Disorder effects on the strain response of model polymer networks

Molecular dynamics simulations are used to investigate polymer networks made by either end-linking or randomly crosslinking a melt of linear precursor chains. The resulting network structures are very different, since end-linking leads to nearly ideal monodisperse networks, while random crosslinking leads to polydisperse networks, characterized by an exponential strand length distribution. Networks with average strand length 20 and 100 were generated. These networks were used to study the effects of disorder in the network connectivity on observables averaged either over the entire network or selected sub-structures. Heterogeneities in the randomly crosslinked networks cause significant differences in the localization of monomers, however, neither the localization of crosslinks nor the microscopic strain response are significantly affected. Compared to end-linked networks, randomly crosslinked networks have a slightly increased tube diameter, and as a result a slightly decreased shear modulus, but otherwise identical stress-strain behavior. For the investigated systems, we conclude that the microscopic strain response, tube diameter, and stress-strain relation are all insensitive to the heterogeneities due to the linking process by which the network were made.     

关于征地制度的思考

针对当前农村土地问题的现状．认为调整农村土地关系改革土地制度是解决当前农村问题的关键之一。介绍苏格兰土地改革的经验．提出农村土地转为非农用地的交易中国家应实行限制性措施．可尝试建立“国家失地农民账户”和“国家失地农民保障基金”．从而合理分配土地交易产生的级差收益保障失地农民的合法利益。     

On a three-dimensional axisymmetric boundary-value problem of nonlinear elastic deformation: Asymptotic solution and exponentially small error

In this paper, we study a three-dimensional axisymmetric boundary-value problem of a slender cylinder composed of a nonlinearly elastic material subjected to an axial force. Starting from the field equations, after a transformation and proper scalings, we identify a small variable and two small parameters, which characterize the present problem. Then, by an approach involving compound series-asymptotic expansions, a nonlinear ODE is derived, which governs the axial strain (the first-term in the series expansion). By imposing the zero radial displacement conditions at two ends, we manage to get the analytical solution of the axial strain, from which all other physical quantities can be deduced and thus the three-dimensional displacement field can be determined. Graphical results are presented, which show that there are two boundary layers near the two ends while the middle part is in a state of almost uniform extension. The asymptotic structure of the analytical solution is derived, which offers clear explanations to the structure of the deformed configuration and shows that the thickness of both boundary layers is of the order of the radius. We also point out the relevance of the present results to the St. Venant’s problem. In particular, we obtain the explicit uniformly-valid exponentially small error term, when the obtained deformed configuration is compared to the configuration of a uniform extension.     

Significance of the elastic peak stress evaluated by FE analyses at the point of singularity of sharp V-notched components

The paper presents an expression useful to estimate the notch stress intensity factor (NSIF) from finite element analyses carried out by using a mesh pattern with a constant element size. The evaluation of the NSIF from a numerical analysis of the local stress field usually requires very refined meshes and then large computational effort. The usefulness of the presented expression is that (i) only the elastic peak stress numerically evaluated at the V‐notch tip is needed and no longer the whole stress–distance set of data; (ii) the adopted meshes are rather coarse if compared to those necessary for the evaluation of the whole local stress field. The proposed expression needs the evaluation of a virtual V‐notch tip radius, i.e. the radius which would produce the same elastic peak stress than that calculated by FEM at the sharp V‐notch tip by means of a given mesh pattern. Once such a radius has been theoretically determined for a given geometry, the expression can be applied in a wide range of notch depths and opening angles.     

冬瓜山铜矿初步设计概算编制的几点体会

简述初步设计概算重要性,结合冬瓜山铜矿概算编制的实例,总结了编制初步设计概算的几点体会。     

限制市场中不定权益的定价

通过构造一族辅助风险溢价来确定不定权益的无套利价格，用这种方法 讨论了存在交易限制时欧式不定权益的定价问题，其结果与Davis的公平价格一致.     

钢铁企业价格预测决策模型体系研究

通过对钢铁企业现行价格管理体系的分析 ,建立了钢铁企业价格预测决策模型体系。充分利用大量的定性、定量信息 ,并把趋势预测和因果预测技术相结合 ,采用组合预测模型对价格进行预测 ,最后对预测出来的多方案进行模糊综合评价 ,给出推荐方案顺序。实际应用表明 ,模型体系是有效的。     

水资源开发使用权出让价格实证分析

2001年浙江省率先利用市场机制配置水资源，经过近6年的实践，已经积累了一些数据，取得了较好的成效。为此，利用浙江省三个县（市）水资源开发权市场拍卖价格，来研究水资源开发权转让价格与相关要素之间的相关性和进行线性回归分析。通过分析，验证了水权出让价格与各有关因素之间的关系，同时指明了水资源市场化配置的良好态势。     

天然气供热供冷的技术经济分析

对冬季采用天然气热水锅炉供热，夏季采用电动离心式冷水机组供冷和冬夏季都采用天然气直燃型溴化锂吸收式冷热水机组进行供热供冷的两种方案进行了技术经济比较。指出天然气价和电价是影响供热供冷成本的最敏感因素。