Syntheses,structure and photoluminescent properties of lanthanide oxalatosulfocarboxylate coordination polymers

Hydrothermal reactions of oxalic acid(H2ox) and 2-sulfobenzoic acid(H2L) with lanthanide oxide or hydroxide yielded five lanthanide oxalatosulfocarboxylates.They have a general formula [Ln2L2(ox)(H2O)6]n[Ln = La(1),Nd(2),Eu(3),Gd(4),Tb(5)].Their structures were characterized by single crystal X-ray diffraction,powder X-ray diffraction(PXRD),infrared(IR) spectroscopy,elemental analysis(EA),and thermogravimetric analysis(TGA).1-5 are isostructural coordination polymers and feature one-dimensional(1D) chains,which are extended into 3D supramolecular frameworks through inter-chain hydrogen bonds between coordinated H2O donors and oxygen acceptors from carboxylate,sulfonate and oxalate groups.In addition,the solid-state photoluminescence properties of the Nd(2),Eu(3) and Tb(5) derivatives have been measured at room temperature.The Eu and Tb-containing coordination polymers(CPs) exhibit intense red and green luminescence emissions,respectively,with lifetimes in the order of millisecond.     

中部地区中小学教师教育公平意识的调查与研究

本研究采用自编问卷对中部六省的600名中小学教师的教育公平意识进行了问卷调查,调查的内容包括教师对学生的关注、对学生的评价、对学生进行教育资源的分配和教育公平感等四个维度.调查结果显示,不同性别、不同学历、不同教龄,不同学段和不同区域的教师在教育公平意识上存在一些差异.这些差异在一定程度上表现了当前中部地区中小学教师教育公平意识状况,并有其内在的原因.     

研究生党员的马克思主义信仰考察——以上海大学学生调查为例

当前研究生党员的马克思主义信仰主流是积极的,但还存在马克思主义信仰淡漠、理论知识欠缺、入党动机不纯、缺乏捍卫马克思主义的勇气等倾向,而且理工类学生比文科类更为明显.这种现象的存在是由于大学生身处开放的多元社会情境下受到各种社会思潮的影响以及马克思主义理论研究和教育滞后等原因造成的.增强研究生党员的马克思主义信仰需要社会、学校、家庭、媒体和研究生党员的共同努力.     

海岩小说中另类女性形象及其原型分析

海岩以其传奇性的书写,在他的作品中创造了两类鲜明的另类女性形象,从而对中国古代小说中神秘莫测的妖女和希腊神话中复仇女神美狄亚这两个原型进行了复制与改造。这不仅极大地丰富了当代文学的女性人物画廊,也给读者提供了新的审美经验,具有独特的社会意义和审美价值。     

Electrodeposition and characterization of thermoelectric Bi<Subscript>2</Subscript>Se<Subscript>3</Subscript> thin films

Bi₂Se₃ thin films were electrochemically deposited on Ti and indium tin oxide-coated glass substrates, respectively, at room temperature, using Bi(NO₃)₃·5H₂O and SeO₂ as starting materials in diluted HNO₃ solution. A conventional three-electrode cell was used with a platinum sheet as a counter electrode, and a saturated calomel electrode was used as a reference electrode. The films were annealed in argon atmosphere. The influence of cold isostatic pressing before annealing on the microstructure and thermoelectric properties of the films was investigated. X-ray diffraction analysis indicates that the film grown on the indium tin oxide-coated glass substrate is pure rhombohedral Bi₂Se₃, and the film grown on the Ti substrate consists of both rhombohedral and orthorhombic Bi₂Se₃.     

Study of two-section composite chain of beads under vertical vibration

We investigated the dynamic properties of a two-section composite chain of beads under vertical vibration.By analyzing the chain’s motion,including phase-shift,mean dilation,center-of-mass displacement,and energy,we found that with different bead arrangements,the chain behaved in different ways.We believe that interaction existing at the interface between bead sections provides the underlying cause.This interaction causes different energy in different arrangements,which leads to different dynamic characteristics.     

Preparation and performance of dye-sensitized solar cells based on ZnO-modified TiO<Subscript>2</Subscript> electrodes

The ZnO-modified TiO₂ electrode was prepared by adding Zn(CH₃COO)₂·2H₂O to the TiO₂ colloid during the sol-gel production process, and was used in dye-sensitized solar cells (DSCs). The open circuit voltage (V _OC) and fill factor (ff) of the cells were improved significantly. The performances of the ZnO-modified TiO₂ electrode such as dark current, transient photocurrent, impedance, absorption spectra, and flat band potential (V _fb) were investigated. It is found that the interface charge recombination impedance increases and V _fb shifts about 200 mV toward the cathodic potential. The effect mechanism of ZnO modification on the performance of DSCs may be that ZnO occupies the surface states of the TiO₂ film.     

拟建隧道下穿热力顶管的现状评估

新建城市隧道通常要下穿某些正在使用中的管线,为降低隧道施工对管线使用的影响,结合隧道下穿热力顶管实际工程,提出一种现状评估思路:对拟建隧道下穿的既有管线检测,获取目前属性参数,利用结构力学理论和有限元方法计算分析其目前抗变形能力,并综合几何尺寸计算结果,得出管线沉降变形和差异变形控制指标,为隧道设计施工提供科学依据.     

一类具有多病程与接种的传染病模型

建立了具有两个感染阶段的疾病传播模型,分别讨论了在常数接种策略下模型的无病平衡态和地方病平衡态的动力学性质,得到了决定疾病是否传播的基本再生数.     

剖析我国男篮中距离投篮技术的运用能力

中距离投篮是篮球比赛中的主要得分方式，因此，中距离投篮得分对比赛胜负起着关键作用。本文通过录像观察法、数理统计法，采用中外男篮对比研究的方法，分析了中国男篮中距离投篮的相关问题，指出了我国男篮在中距离投篮技术上的优势与不足，并提出了具体建议。此项研究为提高中国男篮整体的得分能力以及我国男子篮球运动的整体水平提供了理论依据和实例借鉴。