3D Printing Conductive Composites with Poly(ionic liquid) as a Noncovalent Intermedia to Fabricate Carbon Circuits

In this study, a kind of imidazole type poly(ionic liquid) ([PEP-MIM]Cl) is synthesized, which can disperse carbon effectively. [PEP-MIM]Cl is used as an intermediate to coat carbon on the poly(acrylic acid)(PAA-co-MBA) via ion exchange to obtain conductive polymer composite (CPC). A series of characterizations are performed. Experiments show that carbon can be coated on the PAA-co-MBA uniformly, and compared with using carbon as filler, this method requires less carbon to achieve good conductive performance. The carbon layer on the polymer's surface is enriched via the swelling-shrinking properties of PAA-co-MBA according to the SEM images. Furthermore, in combination with 3D printing technology, PAA-co-MBA can be designed into different shapes to achieve various functions such as pressure-sensing element. Finally, a new type of CPC named carbon clad polymeric laminate (CCPL) is prepared by using the carbon coating method and 3D printing technology. It has the potential to replace copper clad laminate (CCL) and printed circuit board (PCB), to a certain extent. This technology expands the preparation method and application of the CPC such as flexible and wearable conductive fabrics.     

Controllable synthesis of pure monodispersed zirconia nanopowders with tetragonal phase

Nanopowders of pure zirconia have been synthesized using citric acid (CA)-assisted lamellar liquid crystal template method. The microstructure of the zirconia powder prepared at the different mole ratios of CA to zirconium oxynitrate (ZN) was characterized by FT-IR, X-ray diffraction (XRD), laser particle size analyzer, Raman spectroscopy, and scanning electron microscope (SEM) methods. The phase structure of the sodium dodecyl sulfate (SDS)/C₁₀H₂₁OH/H₂O system before and after adding mixing solution CA and ZN was determined by POM (Polarizing Optical Microscope). The results show that lamellar structure of the SDS/C₁₀H₂₁OH/H₂O system after adding mixing solution CA and ZN is stable. The presence of CA inhibits agglomeration and growth of zirconia particle. The crystallite size of zirconia powders decreases and agglomerates lowly with addition of CA. Fourier transform infrared spectrometry (FI-IR) analyses reveal that the structure of chelating organic complex is maintained in zirconia structure at high-temperature calcination to cause oxygen vacancies which stabilizes the tetragonal phase of zirconia. The zirconia powders remained the single metastable tetragonal phase at the molar ratios of CA to ZN ranging from 1:3 to 5:1. The crystallite size of zirconia with spherical morphology varied from 32.2 to 20.1 nm with the increase of the molar ratio of CA to ZN in the range of 1:3 to 5:1.     

"清康熙将军罐"研究

将军罐出现于明,盛行于清,在康熙时期发展至鼎峰,是明清时期是极为重要的器型之一.本文以康熙将军罐为研究对象,结合时代背景,从器型、工艺、纹饰以及外销状况四方面分析总结其特点.     

Revealing Microstructural,Textural, and Hardness Evolution of Ti–6Al–4V Sheet Cooled From Sub β-Transus Temperature at Different Rates

Metallurgical and Materials Transactions A - A hot-rolled Ti–6Al–4V sheet was annealed at 960 °C (sub β-transus temperature) and then subjected to different coolings [in water...     

氧化剂对Cu-Al2O3复合材料微观组织的影响

研究了一种新型简化内氧化工艺,并制备了不同氧源系数的Cu-Al2O3复合材料。用SEM、TEM等分析手段对所制备复合材料烧结态的微观组织进行了研究。结果表明,该简化工艺成功制备了Cu-Al2O3复合材料,在铜基体上弥散分布着大量细小的γ-Al2O3颗粒,其粒径为5~20nm,颗粒间距为25~60nm,当氧源系数(k)为1.20时,压制粉末经烧结(950℃,4h)后全部完成内氧化,此氧化剂含量为最佳的内氧化氧化剂添加量。     

关于复杂黄铜的等效方法及其它

在复杂黄铜等效变换的多元变化过程中，存在着第三种当量系数Ｉ。它是确保合金转化为二元形式所必不可少的导向给定值，是一个定位常数。找出了Ｋ＋Ｊ＝０的误解的产生原因，论证了Ｋ＋Ｊ＝１所在达的过程的实质。指出用二元相图理解等效变换这一三元变化过程的认识误区。     

多通管塑挤胀形工艺的力学分析

讨论了以聚氨酯橡胶棒为胀形介质，采用塑挤胀形复合工艺把无缝管坯一次成形为多通管成品的加工方法，分析了多通管塑挤胀形过程，提出了“应变样条”分析法，进而分析了典型剖面上应力应变状态，讨论了成形力间应具备的合理的数值关系，以使变形区处于最有利于变形的超高的静水压力和合适的偏应力状态，获得尽可能长的支管。     

焊接船体接头设计指南（二）

（接上期） 8卷边和切口 尽量不要广泛使用卷边，因为切割不恰当的卷边有潜在的危险。在构件安装到位后，加强杆或横梁的坡口焊缝处总免不了要用卷边，就像纵向加强杆或舱底龙骨这种情况（图11）。     

铸造用α淀粉复合粘结剂粉体粒度分布的分形研究

模拟混砂机混碾过程，应用分形几何理论研究了α淀粉复合粘结剂及其各组分粉体的粒度分布特征，发现其粒度分布具有分形结构。分维可作为描述粉体粒度分布特征的一个序参量，其大小反映了粉体颗粒的粗细程度和集中、不均匀特征，即粉体粒度分布的空间结构性；且在监控粉磨机械效率、估测颗粒级配、分析设计复合粘结剂结构及性能等方面具有重要意义。最后，对按照本分形理论混制的型砂性能进行了实际测试和浇注实验验证。     

CR／MMA乳液接枝共聚物的研制

用乳液接枝共聚法制备ＣＲ／ＭＭＡ共聚物，讨论ＣＲ乳液、引发剂、接枝温度、ＭＭＡ用量对接枝共聚转化率，接枝ＭＭＡ含量、ＭＭＡ接枝效率和粘接性能的影响，用红外光谱对接枝共聚物进行表征，该共聚物具有较好的粘接性能。