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51.
52.
β-环糊精包合态三氟氯氰杀虫剂的制备 总被引:3,自引:0,他引:3
为了进一步提高三氟氯氰菊酯农药的防治效果。寻找适宜的农药新剂型,我们用液相法制备了三氟氯氰菊酯-β-环糊精包合物,并以水为基质进行了稳定性观察,同时又以差热分析法和气相色谱法确认了包合物的形成,以旋光度法证明两者间的包合比。结果表明,三氟氯氰菊酯与β-环糊精可形成1:1型包合物,该包合物稳定性高,具有一定的水溶性,而且在水中稳定,所以有望通过环糊 包合作用将三氟氯氰菊酯帛成水剂;当以气相法测试包合态三氟氯氰菊酯含量时,必须将其解络,使之成为游离状态,然后按常规方法进行含量测定。 相似文献
53.
红壤丘陵区农业开发中的生态环境效应及其调控 总被引:3,自引:0,他引:3
文章以江西余江县为例。通过实验研究,历史资料对比分析及邻近参照等方法。研究红壤区农业开发中的生态环境效应。农业开发引起的微观环境效应在于改变土壤水分及其运动状况,加速土壤物质迁移及降低土壤肥力质量;区域性效应是植被减少,农业面源污染,水土流失扩大及气候异常;全球性影响除区域集聚效应外,则是农业活动中产生的温室气体对全球气候的影响等,采取的调控对策主要是:保持合理开发,适当减轻土地压力,优化农业开发模式,更新农业耕作技术。强化环境整治与生态建设。 相似文献
54.
Detailed study on the anisotropy of magnetic susceptibility of arctic marine sediments 总被引:3,自引:0,他引:3
Norbert R. Nowaczyk 《Geophysical Journal International》2003,152(2):302-317
55.
本文对松辽盆地东南部后五家户气田划分出22种沉积微相,建立7种相层序,分析了扇三角洲及三角洲沉积环境对天然气成藏的控制作用。指出了扇三角洲前缘砂体和三角洲前缘砂体较为发育,沉积物源来自气田东北部和东南部两个方向。后五家户气田多为构造—岩性气藏和岩性气藏。 相似文献
56.
Introduction The Western Kunlun Mountain Pass M=8.1 earthquake occurred on November 14, 2001 is the other M=8 earthquake occurred 50 years after Dangxiong, Tibet M=8.0 earthquake in Chinese mainland. The earthquake has caused the attention of the seismologists in the following aspects: 1) The fracture length is more than 400 km, which is far away from the estimated length by the statistic empirical function between the magnitude and the fracture length (WANG, et al, 2002); 2) The aftersh… 相似文献
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Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C60, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C70 was detected, nor was C60 found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C60 in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation. 相似文献
59.
M. Krämer Ri. Müller H. Bovensmann J. Burrows J. Brinkmann E. P. Röth J.-U. Grooß Ro. Müller Th. Woyke R. Ruhnke G. Günther J. Hendricks E. Lippert K. S. Carslaw Th. Peter A. Zieger Ch. Brühl B. Steil R. Lehmann D. S. McKenna 《Journal of Atmospheric Chemistry》2003,45(1):51-77
Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation. 相似文献
60.
Finite volume method on unstructured grids in 3D with applications to the simulation of gravity waves 总被引:2,自引:0,他引:2
Summary ?A code for the simulation of atmospheric flows in 3D is presented. The underlying mathematical model is fully compressible,
it takes gravity into account but Coriolis forces, turbulence and viscosity are neglected. The general numerical code consists
of a finite volume discretization on unstructured hexahedral grids in 3D. The code is presently being investigated on applications
to the calculation of atmospheric gravity waves on a mesh which has a structured type and is locally refined near the orography.
We develop two schemes, the main difference between them lies in the different discretizations for the mass fluxes. We show
that both schemes resolve typical structures of gravity waves in potential flow, linear hydrostatic motion and nonlinear non-hydrostatic
regime. We compare advantages and disadvantages of the developed schemes.
Received April 20, 2001; revised September 10, 2001 相似文献