Large-eddy simulations of thermally forced circulations in the convective boundary layer. Part II: The effect of changes in wavelength and wind speed

This paper extends previous large-eddy simulations of the convective boundary layer over a surface with a spatially varying sensible heat flux. The heat flux variations are sinusoidal and one-dimensional. The wavelength is 1500 or 4500 m (corresponding to 1.3 and 3.8 times the boundary-layer depth, respectively) and the wind speed is 0, 1 or 2 m s^-1.In every case the heat flux variation drives a mean circulation. As expected, with zero wind there is ascent over the heat flux maxima. The strength of the circulation increases substantially with an increase in the wavelength of the perturbation. A light wind weakens the circulation drastically and moves it downwind. The circulation has a significant effect on the average concentration field from a simulated, elevated source.The heat flux variation modulates turbulence in the boundary layer. Turbulence is stronger (in several senses) above or downwind of the heat flux maxima than it is above or downwind of the heat flux minima. The effect remains significant even when the mean circulation is very weak. There are effects too on profiles of horizontal-average turbulence statistics. In most cases the effects would be undetectable in the atmosphere.We consider how the surface heat flux variations penetrate into the lower and middle boundary layer and propose that to a first approximation the process resembles passive scalar diffusion.The research reported in this paper was conducted while the first author was on study leave at Colorado State University.     

Electrical conductivity of polycrystalline Mg(OH)<Subscript>2</Subscript> at 2 GPa: effect of grain boundary hydration–dehydration

The effect of intergranular water on the conductivity of polycrystalline brucite, Mg(OH)₂, was investigated using impedance spectroscopy at 2 GPa, during consecutive heating–cooling cycles in the 298–980 K range. The grain boundary hydration levels tested here span water activities from around unity (wet conditions) down to 10⁻⁴ (dry conditions) depending on temperature. Four orders of magnitude in water activity result in electrical conductivity variations for about 6–7 orders of magnitude at 2 GPa and room temperature. Wet brucite samples containing, initially, about 18 wt% of evaporable water (i.e. totally removed at temperatures below 393 K in air), display electrical conductivity values above 10⁻²–10⁻³ S/m. A.C. electrical conductivity as a function of temperature follows an Arrhenius behaviour with an activation energy of 0.11 eV. The electrical conductivity of the same polycrystalline brucite material dried beforehand at 393 K (dry conditions) is lower by about 5–6 orders of magnitude at room temperature and possesses an activation energy of 0.8–0.9 eV which is close to that of protonic diffusion in (001) brucitic planes. Above ca. 873 K, a non-reversible conductivity jump is observed which is interpreted as a water transfer from mineral bulk to grain boundaries (i.e. partial dehydration). Cooling of such partially dehydrated sample shows electrical conductivities much higher than those of the initially dry sample by 4 orders of magnitude at 500 K. Furthermore, the corresponding activation energy is decreased by a factor of about four (i.e. 0.21 eV). Buffering of the sample at low water activity has been achieved by adding CaO or MgO, two hygroscopic compounds, to the starting material. Then, sample conductivities reached the lowest values encountered in this study with the activation energy of 1.1 eV. The strong dependency of the electrical conductivity with water activity highlights the importance of the latter parameter as a controlling factor of diffusion rates in natural processes where water availability and activity may vary grandly. Water exchange between mineral bulk and mineral boundary suggests that grain boundary can be treated as an independent phase in dehydroxylation reactions.     

Characterization of contact properties in biocemented sand using 3D X-ray micro-tomography

The mechanical efficiency of the biocementation process is directly related to the microstructural properties of the biocemented sand, such as the volume fraction of calcite, its distribution within the pore space (localized at the contact between grains, over the grain surfaces) and the contact properties: coordination number, contact surface area, contacts orientation and types of contact. In the present work, all these micromechanical properties are computed, for the first time, from 3D images obtained by X-ray tomography of intact biocemented sand samples. The evolution of all these properties with respect to the volume fraction of calcite is analyzed and compared between each other (from untreated sand to highly cemented sand). Whatever the volume fraction of calcite, it is shown that the precipitation of the calcite is localized at the contacts between grains. These results are confirmed by comparing our numerical results with analytical estimates assuming that the granular medium is made of periodic simple cubic arrangements of grains and by considering two extreme cases of precipitation: (1) The calcite is localized at the contact, and (2) the grains are covered by a uniform layer of calcite. In overall, the obtained results show that a small percentage of calcite is sufficient to get a large amount of cohesive contacts.

     

Shear zones in porous sand: Insights from ring-shear experiments and naturally deformed sandstones

In a high-resolution small-scale seismic experiment we investigated the shallow structure of the Wadi Araba fault (WAF), the principal fault strand of the Dead Sea Transform System between the Gulf of Aqaba/Eilat and the Dead Sea. The experiment consisted of 8 sub-parallel 1 km long seismic lines crossing the WAF. The recording station spacing was 5 m and the source point distance was 20 m. The first break tomography yields insight into the fault structure down to a depth of about 200 m. The velocity structure varies from one section to the other which were 1 to 2 km apart, but destinct velocity variations along the fault are visible between several profiles. The reflection seismic images show positive flower structures and indications for different sedimentary layers at the two sides of the main fault. Often the superficial sedimentary layers are bent upward close to the WAF. Our results indicate that this section of the fault (at shallow depths) is characterized by a transpressional regime. We detected a 100 to 300 m wide heterogeneous zone of deformed and displaced material which, however, is not characterized by low seismic velocities at a larger scale. At greater depth the geophysical images indicate a blocked cross-fault structure. The structure revealed, fault cores not wider than 10 m, are consistent with scaling from wear mechanics and with the low loading to healing ratio anticipated for the fault.     

Interactions climat-eustatisme-tectonique. Les enseignements et perspectives du Crétacé supérieur (Cénomanien-Coniacien)

Résumé

Une analyse de séries sédimentaires d’âge Crétacé supérieur dans le Sud-Est de la France a été entreprise et intégrée dans un cadre de stratigraphie séquentielle. Les limites Cénomanien–Turonien et la limite Turonien–Coniacien sont marquées par des variations rapides et de fortes amplitudes du niveau marin relatif. La comparaison effectuée avec d’autres bassins mondiaux nous amène à envisager le problème dans un cadre global. On constate : (1) le synchronisme d’événements à haute fréquence dans des contextes géodynamiques différents. (2) les effets de la superposition de cycles eustatiques hiérarchiquement différents, c’est-à-dire la superposition d’oscillations à haute fréquence sur une composante de 3^e ordre. Ces observations sont confrontées à deux hypothèses : le glacio-eustatisme et la tectonique à haute fréquence. © Elsevier, Paris.     

Denudation rates of the Quadrilátero Ferrífero (Minas Gerais, Brazil): Preliminary results from measurements of solute fluxes in rivers and in situ-produced cosmogenic Be

This paper investigates the denudation rates in the Quadrilátero Ferrífero, Minas Gerais State (Brazil). The aim is to compare chemical weathering rates from measurements of solute fluxes in rivers and long-term mean erosion rates deduced from in situ-produced cosmogenic ¹⁰Be concentrations measured in fluvial sediments. Both water samples and sediments were collected in fifteen stations (checkpoints) located in four hydrographic basins with low anthropogenic perturbations.Depending of the type of substratum, three degrees of chemical denudation rates from water samples are observed: (i) high rates in marbles; (ii) medium rates in schists, phyllites, granites, gneisses and migmatites; (iii) low rates in quartzites and itabirites. Preliminary results of long-term erosion rates deduced from in situ-produced ¹⁰Be are comparable with those of chemical rates.     

The effects of seasonal changes to in-stream vegetation cover on patterns of flow and accumulation of sediment

In-stream macrophytes are typically abundant in nutrient-rich chalk streams during the spring and summer months and modify the in-stream environment by altering river flows and trapping sediments. We present results from an inter-disciplinary study of two river reaches in the River Frome catchment, Dorset (UK). The investigation focused on how Ranunculus (water crowfoot), the dominant submerged macrophyte in the study reaches, modified patterns of flow and sediment deposition. Measurements were taken on a monthly basis throughout 2003 to determine seasonal patterns in macrophyte cover, associated changes in the distributions of flow velocities and the character and amount of accumulated fine sediment within stands of Ranunculus.Maximum in-stream cover of macrophytes exceeded 70% at both sites. Flow velocities were less than 0.1 m s^− 1 within the stands of Ranunculus and accelerated to 0.8 m s^− 1 outside the stands. During the early stages of the growth of Ranunculus, fine sediment mostly accumulated within the upstream section of the plant but the area of fine sediment accumulation extended into the downstream trailing section of the plant later in the growing season. The fine sediment accumulations were dominated by sand (63–1000 μm) with silts and clays (0.37–63 μm) comprising < 10% by volume. The content of organic matter in the accumulated sediments varied within stands, between reaches and through the growing season with values ranging between 9 and 105 mg g^− 1 dry weight. At the reach scale the two sites exhibited different growth forms of Ranunculus which created distinctive patterns of flow and fine sediment deposition.     

Dynamic stress variations due to shear faults in a plane-layered medium

A complete set of expressions is presented for the computation of elastic dynamic stress in plane-layered media. We use a discrete-wavenumber reflectivity method to compute the stress field radiated by arbitrary moment-tensor sources. The expressions derived here represent an interesting tool for both-the observational and theoretical analysis of dynamic stress changes associated with earthquake phenomena. Dynamic stress changes associated with a strike-slip fault having unilateral rupture are shown. This modelling, which is similar to the 1992 Landers California earthquake, illustrates the effects of distance, directivity and depth on transient stress changes.     

SIMS analyses of oxygen isotopes: Matrix effects in Fe-Mg-Ca garnets

Large instrumental mass fractionation (IMF) may occur during measurements of oxygen isotope ratios by SIMS. Part of this fractionation depends on crystal structure and mineral composition. In order to improve the accuracy of SIMS measurements, we gathered 6 commonly used garnet standards and prepared 6 others to adequately cover the composition range Alm_0-73, Prp_0-99, Grs_0-20. Electron microprobe analyses were performed at UBP-Clermont to check the chemical homogeneity of these standards. Oxygen isotope compositions were determined by laser fluorination and mass spectrometry at UW-Madison. Ten SIMS sessions and 336 δ¹⁸O measurements at CRPG-Nancy, on a Cameca IMS1270 instrument, demonstrate that the standards are homogeneous with external reproducibility of 0.3‰ (1σ). In terms of δ¹⁸O, SIMS measurements indicate that, during a single session, IMF can vary up to 6.3‰ from one garnet standard to another. In most of the sessions, IMF can be correlated with the grossular content. However, for a satisfactory correction scheme, we suggest the combination of the 3 main components (Ca, Fe, Mg). This is done using a simple least square calculation routine. The correction coefficients determined for each session can be used to calculate the IMF and correct the measured isotopic ratio of a garnet of known chemical composition. This way, we were able to reproduce the δ¹⁸O values of most of the Fe-Mg-Ca garnet standards within ± 0.6‰. Interestingly, the use of only 3 end-member standards (AlmCMG, PrpMM, GrsSE) plus a standard of intermediate composition (e.g. UWG-2) is sufficient to reproduce δ¹⁸O within the same precision. Thus, linear interpolation among end-member standards is satisfactory in the case of the garnet solid-solutions. Two studies carried out on zoned garnets from the Alps and the Pyrenees indicate that matrix effects become significant when variations in grossular contents are important (> 10%). In order to obtain reliable isotope ratio measurements on Fe-Mg-Ca garnets using a SIMS, we suggest a correction scheme using at least 3 reliable end-member standards plus a standard of intermediate composition (a garnet standard closest to the average composition of the analysed garnet). This allows cross-checking and incorporates a correction based on the variations in composition of zoned crystals.