solute-flux rates than the sediment pore waters in the central part of the lake. In contrast, sediment pore waters in the central part of Devils Lake have significantly higher nutrient concentrations and solute-flux rates. Major-ion concentrations and solute-flux rates in sediment pore water increase from west to east. These trends indicate that bottom-sediment diagenetic processes are, in part, responsible for the observed concentration gradient in the lake. The higher nutrient concentrations and the higher nutrient diffusional-flux rates in Main Bay are the result of more labile sedimentary organic matter and the occurrence of sulfate reduction. Environmentally-reactive trace-metal concentrations (Cu, Pb, Zn, and Fe) in bottom sediments decrease from west to east with distance from the surface-water sources and with increasing surface-water salinity.     

Major ions characteristics in a disturbed aquifer of an oceanic island——Sipadan, Malaysia

The Sipadan island is the only oceanic island found in Malaysia, and is popularly known for its beautiful corals and diving activities. The aquifer of the island is affected by seawater intrusion associated with groundwater exploitation. Geologically, the aquifer is composed of several series of Quaternary bioherm facies, and its recharge merely depends on rainfall. This research attempts to understand the chemical changes of the groundwater attributed to the salinization processes based on major ion composition （Ca^2＋, Mg^2＋, Na^＋, K^＋, HCO, SO, Cl^-）. The initial assessments were done in years 1993 - 1994, followed by subsequent assessment in years 2004-2005. Methods of analyses were adopted from APHA （1995）. The hydrogeochemical saturation indices （SI） were computed using the PHREEQC program in order to assess the state of equilibrium between groundwater and the minerals present. The results of analyses indicated that the groundwater has been highly enriched in Na^＋, SO and CI, reflecting an encroachment of saline water into the aquifer. The groundwater facies can be classified as sodium chloride （Na-Cl） water type. There are positive correlations （moderate to strong）, except HCO3^-, between the studied parameters. The weak and inconsistent correlation of HCO3^- with the cations and anions related to dissolved salts suggests that saltwater intrusion has an insignificant impact on the chemistry of HCO3^- in the groundwater. Strong correlations （r 〉0.70） exist among the major elements （Na^＋, Mg^2＋, K^＋, Cl^- and SO4^-） and salinity （EC）. These relationships clearly identify the main elements contributing to the groundwater salinity and their tendency to depict a similar trend of salinization pattern. Chloride has a major influence on the salinity of groundwater based on the positive and strong correlation that exist between Cl^- and EC （r=0.97）.     

Diagenetic reactions in reservoir strata and geochemical properties of pore fluid and its origin in Songliao Basin

The reservoirs of the SOngliao Basin are composed of typical unstable sandstones,with high percentages of volcanic fragments and feldspar,In the course of sedimentation and burying,a series of physical and chemical reactions took place between minerals and pore water and water-rock reactions and ion exchange caused changes in ion assemblage of pore water,Hydration-hydrolysis,dissolution and the albitization of feldspar made many ions free from their framework and inter into the pore water,and induced the precipitation of a large amount of authigenic minerals such as smectite and chlorite,During the diagenesis of sandstone.diagenetic reactions involved several stages with increasing depth,and so did the precipitation of authigenic minerals and the transformaiton of minerals.The migration of ions is related with the precipitation,transformation and dissolution of authigenic minerals.Thus,to deepen our study on sandstone diagenesis is an important link for the analysis of ion migration in the evolution of pore water ,the origin and evolution of pore water could be tracked in terms of the geochemistry of fluid inclusions in authigenic minerals.And the isotopic composition of the authigenic mineral calcite can provide its genetic information.     

Effect of Sediment Motion Patterns on Sorption of Cadmium Ions by Sediment Particles

I.INTRODUCTIONThefateofmanytraceheavymetalsinnaturalwatersis,toalargeextent,controlledbysorptionprocessesandthedynamicsoftheparticlesthemselves.Thepotentialinfluencesofenvironmentalvariablessuchastemperature,CaZ+,Na+andCI--,dissolvedorganiccarbonandPHvaluesontraceheavymetalpartitioninghavebeenwidelyinvestigated.Forexample,StumnandMorgan(1981)suggestthattheextentofsorptionvariespositivelywithtemperature.Itfollowsthatdecreasedsorptionmightbeexpectedatlowtemperatures,e.g.duringwintermont…     

极光区离子分布函数视线方向上的解析解及其饱和现象

以弛豫碰撞模式下Boltzmann方程的解为基础，从极光区视线方向上离子的非Maxwell一维速度分布函数的Raman等人的积分解出发，导出了一维速度分布函数的解析形式解，给出了它的一些特性，并研究了该分布函数随电场增强而出现的饱和现象，给出了物理解释，计算了几种情况下的饱和电场值．     

雷暴下地面自然尖端电晕放电离子时空演化的数值模拟

为了对雷暴云下近地面的电特性进行分析，本文建立了模拟自然尖端所产生的电晕离子演化的一维数值模式。以地面电场为基础，考虑到地面电晕离子的演化，成功地计算了从地面至８００ｍ的空中电场及电荷、电流的时空演变，发现地面电晕离子可解释除雷暴云电荷影响外的空中电场和地面电场的差异，空间电场比地面电场更能反应雷暴电荷所产生的电场。空间电荷层可延伸到８００ｍ的高度上，且电荷密度可高达０．２５ｎＣ／ｍ^３，６００ｍ高度上的传导电流密度可达０．１ｎＡ／ｍ^２。     

地磁活动与太阳活动对环电流离子成分与位置的影响

根据CRRES卫星上MICS离子成分探测器的观测资料以及前人有关AMPTE卫星的观测数据，研究了地磁活动和太阳活动性对环电流成分以及各种环电流离子的最大通量位置的影响. 观测表明相对于地磁平静时期，在地磁活动的活跃时期，环电流中O+、He++和He+离子的数密度和能量密度占环电流总数密度和总能量密度的份额增加，相反H+离子所占的比例却明显减少. 太阳活动极大年时环电流中H+离子丰度比极小年时低，而O+和He++离子的丰度却比太阳活动极小年时高. 卫星数据观测还表明，在地球磁暴期间，环电流中O+离子和He+离子的最大通量位置会随着地磁的活动径向移动，平均来看太阳活动极大年的能量粒子最大数密度位置距离地球比极小年时约小0.5RE （RE 为地球半径）.     

SrTiO3基钙钛矿结构X射线衍射谱特征

通过对常规电子陶瓷工艺合成的Sr1-xCaxTiO3和Sr1-xPbxTiO3钙钛矿结构陶瓷进行研究X射线衍射谱特征、晶体结构和衍射强度I100/I110进行研究,并根据原子散射因子与衍射强度关系,提出用衍射强度I100/I110变化规律预测ABO3钙钛矿结构中置换A位离子种类的方法.