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71.
Jui Chakraborty Mithlesh K. Sinha Debabrata Basu 《Journal of the American Ceramic Society》2007,90(4):1258-1261
Bone, a natural composite, comprises non-stoichiometric calcium hydroxyapatite (HAp) precipitated in a controlled reaction environment of a highly aligned, anisotropic organic template (type I collagen) that leads to its exotic tensile and compressive strength. It differs from stoichiometric hydroxyapatite in composition, crystallinity, and other physical and mechanical properties. In the present study, functionalized biomolecular template-induced precipitation of HAp on an SS 316 L substrate following biomimetic route exhibits distinct alterations in crystal growth and geometry, which in turn indicates the potential of the process to develop a non-stoichiometric HAp coating on metal implants. 相似文献
72.
Santanu Basu Amitava Chakraborty Parukuttyamma Sujatha Devi Himadri Sekhar Maiti 《Journal of the American Ceramic Society》2005,88(8):2110-2113
Nanocrystalline La0.9 Sr0.1 Al0.85 Co0.05 Mg0.1 O3 oxide powder was synthesized by a citrate–nitrate auto-ignition process and characterized by thermal analysis, X-ray diffraction, and impedance spectroscopy measurements. Nanocrystalline (50–100 nm) powder with perovskite structure could be produced at 900°C by this process. The powder could be sintered to a density more than 96% of the theoretical density at 1550°C. Impedance measurements on the sintered samples unequivocally established the potential of this process in developing nanostructured lanthanum aluminate-based oxides. The sintered La0.9 Sr0.1 Al0.85 Co0.05 Mg0.1 O3 sample exhibited a conductivity of 2.40 × 10−2 S/cm in air at 1000°C compared with 4.9 × 10−3 S/cm exhibited by La0.9 Sr0.1 Al0.85 Mg0.15 O3 . 相似文献
73.
Shankar Chakraborty Runumi Bordoloi 《The International Journal of Advanced Manufacturing Technology》2006,29(5-6):577-583
A number of recent research works have focused on how to improve the performance of production systems. This paper examines
the system based on a simulation model with two manufacturing cells under a re-entrant environment. With the model a set of
experiments has been carried out to study how the factors influence the system performance. Different release times and lot
sizes have been compared, and scheduling heuristics for both bottleneck and non-bottleneck have been discussed to capture
the essence of the production system. We used ANOVA to analyze the experimental results and achieved the conclusions that:
interval releasing is better than beginning releasing; lot size can improve one of the performance indicators, but deteriorate
the other under interval releasing; NC policy can obtain both good due-date performance and high throughput. 相似文献
74.
Sarbani Ghoshal Sandip Mukherjee Molee Chakraborty Eliwaza Naomi Msengi Jake Haubner Anutosh Chakraborty 《International journal of molecular sciences》2022,23(4)
(1) Background: We previously demonstrated that disruption of IP6K1 improves metabolism, protecting mice from high-fat diet-induced obesity, insulin resistance, and non-alcoholic fatty liver disease and steatohepatitis. Age-induced metabolic dysfunction is a major risk factor for metabolic diseases. The involvement of IP6K1 in this process is unknown. (2) Methods: Here, we compared body and fat mass, insulin sensitivity, energy expenditure and serum-, adipose tissue- and liver-metabolic parameters of chow-fed, aged, wild type (aWT) and whole body Ip6k1 knockout (aKO) mice. (3) Results: IP6K1 was upregulated in the adipose tissue and liver of aWT mice compared to young WT mice. Moreover, Ip6k1 deletion blocked age-induced increase in body- and fat-weight and insulin resistance in mice. aKO mice oxidized carbohydrates more efficiently. The knockouts displayed reduced levels of serum insulin, triglycerides, and non-esterified fatty acids. Ip6k1 deletion partly protected age-induced decline of the thermogenic uncoupling protein UCP1 in inguinal white adipose tissue. Targets inhibited by IP6K1 activity such as the insulin sensitivity- and energy expenditure-inducing protein kinases, protein kinase B (PKB/Akt) and AMP-activated protein kinase (AMPK), were activated in the adipose tissue and liver of aKO mice. (4) Conclusions: Ip6k1 deletion maintains healthy metabolism in aging and thus, targeting this kinase may delay the development of age-induced metabolic dysfunction. 相似文献
75.
Jacob M. LaManna Subhadeep Chakraborty Jeffrey J. Gagliardo Matthew M. Mench 《International Journal of Hydrogen Energy》2014
Liquid water saturation profiles were determined using high resolution neutron radiography for commercially available fuel cell materials and hardware. Temperature, pressure, and relative humidity (concentration) gradients were imposed on the cell to determine individual influences on water content for each gradient. The asymmetric anode/cathode channel/land architecture used in this work results in significant water accumulation in the anode diffusion media with saturation values of up to ∼50%. Anode water content was found to change substantially with imposed pressure or concentration gradient, whereas the cathode saturation profile remained relatively consistent, indicating the channel/land ratio and thickness have a determinant role in diffusion media retention. The data generated in this work has been made publicly available through www.pemfcdata.org, and should be useful for computational modelers seeking validation data. 相似文献
76.
Hydroxypropylcellulose (HPC) has been used as a steric stabilizer for preparing polyaniline dispersions using the route of oxidative dispersion polymerization of aniline. Using strongly acidic conditions (1 mol l?1 HCl), low temperature of about 2 °C and a concentration of aniline as low as 0.5%, ammonium peroxodisulfate at 1.25% and hydroxypropylcellulose concentrations at 0.5–1 g d l?1, unstable dispersions were obtained not only in water but also in aqueous alcohols (ethanol and methanol) up to at least 70 vol% alcohol. In contrast, dispersions that remained stable for at least 72 h were obtained when the alcohol concentration of the medium was as high as about 80 vol%. Kinetic studies of the polymerization systems suggested that success in the latter case was due to a lowering of the rate of polymerization. Transmission electron microscopy studies showed that dispersion particles prepared in 80 vol% alcohol media are spherical in shape and their diameter decreases with increasing stabilizer concentration. However, a change of morphology from spherical to aggregated needle‐shaped was observed when the rate was increased by increasing the aniline concentration from 0.5% to 0.75% g d l?1 in the above recipe. The aggregated particles were found to be broken down to spherical nanoparticles when the as‐prepared dispersions were sonicated for about 30 min. The sonicated dispersion on drying showed the presence of fractal clusters of polyaniline particles in the dried film. The fractal dimension was determined to be 1.77 which agreed well with the theoretical value determined by computer simulation based on a diffusion limited cluster–cluster aggregation model in three dimensions. © 2001 Society of Chemical Industry 相似文献
77.
78.
The transport of flame surface density (FSD) in turbulent premixed flames has been studied using a database obtained from Direct Numerical Simulation (DNS). Three-dimensional freely propagating developing statistically planar turbulent premixed flames have been examined over a range of global Lewis numbers from 0.6 to 1.2. Simplified chemistry has been used and the emphasis is on the effects of Lewis number on FSD transport in the context of Reynolds-averaged closure modelling. Under the same initial conditions of turbulence, flames with low Lewis numbers are found to exhibit counter-gradient transport of FSD, whereas flames with higher Lewis numbers tend to exhibit gradient transport of FSD. Stronger heat release effects for lower Lewis number flames are found to lead to an increase in the positive (negative) value of the dilatation rate (normal strain rate) term in the FSD transport equation with decreasing Lewis number. The contribution of flame curvature to FSD transport is found to be influenced significantly by the effects of Lewis number on the curvature dependence of the magnitude of the reaction progress variable gradient, and on the combined reaction and normal diffusion components of displacement speed. The modelling of the various terms of the FSD transport equation has been analysed in detail and the performance of existing models is assessed with respect to the terms assembled from corresponding quantities extracted from DNS data. Based on this assessment, suitable models are identified which are able to address the effects of non-unity Lewis number on FSD transport, and new or modified models are suggested wherever necessary. 相似文献
79.
I. G. Siddhalingeshwar A. Behera R. Mitra M. Chakraborty 《Transactions of the Indian Institute of Metals》2009,62(4-5):379-382
In situ Al-4.5Cu-5TiB2 composite has been processed through stir casting method, in which, the TiB2 particles have been precipitated in situ by mixed salt route involving reactions between K2TiF6 and KBF4.The as-cast specimens containing 20 volume percent liquid content have been subjected to three mushy state roll passes, each leading to 5 percent reduction in thickness. The grain structure has been found to be globular in the mushy state rolled composites. Measurements along the cross-section have shown decrease in average grain size and increase in hardness, as one proceeds along the direction of rolling. On the other hand, grain size and hardness have been found to be more or less similar, when compared for sections perpendicular to the rolling direction. 相似文献
80.
A model of a downdraft gasifier has been developed based on chemical equilibrium in the pyro‐oxidation zone and finite rate kinetic‐controlled chemical reactions in the reduction zone. The char reactivity factor (CRF) in the reduction zone, representing the number of active sites on the char and its degree of burn out, has been optimized by comparing the model predictions against the experimental results from the literature. The model predictions agree well with the temperature distribution and exit gas composition obtained from the experiments at CRF=100. A detailed parametric study has been performed at different equivalence ratios (between 2 and 3.4) and moisture content (in the range of 0–40%) in the fuel to obtain the composition of the producer gas as well as its heating value. It is observed that the heating value of the producer gas increases with the increase in the equivalence ratio and decrease in the biomass moisture content. The effect of divergence angle of the reduction zone geometry (in the range of 30–150°) on the temperature and species concentration distributions in the gasifier has been studied. An optimum divergence angle, giving the best quality of the producer gas, has been identified for a particular height of the reduction zone. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献