Blanching and long‐term freezing affect various bioactive compounds of vegetables in different ways

An extensive study on the effects of blanching/freezing and long‐term freezer storage on various bioactive compounds of more than 20 commonly used vegetables was performed. Effects were strongly plant species‐dependent. Contents of dietary fibre components either were not affected or increased slightly. Minerals in general were also stable, but some losses of soluble minerals by leaching were observed. Phenolic antioxidants and vitamins were clearly more sensitive. Significant losses (20–30%) of antioxidant activity and total phenolics were detected in many vegetables. A qualitative HPLC profiling method for phenolic antioxidants was developed which proved to be very useful when evaluating the complex behaviour of phenolics during food processing. Up to one‐third of vitamin C contents were lost during blanching, and further slight losses were detected during storage. Folic acid turned out to be very sensitive to blanching, with more than half of the vitamin being lost, but was stable during freezer storage. Carotenoids and sterols were not affected by blanching or freezer storage. The usefulness of the applied screening methods for evaluation of the effects of processing on vegetables is shown. Copyright © 2003 Society of Chemical Industry     

Novel two-step synthesis of gold nanoparticles capped with bile acid conjugates

Bile acids and their conjugates are physiologically important molecules. Syntheses and structure elucidation combined with investigation of properties and applications of bile acids and their derivatives are of academic interest. The concept of using bile acids and their conjugates in nanoscience is a novel idea, which opens up fascinating prospects. In this article, an easy and simple route for obtaining N-lithocholyl-l-(cysteine ethyl ester) (3), capable of effectively capping and stabilizing metal nanoparticles, is described. The whole synthetic route needs only two steps giving a moderate to good yield. The gold NPs are characterized by elemental analysis, UV spectroscopy, and TEM. Additionally, ¹³C CP/MAS NMR studies for different ligand/Au ratios have been performed.     

Immunologic evaluations during prolonged and chronic hepatitis. Significance for diagnosis and prognosis. 100 cases]

This retrospective study illustrates the valuable contribution of immunological studies carried out during the third month of hepatitis. The persistence of HBs antigen at this stage of the disease considerably increases the risk of chronic hepatitis though not necessarily implying progression to cirrhosis. The latter should be feared if there is a marked increase in gamma globulins and in the presence of a high level of anti-smooth muscle and antinuclear antibodies. Amongst the other immunological features, an increase in IgA and IgM also indicates the possibility of progression from chronic hepatitis to cirrhosis. Comparative study in chronic active hepatitis of HBs antigen and various antibodies indicates essentially three types: - CAH with Ag HBs without auto-antibodies - Auto-immune CAH without Ag HBs - CAH without auto-antibodies nor Ag HBs. Progression to cirrhosis appears to be less frequent in the first group than in the second.     

Mechanical properties of cellulose nanofiber (CNF) reinforced polylactic acid (PLA) prepared by twin screw extrusion

The aim of this study was to develop cellulose nanofiber (CNF) reinforced polylactic acid (PLA) by twin screw extrusion. Nanocomposites were prepared by premixing a master batch with high concentration of CNFs in PLA and diluting to final concentrations (1, 3, 5 wt.%) during the extrusion. Morphology, mechanical and dynamic mechanical properties (DMA) were studied theoretically and experimentally to see how different CNF concentrations affected the composites’ properties. The tensile modulus and strength increased from 2.9 GPa to 3.6 GPa and from 58 MPa to 71 MPa, respectively, for nanocomposites with 5 wt.% CNF. The DMA results were also positive; the storage modulus increased for all nanocomposites compared to PLA; being more significant in the high temperature region (70 °C). The addition of nanofibers shifted the tan delta peak towards higher temperatures. The tan delta peak of the PLA shifted from 70 °C to 76 °C for composites with 5 wt.% CNF.     

Extended frequency-band-decomposition sigma–delta A/D converter

Parallelism can be used to increase the bandwidths of ADC converters based on sigma–delta modulators. Each modulator converts a part of the input signal band and is followed by a digital filter. Unfortunately, solutions using bandpass sigma–delta modulators are very sensitive to the position of the modulators’ central frequencies. This paper shows the feasibility of a frequency-band-decomposition (FBD) ADC using continuous time bandpass sigma–delta modulators, even in the case of large analog mismatches. The major benefit of such a solution, called extended-frequency-band-decomposition (EFBD) is its low sensitivity to analog parameters. For example, a relative error in the central frequencies of 4% can be accepted without significant degradation in the performance (other published FBD ADCs require a precision of the central frequencies better than 0.1%). This paper will focus on the performance which can be reached with this system, and the architecture of the digital part. The quantization of coefficients and operators will be addressed. It will be shown that a 14 bit resolution can be theoretically reached using 10 sixth-order bandpass modulators at a sampling frequency of 800 MHz which results in a bandwidth of 80 MHz centered around 200 MHz (the resolution depends on the effective quality factor of the filters of the analog modulators).     

Circular-array ultrasound holography imaging using the linear-array approach

A circular-array, pulse-echo, ultrasound holography imaging method is presented. The configuration of the measurement system is much simpler than that of traditional computed-tomography (CT) and compound beta-scan imaging. Wide-beam insonification is used. The geometrical differences of the circular array compared with a linear array system are corrected in the frequency domain of the hologram. The computation time of the reconstruction process for a circular image is practically the same as that of a linear array imaging process using the backward propagation (BP) principle. A fast Fourier transform (FFT) algorithm is directly used in the reconstruction process. Computer simulation shows that the resolution of this imaging method can surpass that of a linear-array system. In the preliminary experiments, 2-mm resolution was achieved in both the lateral and radial directions with an ultrasound frequency of 2 MHz.     

Tension between perceived collocation and actual geographic distribution in project teams

This paper describes an exploratory comparative study of knowledge workers and their challenges in high tech global project teams. More specifically we focus on the tension between perceived collocation and actual geographical distributed project work as a function of: (1) the demand to distribute and shift attention in multi-teaming, (2) virtuality i.e. number of virtual teams participants engage in, (3) the continuous adjustment and re-adjustment to new places they perform their activity, and (4) the collaboration technologies they use. We present the methodology for data collection that included semi-structured interviews, surveys, and on site shadowing of the project participants, and discuss the findings from the data analysis. The study is based on the bricks-bits-interaction framework. It is at the intersection of the design of physical spaces, i.e., bricks; rich digital information and collaboration technology (ICT) content, mobile devices and network infrastructures, i.e., bits, and emergent work practices, process, and new ways people behave in communicative events using the affordances of ICT augmented physical, virtual spaces and digital content, i.e., interaction.     

Crosslinked poly(vinyl alcohol) composite films with cellulose nanocrystals: Mechanical and thermal properties

In this work, poly(vinyl alcohol) (PVA) and cellulose nanocrystals (CNCs) were crosslinked using sodium tetraborate decahydrate (borax) to improve the mechanical and thermal properties of the neat PVA. The results showed that the CNCs affected the crystallization behavior of the crosslinked PVA. The crystallization temperature of the crosslinked PVA with CNCs increased considerably from ～152 to ～187 °C. The continuous improvement of the thermal stability was observed with the increasing content of CNCs in the crosslinked PVA films. Additionally, the strong interaction between the CNCs and PVA was theoretically estimated from the Young's modulus values of the composites. Thermodynamic mechanical testing revealed that the crosslinked PVA composite films with CNCs could bear higher loads at high temperature compared to the films without the CNCs. At 60 °C, 2.7 GPa was reported for the storage modulus of the crosslinked composites with 3 wt % of CNCs, twice as high as that for the crosslinked films without CNCs. Moreover, creep results were improved when CNCs were added in the crosslinked nanocomposites. The materials prepared in this work could broaden the opportunities for applications in a wide range of temperatures. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45710.