Dielectric spectroscopic study of wood plastic combinations

Curing of wood-polyester combitions was studied by recording dielectric spectra as a function of temperature at fixed frequency at different stages of cure and as function of cure-time at fixed temperature. The measurements were preformed by a specially constructed continuously recording spectrometer equipped with linear temperature program. By measuring the shifts of the dielectric transition temperatures it was possible to follow changes of the molecular mobilities in the resin as crosslinking proceeded. By measuring the relative intensities of the dielectric absorption the change of the concentration of the polar groups as a function of cure time could be followed. The existence of a stepwise aftercuring waw revealed.     

GPC study of ethylene-propylene copolymers combined with viscometry and IR spectroscopy

Summary By combining GPC fractionation with IR spectroscopy of ethylene-propylene copolymer (EP) samples, it has been shown that copolymer composition of EP's used in this study does not dep-end on molecular weight. Thus, contrary to earlier investigations by others, molecular weight distributions (MWD) and averages of EP's have been determined by using only experimental data such as GPC traces, universal calibration curve of GPC, and intrinsic viscosities. A comparative study has been carried out by using the MV method (called median value method) and the method of Ogawa and Inaba (OI method) for determination of MWD's and molecular weight averages of EP's. Application of the MV method results in lower molecular weight averages than the use of the equations proposed by Ogawa and Inaba for calculation of Mark-Houwing constants of EP's. However, polydispersities were found to be the same in both methods. The MV method also yields composition depending reliable pairs of Mark-Houwink constants, a and K, for EP's in 1,2,4-trichloro-benzene at 135 °C.     

On radiant energy in high-temperature research

The mechanism of heating solids with radiant energy is reviewed and the need for measuring radiative properties is pointed out. Image furnaces are suitable for such measurement at high temperatures. The limitations of image furnace operations are discussed and methods as well as equipment offered to overcome the limitations. The importance of artificial black bodies in high-flux measurements is described and a new shape for such cavities is proposed. Data comparing this shape with hitherto used shapes are tabulated. Design for a fast-action on-off shutter for image furnaces is presented. In its retracted position the shutter does not cast any shadow on the mirror and it does not require artificial cooling even when exposed to radiation.     

Influence of naltrexone on cue-elicited craving among hazardous drinkers: The moderational role of positive outcome expectancies.

This study was designed to elucidate mechanisms by which naltrexone (NTX) influences drinking among hazardous drinkers. Thirty-six hazardous drinkers received 50 mg NTX or placebo on 2 separate occasions before participation in a taste test procedure with low-alcohol beer. Urges to drink before consumption, beer volume consumed, and perceived stimulation and sedation after consumption were assessed. Although NTX did not influence beer consumption, hazardous drinkers who reported high positive reinforcement expectancies rated their urges to drink as significantly lower when they were on NTX compared with placebo. Positive outcome expectancies also moderated the effects of NTX on subjective reports of stimulation following drinking. These findings suggest that naltrexone may be particularly effective at reducing alcohol cue-elicited positive reinforcement for those with high positive alcohol outcome expectancies. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The influence of ECAP on the small punch creep of Al–4 vol.% Al<Subscript>4</Subscript>C<Subscript>3</Subscript> composite

The creep behaviour of a composite based on an aluminium matrix reinforced by 4 vol.% Al₄C₃ was studied at temperatures of 623 and 723 K by small punch testing with a constant force. The composite was tested in two different states: (i) as received by mechanical alloying with hot extrusion (HE) as the final operation and (ii) with equal channel angular pressing (ECAP) superimposed on the hot-extruded material. The ECAP does not improve the observed creep resistance. The reduction of force leading to the same deflection rate is not very significant. This points out that the ECAP process of the present composite, which produces substantial strengthening at lower temperatures, is not accompanied by pronounced weakening of creep resistance at elevated temperatures. The threshold force in the ECAP material is about 5 N weaker than in the HE material.     

Publication and cooperation patterns of the authors of neuroscience journals

Characteristics of publication activity and co-authorship in neurosciences are analysed. The present study aims at describing the common, as well as the distinguishing features of productivity and co-publication patterns of four types of authors. For this purpose, authors are classified according to their anterior and posterior records. The role of the author types in the process of documented scientific communication, the relation between co-authorship and publication activity, as well as collaboration between the four types is studied. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Role of Inflammatory Mediators in the Development of Gastrointestinal Motility Disorders

Feeding intolerance and the development of ileus is a common complication affecting critically ill, surgical, and trauma patients, resulting in prolonged intensive care unit and hospital stays, increased infectious complications, a higher rate of hospital readmission, and higher medical care costs. Medical treatment for ileus is ineffective and many of the available prokinetic drugs have serious side effects that limit their use. Despite the large number of patients affected and the consequences of ileus, little progress has been made in identifying new drug targets for the treatment of ileus. Inflammatory mediators play a critical role in the development of ileus, but surprisingly little is known about the direct effects of inflammatory mediators on cells of the gastrointestinal tract, and many of the studies are conflicting. Understanding the effects of inflammatory cytokines/chemokines on the development of ileus will facilitate the early identification of patients who will develop ileus and the identification of new drug targets to treat ileus. Thus, herein, we review the published literature concerning the effects of inflammatory mediators on gastrointestinal motility.     

Isocyanonaphthol Derivatives: Excited-State Proton Transfer and Solvatochromic Properties

Fluorescent probes that exhibit solvatochromic or excited-state proton-transfer (ESPT) properties are essential tools for the study of complex biological or chemical systems. Herein, the synthesis and characterization of a novel fluorophore that reveals both features, 5-isocyanonaphthalene-1-ol (ICOL), are reported. Various solvatochromic methods, such as Lippert–Mataga and Bilot–Kawski, together with time-dependent density functional theory (TD-DFT) and time-resolved emission spectroscopy (TRES), were applied to gain insights into its excited-state behavior. To make comparisons, the octyloxy derivative of ICOL, 5-isocyano-1-(octyloxy)naphthalene (ICON), was also prepared. We found that internal charge transfer (ICT) takes place between the isocyano and –OH groups of ICOL, and we determined the values of the dipole moments for the ground and excited states of both ICOL and ICON. Furthermore, in the emission spectra of ICOL, a second band at higher wavelengths (green emission) in solvents of higher polarities (dual emission), in addition to the band present at lower wavelengths (blue emission), were observed. The extent of this dual emission increases in the order of 2-propanol < methanol < N,N-dimethylformamide (DMF) < dimethyl sulfoxide (DMSO). The presence of the dual fluorescence of ICOL in these solvents can be ascribed to ESPT. For ICOL, we also determined ground- and excited-state pK_a values of 8.4 ± 0.3 and 0.9 ± 0.7, respectively, which indicates a considerable increase in acidity upon excitation. The TRES experiments showed that the excited-state lifetimes of the ICOL and ICON spanned from 10.1 ns to 5.0 ns and from 5.7 ns to 3.8 ns, respectively. In addition, we demonstrated that ICOL can be used as an effective indicator of not only the critical micelle concentration (cmc) of ionic (sodium lauryl sulfate (SLS)) and nonionic surfactants (Tween 80), but also other micellar parameters, such as partition coefficients, as well as to map the microenvironments in the cavities of biomacromolecules (e.g., BSA). It is also pointed out that fluorescence quenching by pyridine can effectively be utilized for the determination of the fractions of ICOL molecules that reside at the water–micelle interface and in the interior spaces of micelles.