针对更精确电迁移预测应用的热耦合模型建模

基于先进逻辑CMOS工艺平台,构建了集成电路热耦合模型,为后端金属线电迁移预测提供更精确的温度变化和分布信息。在建模过程中,为了提高建模和仿真效率,对金属线网络和晶体管有源区进行简化,并用热传输比率对热耦合进行表征。考虑到晶体管参数、金属线走向、金属线之间相对位置对热传输比率的影响,模型中引入相关因子对热传输比率做进一步修正。最后,将该热传输模型嵌入到商用仿真软件中。结果表明,热传输比率(即温度)的仿真值与基于工艺平台流片的实测值吻合良好,验证了模型的准确性。     

Cyber-based design for additive manufacturing using artificial neural networks for Industry 4.0

Additive Manufacturing (AM) requires integrated networking, embedded controls and cloud computing technologies to increase their efficiency and resource utilisation. However, currently there is no readily applicable system that can be used for cloud-based AM. The objective of this research is to develop a framework for designing a cyber additive manufacturing system that integrates an expert system with Internet of Things (IoT). An Artificial Neural Network (ANN) based expert system was implemented to classify input part designs based on CAD data and user inputs. Three ANN algorithms were trained on a knowledge base to identify optimal AM processes for different part designs. A two-stage model was used to enhance the prediction accuracy above 90% by increasing the number of input factors and datasets. A cyber interface was developed to query AM machine availability and resource capability using a Node-RED IoT device simulator. The dynamic AM machine identification system developed using an application programme interface (API) that integrates inputs from the smart algorithm and IoT interface for real-time predictions. This research establishes a foundation for the development of a cyber additive design for manufacturing system which can dynamically allocate digital designs to different AM techniques over the cyber network.     

竞态漏洞检测方法综述

并行化程序运行环境中资源竞争导致的竞态漏洞是当今操作系统安全的重要威胁之一,攻击者常常间接利用竞态漏洞实施诸如远程命令执行、本地提权等攻击行为。分析了不同条件下竞态漏洞的产生机理及其相互关系,提出了竞态漏洞检测基本范式和通用框架,分别综述了用户态和内核态竞态漏洞检测方法的技术思想和发展脉络,讨论了制约检测效率的瓶颈问题以及可能的解决方法,结合最新技术应用指出了未来发展趋势和亟待解决的问题。     

Synthesis of soluble oligsiloxane-end-capped hyperbranched polyazomethine and their application to CO2/N2 separation membranes

Three soluble hyperbranched polyazomethines containing oligosiloxane end group HBP-PAZ-SiO_n were successfully synthesized. HBP-PAZ-SiO_ns were used as modifiers of ethyl cellulose (EC) and polysulfone (PS) membranes. Blend membranes, HBP-PAZ-SiO_n/EC and HBP-PAZ-SiO_n/PS were prepared by blending the THF solution of HBP-PAZ-SiO_n with ethanol solution of EC and dichloromethane solution of PS, respectively. Surprisingly, the permeabilities for CO₂ of the blend membranes were more than 15–16 times higher than those of pure EC and PS membranes without any drop of pemselectivity to N₂. This unusual improvement has been achieved by both enhancement of diffusivity for carbon dioxide and nitrogen by the oligosiloxane groups and enhancement of affinity of the amino groups with carbon dioxide at the end groups of HBP-PAZ-SiO_n.     

基于成团效应的众核处理器失效核分布建模方法

随机产生失效核分布的方法不能反映众核处理器物理拓扑结构的真实状况,在评价相关拓扑重构算法的效能时有失客观性.本文针对这一现状,提出了一种基于缺陷成团效应的众核处理器失效核分布建模方法.实验表明,本方法得到的物理拓扑结构缺陷分布呈现出不同程度的成团特性,且成团效应会显著影响核级冗余技术的拓扑重构效果.     

微波-化学溶液联合作用下矿石的劣化机理研究

为了提高微波辅助磨矿的适用性,以红透山铜矿和思山岭铁矿为研究对象,分别采用微波、盐酸溶液、草酸溶液及其组合的方式对矿石进行预处理.对比了7种预处理方式下矿石的升温特征、表面形态、磨矿效果,并通过介电常数、波速、微观照片揭示矿石的劣化机理.试验结果表明:铜矿和铁矿浸酸后介电常数减小,导致微波作用下升温速率降低,温度分布更...     

光还原铁离子活化过硫酸盐系统去除水中碘海醇

过渡金属Fe2+是最经济有效且环境友好的PS活化物质,但是Fe2+易于被氧化而失去活化能力导致Fe2+/PS体系持续效果较差。为了提高Fe2+活化PS氧化降解有机污染物的效率,本论文将医学上常用的碘化X射线显影剂（ICM）的典型代表碘海醇（Iohexol）作为目标污染物,研究其在UV/PS、Fe(C2O4)33-/PS、UV/Fe(C2O4)33-/PS和Fe2+/PS 4种高级氧化体系中的降解,考查Fe(C2O4 )33-浓度、紫外光强和pH对UV/Fe(C2O4)33-/PS体系中碘海醇降解和PS活化分解的影响,并且分析体系中Fe2+浓度变化及其转化率。结果表明：4种高级氧化体系中碘海醇的氧化分解率分别为：83.8%、7.0%、98.8%、69.9%,其中,UV/Fe(C2O4 )33-/PS体系能够通过紫外光促进铁离子还原,溶液中对PS起活化作用的Fe2+逐渐释出,对碘海醇的降解最为高效彻底。随着Fe(C2O4 )33-浓度的增加,UV/Fe(C2O4 )33-/PS体系中PS的分解率不断增加,而碘海醇的降解率却先增加后减少。4种不同初始Fe(C2O4 )33-浓度下（20 μM、50 μM、100 μM、200 μM）,碘海醇降解速率依次为：100 μM ＞ 200 μM ＞ 50 μM ＞ 20 μM。在UV/Fe(C2O4 )33-/PS体系中,Fe2+浓度均是先快速增加后缓慢下降,碘海醇的降解率、PS的分解率以及Fe2+的最高转化率均与光强正相关,与pH负相关。因此,利用紫外光还原铁离子能够极大的提高提高Fe2+活化PS效率,且体系对于光强、pH等影响因素有较强的适应能力,在水处理高级氧化领域的具有较大的应用前景。     

Revealing the Kinetic Balance between Proton-Feeding and Hydrogenation in CO2 Electroreduction

Electrocatalytic reduction of CO₂ to high-value-added chemicals provides a feasible path for global carbon balance. Herein, the fabrication of Ni_NPx@Ni_SAy-NG (x,y = 1, 2, 3; NG = nitrogen-doped graphite) is reported, in which Ni single atom sites (Ni_SA) and Ni nanoparticles (Ni_NP) coexist. These Ni_NPx@Ni_SAy-NG presented a volcano-like trend for maximum CO Faradaic efficiency (FE_CO) with the highest point at Ni_NP2@Ni_SA2-NG in CO₂RR. Ni_NP2@Ni_SA2-NG exhibited ≈98% of maximum FE_CO and a large current density of −264 mA cm⁻² at −0.98 V (vs. RHE) in the flow cell. In situ experiment and density functional theory (DFT) calculations confirmed that the proper content of Ni_SA and Ni_NP balanced kinetic between proton-feeding and CO₂ hydrogenation. The Ni_NP in Ni_NP2@Ni_SA2-NG promoted the formation of H* and reduced the energy barrier of *CO₂ hydrogenation to *COOH, and CO desorption can be efficiently facilitated by Ni_SA sites, thereby resulting in enhanced CO₂RR performance.     

Tribological performance of UV picosecond laser multi-scale composite textures for C/SiC mechanical seals: Theoretical analysis and experimental verification

The performance of mechanical seals can be improved by using multi-scale composite textures with spiral grooves and micro-dimples, but without a clear texture function mechanism, it is difficult to optimize the textures on the sealing surface. This research established a mathematical model based on the mass-conservative JFO cavitation boundary to analyze the mechanical seal performance of multi-scale composite micro-textures. We use the multi-grid method for numerical solutions, investigate the hydrodynamic lubrication characteristics of composite-textured mechanical seals, and inspect the coupling effect of micro-dimples and spiral grooves. We also analyzed the influence of the geometrical parameters of composite textures on the sealing performance and optimized the sealing surface textures using theoretical analysis. The numerical analysis showed that the multi-scale composite-textured mechanical seal produced a coupling effect between the micro-dimples and spiral grooves, which improved the lubrication of the sealing pair. Eventually, C/SiC mechanical seal bench tests confirmed the tribological improvement of composite textures compared with the un-textured seal under various sealing liquid pressures and rotation speeds. Through comparing the Stribeck curve, the multi-scale composite textured C/SiC mechanical seals have a lower and more stable friction torque than the un-textured.     

手性有机多孔材料的合成及其手性拆分膜研究进展

随着光学纯化合物需求的不断增加,手性分离的研究在医药、化学、生物学等领域具有重要意义.膜分离法是近年来发展的一种新型节能技术,具有连续操作、易于放大、无污染等优点,被认为是一种具有潜力的大规模拆分对映异构体的方法.大多数一维聚合物手性分离膜的选择性与通量之间呈反向关系,且耐溶剂性差,导致分离性能不稳定,通量较低.有机多...