小体积萃取-石墨炉原子吸收法测定高纯硝酸钡中纳克级重金属元素

本文研究了石墨炉原子吸收光谱法测定高纯硝酸钡中超痕量重金属元素的分析技术。提出在大量钡基体存在时,采用小体积萃取体系APDC-MIBK同时萃取纳克级的Fe、Cu、Co和Ni。该法具有灵敏度高、无干扰、操作方便和减少沾污等特点。方法检出限为:Fe 7.2ng/g、Cu 12.8ng/g、Co 4.4ng/g和Ni 6.7ng/g。应用于红外光纤原料硝酸钡、硝酸铝中痕量重金属的测定,效果良好。     

改进Faster R-CNN的遥感图像多尺度飞机目标检测

为了提高遥感图像中多尺度飞机目标的检测精度,本文提出一种基于改进Faster R-CNN的遥感图像飞机目标检测方法。该方法借助多层级融合结构,将深层次的语义特征与浅层次的细节特征相结合,生成多种尺度的既具有精确的位置信息又具有深层次的语义特征的特征图;再借助Faster R-CNN的多尺度RPN (Region Proposal Network)机制,通过对RPN中候选区域尺度的修正,从而提高遥感图像中多尺度飞机目标的定位精度;最后利用Faster R-CNN的分类回归网络,得到飞机目标检测结果。在高分辨率遥感图像中进行了实验,对3种特征提取网络ZF、VGG-16以及ResNet-50进行改进,改进后的精度分别提高了11.34%、9.87%以及1.66%,并且生成的检测框更加贴合飞机目标。实验结果表明,本文方法适用于遥感图像多尺度飞机目标检测,在提高目标定位精度的同时降低了目标漏检现象。     

Analytical perspective on trace element species of interest in exploration

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.     

Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

亚洲夏季风建立格局和南海季风爆发特征及其成因初探

使用１９８０￣１９８６年欧洲中期预报中心（ＥＣＭＷＦ）格点资料和１９８０￣１９９２年日本地球静止气象卫星（ＧＭＳ）观测到的黑体辐射（ＴＢＢ）资料，分析了南海季风爆发和亚洲夏季风建立格局及其可能机制。发现亚洲夏季风建立征兆最早出现在中南半岛－南海地区，随后自该地区分别向西、向东扩展；中南半岛地区是东亚季风和印度季风的天然分界线，其两侧夏季风的建立特征和形成机制迥然不同。亚洲夏季风自东向西逐渐建立的格     

中国特有的永瓣藤属植物区系地理性质与特征

永瓣藤是卫矛科的单型属(Monimop etalum Chinese Rehd),为中国特有的珍稀濒危植物,分布于北纬28°30'～30°10'和东经114°30'～118°10'的长江中下游南岸地区。文中研究了永瓣藤的自然地理环境与群落特征,分布区的历史和分布格局的现状,探讨了它起源的时间、地区及区系地理性质。研究结果表明:(1)永瓣藤适应于温暖湿润和偏酸性(pH5.5～6.5)土壤的地理环境;它是群落的伴生成分,其分布受到杉木、马尾松、毛竹、赤杨叶等优势成分的影响。(2)其分布区的地史演变大概为:连续分布(新第三纪)→间断分布(第四纪及以后)→星散分布(现状).通山县的残存为湖北省植物区系地理分布新记录属(种).(3)它分布于我国东部中亚热带向北亚热带过渡区域,是一个具亚热带性质的华东特有属。(4)其起源地可能是扬子古陆的九岭-怀玉联合地体;起源时间大约在新第三纪中新世(或更晚),是被子植物一个起源比较年轻的属,并不是起源古老的地理成分。     

基于GTP的地下工程与围岩一体化真三维空间构模

针对地下工程开挖体的基本特征及其真三维建模要求，在广义三棱柱(GTP)模型的基础上进行扩展，提出采用E—GTP模型来构建地下工程开挖体的真三维模型。通过与其围岩地质体的G—GTP模型的耦合，实现了基于GTP的工程开挖体与围岩地质体的一体化建模。该模型将地下三维空间实体抽象为点、线、面、体四类对象，通过结点、TIN边、侧边、TIN面、侧面和GTP体元共6个基本几何元素进行统一表达。该文重点讨论了E—GTP的建模原理与方法，并介绍了基于面向对象思想的一体化空间数据结构。     

基于DEM的洪泛平原湿地数字水系提取研究

为了研究探索洪泛平原湿地区域基于DEM的地表水要素数字特征,采用ArcGIS9.0的Hydro Arc Tools模块,配合改进升值裂开算法编制的程序在三江平原洪河保护区1:1万比例尺的DEM基础上进行了数字水系提取研究,将研究区划分为6个数字集水区,提取出以沃绿兰河-浓江河为主的数字河网,以及大小82处泡沼和洼地。研究表明,在保持高精度DEM前提下,数字地表水系统可以通过基于DEM自动提取出来,但是存在河道偏移以及河网形态失真等问题,需要在进行数字提取前后进行多次修正。在DEM数字高程预处理过程中保持高程信息的水文特征不丢失,以及发展专业处理平坦区域和低洼地域的有效算法,将是进一步提高洪泛平原湿地区域数字水系提取效率和精度的关键。     

金伯利岩中铬铁矿原生表面特征成因类型及其成分特征

对金伯利岩中铬铁矿原生表面特征的成因做出了合理解释,并提出了４种成因类型;通过探讨铬铁矿原生表面特征,化学成分,含矿性之间的关系,初步建立了铬铁矿原生表面特征与金刚石含矿性之间的关系。     

湘西沃溪金矿床地质特征及其找矿前景探讨

矿床受与沃溪深断裂平行的层间断裂控制，元古宇板溪群变质浅海相粘土质沉积岩是主要的赋矿层位，矿体（脉）具斜列延深，多层产出，砷等元素具有找金矿的地球化学意义，资料分析表明，矿床及外围具有找矿前景。