Studies on syntheses and properties of novel CeO2/polyimide nanocomposite films from Ce(Phen)3 complex

A series of cerium dioxide (CeO₂)/polyimide (PI) nanocomposites were successfully prepared from Ce(Phen)₃ and polyamic acid (PAA) via the solution direct-dispersing method, followed by a step thermal imidization process. TGA and XPS studies showed that the cerium complex decomposed to form CeO₂ during the thermal imidization process at 300 °C. SEM observation showed that the formed CeO₂ as nanoparticles was well dispersed in polyimide matrix with a size of about 50-100 nm for samples with different contents of CeO₂. Thermal analysis indicated that the introduction of CeO₂ decreased the thermal stability of nanocomposite films due to the decomposition of Ce(Phen)₃ in the imidization process, while the glass transition temperature (T_g) increased obviously, especially nanocomposite films with high loading of CeO₂ exhibited a trend of disappearance of T_g. DMTA and static tensile measurements showed that the storage modulus of nanocomposite films increased, while the elongation at break decreased with increasing CeO₂ content.     

"课程思政"融入专业课程教学的研究与实践

"互联网+"时代给职业教育带来更多的机遇与挑战,人才培养工作的战略地位越来越突出,职业院校迫切需要进行"课程思政"改革,将"课程思政"融入专业课程教学中,采用多样的信息化手段,培养学生正确的世界观、人生观和价值观,凸显"课程思政"的育人功能.     

Preparation of modified LiMn2O4 by solid-state reaction

Modified lithium manganese oxides were prepared by solid-state reaction of LiMn2O4 and LiCoO2 as raw materials. A study was carried out by TG-DSC,XRD, DSC and electrochemical to analyse the reaction process and structural characterization of products. The results show that the LiMn2O4 reacts chemically with LiCoO2 at high temperature. All of Li and partial Co atoms can insert into the LiMn2O4 crystal lattice and a newly formed spinel phase-modified LiMn2O4 was obtained. The distribution of Co content is even in modified LiMN2O4 compound. The modified LiMn2O4 compound exhibits improved cycling stability at room and elevated temperature in comparison with the pure LiMn2O4.     

产业化影响下高校办学理念的思考

高等教育已经是一种产业，我们必须按产业化的规律来运作；高等教育是一种特殊的产业，我们必须凸现高等教育的特殊地位和特殊功能。以此为前提，在我们思考产业化影响下的高校办学理念时，应特别关注高等教育功能的前瞻性和先导性，强调以人为本，科学思维，体现哲学强校，在表述上要有特色和创新。     

基于VPN技术构建安全的无线校园网络

随着校园网络规模逐渐扩大,远程用户、远程办公人员、分支机构等不断增多,以及关键业务需求的增加,出现了一种通过公共网络（如Internet）来建立自己专用网络的技术,这种技术在无线校园网中的应用提高了校园网的可管理性、灵活性和安全性。     

基于一致性的综合能源系统低碳经济调度

综合能源系统(integrated energy system, IES)是解决能源损耗和环境污染问题的有效途径。为提高IES的经济性和环保性,提出了一种基于一致性的IES低碳经济调度策略。首先,在IES中引入阶梯式碳交易机制,在碳交易成本函数构造中,提出一种随着碳排区间而递增的成本系数,通过成本的非线性递增来限制碳排放量。其次,综合考虑能量传输过程中的损耗问题,构建一种结合用能需求和传输损耗的供需平衡约束条件。然后,将电、热、气供能单元的增量成本作为一致性变量,利用领导一致性算法对IES进行分布式调度,进而实现各单元的供能最优输出。最后,结合不同的实验案例验证了所提低碳经济调度策略的有效性。     

High sensitive and selective formaldehyde sensors based on nanoparticle-assembled ZnO micro-octahedrons synthesized by homogeneous precipitation method

Nanoparticle-assembled ZnO micro-octahedrons were synthesized by a facile homogeneous precipitation method. The ZnO micro-octahedrons are hexagonal wurtzite with high crystallinity. Abundant structure defects were confirmed on ZnO surface by photoluminescence. Gas sensors based on the ZnO micro-octahedrons exhibited high response, selectivity and stability to 1–1000 ppm formaldehyde at 400 °C. Especially, even 1 ppm formaldehyde could be detected with high response (S = 22.7). It is of interest to point out that formaldehyde could be easily distinguished from ethanol or acetaldehyde with a selectivity of about 3. The high formaldehyde response is mainly attributed to the synergistic effect of high contents of electron donor defects (Zn_i and V_O) and highly active oxygen species (O²⁻) on the ZnO surface.     

Preparation and characterization of single-crystalline gallium oxide nanobelts

Single-crystalline β-Ga₂O₃ nanobelts were synthesized by a simple physical evaporation method in argon atmosphere with the starting materials of Ga. The β-Ga₂O₃ nanobelts have a width of 50-100 nm and width-to-thickness ratios of 5-10, and length of up to a few millimeters, which may have potential applications in nanosize sensors or optoelectronic nanodevices.     

刚性转子-轴承系统的复杂非线性动力学行为研究

为揭示转子系统复杂的非线性行为,用多初始点分岔分析方法研究了刚性转子-轴承系统在转速、偏心等参数变化时系统响应随参数变化的非线性现象,各吸引子的吸引域在相空间中的变化情况,以及从单初始点出发系统在相空间中的运动规律。结果表明:多初始点分岔分析法能够发现更加丰富的非线性现象;在多吸引子共存的相空间不同的初始点系统稳态响应可能表现出不同的运动;根据相空间中吸引域的变化规律能够从机理上对传统单初始点方法得到的非线性现象进行很好的解释。     

凸圆弧前刀面车刀微量切削机理

研究了凸圆弧前刀面车刀微量切削机理，实验证实了该刀具在微切深和小进给量的工作情况下，切削均匀而连续，在加工逆性材料时，可获得连续不断的丝状切削，且能获得较小的表面粗糙度。