Electrodes based on nano-tree-like vanadium nitride and carbon nanotubes for micro-supercapacitors

Vanadium nitride(VN) was deposited by DC-sputtering on a vertically aligned carbon nanotube(CNTs)template for the purpose of nano-structuration. This led to the fabrication of hierarchically composite electrodes consisting of porous and nanostructured VN grown on vertically aligned CNTs in a nano-treelike configuration for micro-supercapacitor application. The electrodes show excellent performance with an areal capacitance as high as 37.5 m F cm~(-2) at a scan rate of 2 mV s~(-1) in a 0.5 MK_2SO_4 mild electrolyte solution. Furthermore, the capacitance decay was only 15% after 20,000 consecutive cycles. Moreover,the capacitance was found to increase with VN deposit thickness. The X-ray photoelectron spectroscopy analyses of the electrodes before and after cycling suggest that the oxide layers that form at the VN surface is the responsible for the redox energy storage in this material. Such electrodes can compete with other transition metal nitride based electrodes for micro-supercapacitors.     

An axiomatic characterization of the ranking based on the h-index and some other bibliometric rankings of authors

In the last few years, many new bibliometric rankings or indices have been proposed for comparing the output of scientific researchers. We propose a formal framework in which rankings can be axiomatically characterized. We then present a characterization of some popular rankings. We argue that such analyses can help the user of a ranking to choose one that is adequate in the context where she/he is working.     

Image segmentation by a contrario simulation

Segmenting an image into homogeneous regions generally involves a decision criterion to establish whether two adjacent regions are similar. Decisions should be adaptive to get robust and accurate segmentation algorithms, avoid hazardous a priori and have a clear interpretation. We propose a decision process based on a contrario reasoning: two regions are meaningfully different if the probability of observing such a difference in pure noise is very low. Since the existing analytical methods are intractable in our case, we extend them to allow a mixed use of analytical computations and Monte-Carlo simulations. The resulting decision criterion is tested experimentally through a simple merging algorithm, which can be used as a post-filtering and validation step for existing segmentation methods.     

Experimental and Molecular Dynamics Simulations of Tribochemical Reactions with ZDDP: Zinc Phosphate–Iron Oxide Reaction

Zinc phosphate glass is considered to be the main constituent of tribofilms generated under boundary lubrication with zinc dialkyldithiophosphate (ZDDP), a well-known antiwear additive. The reaction occurring during friction between zinc phosphate glasses and steel native iron oxide layer is investigated by both an experimental approach and by Molecular Dynamics simulations (MD). The importance of this “tribochemical” reaction in the general ZDDP antiwear process is discussed.     

光学仿真分析在光电传感器开发过程中的应用

1 引言 光电传感器是指利用光电效应作为传感原理的传感器件,它主要由光源、光学通路、光电探测器等部分.光源发出的光照射到待检测的目标物体上,被目标物体调制后被光电探测器所接收.     

Zinc Dialkyl Phosphate (<Emphasis Type="Bold">ZP</Emphasis>) as an Anti-Wear Additive: Comparison with <Emphasis Type="Bold">ZDDP</Emphasis>

In this study, we are interested in the anti-wear properties of zinc dialkyl phosphate additive (ZP) in comparison with ‘classical’ zinc dialkyldithiophosphate (ZDDP). Friction tests were performed on a reciprocating tribometer using both ball-on-flat and cylinder-on-flat configurations under a Hertzian contact pressure of 0.9 GPa. Experiments were carried out as a function of temperature (25 and 100 °C), sliding speed (25, 50 and 100 mm/s) and additives concentrations. Ball wear scar diameters as well as friction coefficient were measured. In order to better understand the anti-wear mechanisms of these additives, friction tests were followed by surface analyses such as AES (Auger Electron Spectroscopy) and XPS (X-Ray Photoelectron Spectroscopy). Transmission Electron Microscopy (TEM) observations of the ZDDP and ZP tribofilms were also carried out to visualise the generated layers. The anti-wear capability of ZP molecule is discussed.     

On‐line acoustic attenuation spectroscopy of emulsions stabilized by vinyl alcohol–vinyl acetate copolymers: a model system for the suspension polymerization of vinyl chloride

BACKGROUND: Poly[(vinyl alcohol)‐co‐(vinyl acetate)] (PVA) copolymers obtained by partial hydrolysis of poly(vinyl acetate) are currently used as industrial stabilizers in the suspension polymerization of vinyl chloride monomer (VCM). Their molecular characteristics, mainly the average degree of hydrolysis (DH ) and average degree of polymerization (DPw ), have a major influence on the monomer droplet size and the properties of the final poly(vinyl chloride) resin. RESULTS: The average droplet size and size distribution of chlorobutane/water emulsions, as a model system for VCM/water emulsions, were studied using acoustic attenuation spectroscopy on‐line with an agitated laboratory reactor. The emulsions were stabilized by PVA with DH values between 73 and 88 mol% and DPw values between 450 and 2500. The effects of agitation speed, stirring time and concentration of the PVA copolymers were investigated. An attempt was made to correlate the interfacial tension and the droplet size. CONCLUSION: On‐line acoustic spectroscopy appears to be a suitable technique for the real‐time control of the droplet size of monomer suspensions. The advantages and limitations of the technique are outlined. The validity and the application limits of the commonly cited correlation between the droplet size and the Weber number are established for polymeric surfactant‐stabilized emulsions. Copyright © 2009 Society of Chemical Industry     

Comparison of the wound-activated transformation of caulerpenyne by invasive and noninvasive Caulerpa species of the Mediterranean

The invasive green alga, Caulerpa taxifolia, that has spread rapidly after its introduction into the Mediterranean and the North American Pacific, reacts to wounding by transforming its major metabolite caulerpenyne (1). This wound-activated reaction involves the transformation of the bis-enol acetate moiety of 1, releasing reactive 1,4-dialdehydes. The ability to perform this transformation is found also in both the noninvasive Mediterranean C. prolifera and the invasive C. racemosa. Trapping experiments, as well as transformation of the model substrate geranyl acetate, suggest that all three investigated Caulerpa spp. rely on esterases that act upon wounding of the algae by subsequently removing the three acetate residues of caulerpenyne. The resulting reactive 1,4-dialdehyde oxytoxin 2 (9) can be identified by liquid chromatography–mass spectrometry and is unstable in the wounded tissue. Caulerpenyne transformation occurs rapidly, and severe tissue damage caused degradation of more than 50% of the stored caulerpenyne within 1 min in all three algae. Prevention of the enzymatic reaction before extraction, by shock freezing the tissue with liquid nitrogen, was used for the determination of the caulerpenyne content in intact algae. It gives about twofold higher values compared to an established methanol extraction protocol. The speed and mechanism of the wound-activated transformation, as well as the caulerpenyne content in intact tissue of invasive and noninvasive Caulerpa spp., are comparable. Thus, this enzymatic , transformation, despite being fast and efficient, is likely not the key for the success of the investigated invasive species.     

Estimation of the total uncertainty of sky-radiance measurements in field experimental conditions: implications for the aerosol single-scattering albedo

We compare the spectral sky radiance measured by three ground-based optical radiometers during the second Aerosol Characterization Experiment (ACE-2) to estimate the total uncertainty of the radiance in field experimental conditions. The propagation of this uncertainty on the column-integrated aerosol single-scattering albedo omega0 at 868 nm is investigated. The radiance measurements are affected by a systematic gain uncertainty of less than 2% in the visible spectral region and within 6% in the near-IR region. Correcting the measured radiance by a systematic uncertainty reduces the dispersion of the omega0 from 0.07 to 0.03. Besides, the total relative uncertainty of the radiance measurements in field experimental conditions is within 4% at any wavelength. The corresponding uncertainty delta omega0 is 4% for an aerosol optical thickness of 0.2.     

Retrieval of the ultraviolet aerosol optical depth during a spring campaign in the Bavarian Alps

A measurement campaign was organized in March 1999 in the Bavarian Alps as part of the European project, Characteristics of the UV Radiation Field in the Alps (CUVRA), to analyze the effect of altitude, aerosols, and snow cover on ground-level UV spectral irradiance. We present the results of simultaneous measurements of aerosol optical depth (AOD) made at various sites on two cloudless days in March 1999. The two days exhibited different aerosol conditions. Results derived from spectral measurements of UV irradiance are compared with data from filter radiometer measurements made at discrete wavelengths extending from the UV to the near IR. The different methods generated values for the AOD that were in good agreement. This result confirms that one can use either method to retrieve the AOD with an uncertainty of approximately 0.03-0.05. On 18 March, high turbidity was observed at low altitude (400-nm AOD approximately 0.5 at 700 m above sea level), and the AOD decreased regularly with altitude; on 24 March, the turbidity was much less (0.11 at 700 m above sea level). On both days very low AODs (0.05-0.09) were measured at 3000 m above sea level. The spectral dependence of the AOD is often parameterized by the angstrom relationship; the alpha parameter is generally difficult or impossible to retrieve from spectral measurements because of the relatively narrow wavelength range (320-400 nm), and only one of the spectro-radiometers used during the campaign permits this retrieval. In most cases, during this field campaign, alpha was found by filter sunphotometers to be 1.1-1.5.