Warm forging: new forming sequence for the manufacturing of long flat pieces

Warm forming of steel is an economic and ecologic alternative to the conventional hot forging technology. It offers several advantages like decreased energy input, reduced scale formation, better surface quality and closer tolerances. Warm forming is common for rotation symmetric parts but has not been applied for long flat pieces yet. The main obstacles prohibiting the transfer are the missing of a suitable preforming technology and the problems to keep the narrow temperature tolerances despite the increased number of forming operations compared to rotation-symmetric process routes. In a cooperative effort within a European consortium of forges and scientific institutes, closed-die warm forging processes for long flat pieces have been developed. To cover a wide range of longitudinal geometries, two model products, a connecting rod and a steering link, with unequal requirements towards the production process have been selected. The process developed for the steering link is discussed in this article.     

Performance loss of proton exchange membrane fuel cell due to hydrophobicity loss in gas diffusion layer: Analysis by multiscale approach combining pore network and performance modelling

Loss of hydrophobicity in the gas diffusion layers (GDL) is sometimes suggested as a potential mechanism to explain in part the performance loss of PEMFC. The present study proposes a numerical methodology to analyse this effect by combining pore network modelling (PNM) and performance modelling (PM): the PNM/PM approach. PNM allows simulating the decrease of through-plane gas diffusion coefficient in the GDL as a function of the hydrophobicity loss, which is taken into account through the increase in the fraction of hydrophilic pores in GDL. Then PM based on Darcy equations allows simulating performance loss of PEMFC as a function of gas diffusion decay. This coupling shows that the loss of hydrophobic treatment increases flooding, decreases performance, and increases current density heterogeneities between inlet and outlet of the cell. Interestingly, this degradation is found to be highly non-linear, mainly because of the non-linear influence of the fraction of hydrophilic pores on gas diffusion (this is due to the existence of a percolation threshold associated with the hydrophilic pore sub-network) as well as the non-linear behaviour of electrochemistry with gas diffusion. This study also shows that the loss of hydrophobicity in a GDL is a very suitable candidate to explain performance loss rates that are classically observed during long-term tests. The proposed methodology may also help linking other local properties of components to fuel cell global performance.     

Das Zusammenspiel von Projektsteuerung und interorganisationalem Lernen und dessen Effekt auf kulturelle Unterschiede in globalen ISE-Outsourcing-Projekten mit mehreren Dienstleistern

Research into global, multisource, information systems development outsourcing projects has uncovered management challenges, including cultural differences on multiple levels. While control mechanisms and interorganizational learning have been shown to contribute to the mitigation of cultural differences in such projects, a gap persists regarding the effect of the interplay between these mechanisms. This study employs an exploratory single-case study design to analyze how formal and informal control mechanisms and interorganizational learning interact and thus contribute to the mitigation of cultural differences in global, multisource, information systems development outsourcing projects. With the key finding that the influence of informal controls and interorganizational learning on formal controls changes over time, this research helps expand the domain of control dynamics in global IS projects. This study also contributes to literature on ways to handle cultural differences in global, multisource, IS outsourcing projects.     

Fast Ray Tracing of Arbitrary Implicit Surfaces with Interval and Affine Arithmetic

Existing techniques for rendering arbitrary-form implicit surfaces are limited, either in performance, correctness or flexibility. Ray tracing algorithms employing interval arithmetic (IA) or affine arithmetic (AA) for root-funding are robust and general in the class of surfaces they support, but traditionally slow. Nonetheless, implemented efficiently using a stack-driven iterative algorithm and SIMD vector instructions, these methods can achieve interactive performance for common algebraic surfaces on the CPU. A similar algorithm can also be implemented stacklessly, allowing for efficient ray tracing on the GPU. This paper presents these algorithms, as well as an inclusion-preserving reduced affine arithmetic (RAA) for faster ray-surface intersection. Shader metaprogramming allows for immediate and automatic generation of symbolic expressions and their interval or affine extensions. Moreover, we are able to render even complex forms robustly, in real-time at high resolution .     

Speciation of Zn associated with diatoms using X-ray absorption spectroscopy

The long- and short-term interactions between zinc, an essential but also toxic element, and freshwater and marine diatoms are not well understood partly because of a lack of information on Zn speciation on the surface and inside the cells. In this work, interactions of aqueous Zn2+ with marine (Skeletonema costatum) and freshwater (Achnanthidium minutissimum, Navicula minima, and Melosira varians) diatoms were studied using conventional macroscopic techniques, while the local atomic structure of metal ions adsorbed on their surface or incorporated into the cells was characterized by in-situ Zn K-edge X-ray absorption fine structure (XAFS) spectroscopy on both intact and liophylized samples. At the cell surface for all diatom species studied, Zn was tetrahedrally coordinated with oxygen at approximately 2.00 +/- 0.02 A and monodentately bonded to one or two carboxylate groups; these results are consistent with the surface speciation model developed from macroscopic adsorption experiments. The atomic environment of Zn incorporated into freshwater diatoms during long-term growth in normal nutrient media was distinctly differentfrom that of adsorbed Zn: it was dominated by O (and/or N) neighbors in a tetrahedral arrangement at 1.97 +/- 0.02 A in the first atomic shell, with the presence of 1 phosphorus and 2 carbons in the Zn second shell. Contrasting speciation of intracellular zinc was revealed for the marine species Skeletonema costatum in which Zn was coordinated to 2 O/N atoms and 2 sulfur groups in the form of cysteine-histidine complexes and/or zinc thiolate clusters. These new structural data strongly suggest: (i) the predominant > R-COO- ligand binding of Zn atthe diatom surface; (ii) the nonspecific storage of Zn in the form of carboxylate/phosphate groups inside the cell of freshwater species; and (iii) the highly specific thiol-ligand coordination of intracellular zinc for marine S. costatum species.