地下水渗流场对库区滑坡稳定性影响的数值模拟——以白马库区羊角滩滑坡为例

针对库水位变化条件下滑坡的稳定性定量评价复杂问题,考虑降雨和库水位变化对地下水渗流场变化规律的影响机制,采用饱和-非饱和渗流的基本理论,运用渗流模拟有限元法,对重庆市武隆区羊角滩滑坡在6种不同工况下的库区滑坡的稳定性开展了模拟研究。结果表明: ①降雨工况下,降雨对地下水渗流场都有影响,滑坡中部位置受地下水位影响最大,前后部影响小,降雨条件下,滑坡稳定性随着降雨历时的增加而变小,到达一定阶段后,滑坡已经滑动,滑坡稳定性系数不再变化; ②库水位工况下,主要影响滑坡前缘,地下水位是随库水位变化而迅速变化的,随着库水位的上涨,滑坡稳定性系数呈现先减小后增大的趋势; ③地下水位的骤升对浮托作用影响有限,对压坡作用影响较大,同时降低了渗流力的影响,对滑坡稳定起到了积极作用,地下水位的骤降增大了渗流力,减弱了前缘库水位的压坡作用,滑坡失稳的可能性最大。可为库区该类滑坡的稳定性现状及发展趋势预判提供科学依据。     

广西宁明县海渊镇土地质量地球化学评价

为了查清广西宁明县海渊镇土地质量地球化学基本状况并提出优质土地资源开发利用建议,本文以第二次全国土地调查成果中的土地利用图斑为评价单元,系统采集了该区土壤及农作物样品,并分析了土壤的养分指标（氮、磷、钾、硒）、环境指标（pH、镉、汞、砷、铜、铅、锌、铬、镍）,农作物样品的评价指标（硒和镉、汞、砷、铜、铅、锌、铬、镍）,在此基础上参照《土地质量地球化学评价规范》进行了土地质量评价,划分了无污染风险富硒土地。结果表明：该区土壤养分质量较差,综合等级以较缺乏和缺乏为主;土壤环境质量优质,无风险等级土壤占比95.57%;土壤质量一般,评价等级以中等为主,面积124.01 km2,占全区总面积的56.28%,主要由土壤养分缺乏导致;水稻样品富硒比例高达66.67%,水稻重金属超标率仅为1.67%,圈定无污染风险富硒土地35.69 km2。上述评价结果可为当地富硒等优质土地开发与农产品安全利用提供重要的地球化学依据。     

一种适用于沉积有机质族组分分离的微型柱色谱法

硅胶-氧化铝柱色谱是广泛采用的沉积有机质组分分离方法。但在常规柱色谱分离方法中,存在吸附剂、溶剂使用量过大、烷烃/芳烃组分交叉严重等问题。介绍一种微型柱色谱分离法,其分离效果与常规方法的效果基本相同或略有改善,吸附剂用量与样品的比例由100～250降低为25～50,洗脱溶剂与样品的比例由1800～4600降低至250～500。同时,操作程序进一步简化,分析成本和对环境的污染程度大幅度降低。     

北京房山岩体形成过程中的岩浆混合作用证据

北京房山侵入岩体主要由石英二长闪长岩单元和三种不同结构的花岗闪长岩单元组成,岩体中广泛分布的镁铁质微粒包体、富集暗色矿物的线状条带以及各岩相单元的非渐变接触关系等宏观特征,指示岩体的形成与岩浆混合作用有密切联系。122个斜长石成分剖面电子探针分析表明,它们众数成分为 An=29的更长石。但是,其成分变化范围极宽(An=14～56),晶体内不同部位的成分有很大差别,出现正常环带的 An 值较低(14～42),内环带的 An 值较高(24～56)的特殊情况,指示斜长石结晶环境的改变,暗示具有富钙基性岩浆的加入。从岩体边部到中心,斜长石 An 牌号逐渐降低,但相邻岩相单元之间有较大的重叠,表明不同岩石单元中的斜长石成分主要受控于岩浆成分的变化,与分离结晶作用无关。斜长石的韵律性环带、特别是内环带的发育则是岩浆混合作用机制的有力证据。基性岩浆的反复注入不仅改变寄主岩浆的成分,而且也控制了它的温度、定位机制和岩石的结构特征。因此,房山岩体的形成过程还包含了镁铁质岩浆多次注入的历史,并且从外到里基性岩浆的作用逐渐减弱。     

苏鲁超高压变质岩中地震波速随围压的变化规律

我们在10~800MPa的静水压力下测量了中国大陆科学钻探(CCSD)主孔岩心和采自苏鲁地区地表露头上的共68块典型超高压变质岩试样的地震波速,并建立了波速和围压的定量关系,成功地解释了描述这一定量关系方程中4个参数的物理意义。笔者相信,本文将为超高压变质岩地区以及新老俯冲带地震波资料的解释提供必不可少的理论和实验支撑。     

试论新疆成矿体系与时空演化模式

文章探讨了成矿体系的内涵,在以往研究成果和编制1∶1 500 000中国新疆维吾尔自治区矿床成矿系列图的基础上,根据先时间、后空间、再成因的总体思路,完善了新疆前寒武纪、早古生代、晚古生代、中生代、新生代五个时段成矿体系,初步构建了各时段成矿体系的时空演化模式,总结出5个时段成矿体系的特点是:前寒武纪为基底陆壳的形成与发展各具特色的成矿体系;早古生代板块体制早期发育具中亚成矿域特色的成矿体系;晚古生代板块体制晚期发育具中亚成矿域特色的成矿体系;中生代新疆北部发育板内西域成矿特色的成矿体系和新疆南部发育特提斯成矿域特色的成矿体系;新生代发育板内西域成矿特色的大陆成矿体系。     

大兴安岭中北段塔尔气地区早白垩世白音高老组火山岩地球化学特征及意义

塔尔气地区早白垩世白音高老组火山岩主要由流纹岩、流纹质(含角砾)岩屑晶屑凝灰岩及流纹质岩屑晶屑凝灰熔岩等组成。岩石地球化学研究表明,火山岩具有富铝(Al2O3含量13.37%~15.79%)、富碱(Na2O+K2O含量6.10%~8.56%)、贫镁钙的特点;稀土元素丰度总量较高,轻、重稀土元素分馏明显[(La/Yb)N=3.72~17.9],且HREE有较明显的凹陷;微量元素以相对富集K、Rb、Ba、LREE等大离子亲石元素,而相对亏损Sr元素以及高场强元素Nb、Ta、Ti为特征。结合前人研究结果表明,塔尔气地区白音高老组火山岩来源于基性下地壳物质的部分熔融。结合火山岩所具有的A型流纹岩的特点,暗示为伸展构造体制下的产物,可能与蒙古—鄂霍茨克洋闭合后的伸展环境有关。     

Jurassic Hornblende Gabbros in Dongga, Eastern Gangdese, Tibet: Partial Melting of Mantle Wedge and Implications for Crustal Growth

The Gangdese batholith, more than 2500 km in length, is composed mainly of JurassicMiocene igneous rocks. This batholith is one of the most important constituents of the Tibetan orogenesis and provides an ideal place for study of Neo-Tethyan ocean geodynamic evolution and plateau uplift. Recent studies on the Gangdese Jurassic felsic magmatism highlight its juvenile source. However, important aspects concerning the genesis of the juvenile magmatism and related deep geodynamic evolution are still unclear. Here, we report detailed petrological, geochronological, geochemical, whole-rock Sr-Nd isotopic, and in situ Sr-Hf isotopic data for a recently identified hornblende gabbro in the Dongga area, southern Lhasa sub-block. This hornblende gabbro is dominated by hornblende and plagioclase, dated at Early Jurassic(ca. 180–190 Ma), and characterized by a narrow compositional range in SiO_2(49.38wt%–52.27wt%), MgO(4.08wt%–7.00wt%), FeO(10.43wt%–11.77wt%), Na_2O(2.58wt%–3.51wt%), and K_2O(0.48wt%–1.53wt%). It has depleted isotopic signatures, with whole-rock(~(87)Sr/~(86)Sr)i ratios of 0.7033–0.7043, ε_(Nd)(t) values of +4.90 to +6.99, in situ plagioclase(~(87)Sr/~(86)Sr)i ratios of 0.7034–0.7042, and zircon ε_(Hf)(t) of +12.2 to +16.8. Our results integrated with published data suggest a model of Gangdese juvenile crustal growth by a subduction-related water-enriched mantle wedge. The hydrous partial melting of the lithosphere mantle was triggered by the dehydration of a Neo-Tethyan oceanic slab. This mafic magmatism emplaced in the middle-lower crust of intraoceanic arcs or active continental margins, leading to Jurassic juvenile crustal growth in southern Tibet.     

西藏首例云英岩型钨矿——甲岗雪山W-Mo多金属矿床地质特征研究

甲岗雪山W-Mo多金属矿床位于西藏自治区申扎县境内,地处冈底斯北部,成矿时代为中新世。矿床与矿区内的二长花岗岩体时空关系紧密,矿区内的围岩蚀变普遍见云英岩化,并且云英岩化强烈的地方多伴随强烈的钨钼矿化;矿体的类型以云英岩型为主,还有少量石英脉型,矿石又多呈细脉状或浸染状赋存于云英岩或云英岩化二长花岗岩体内部,证实了矿床的成因类型为云英岩型。依据野外见到的矿物共生组合、脉体穿切关系等,可将成矿期划分为硅酸盐-氧化物阶段和硫化物阶段。流体包裹体研究表明,甲岗雪山W-Mo多金属矿床主成矿期的成矿流体为中-高温、中-低盐度的流体,从主成矿期的硅酸盐-氧化物阶段演化到硫化物阶段,成矿流体的温度下降明显,盐度也有所下降。     

Heat capacity and phase equilibria of wadeite-type K2Si4O9

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.