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Free eutectic growth and its competition with single-phase growth in solidification of undercooled near-eutectic alloys are not yet fully understood. In this paper, the historical development of eutectic growth models was reviewed. The LZ model of free eutectic growth was evaluated using recent data of eutectic growth velocities in an undercooled Ni81.3Sn18.7 eutectic composition. An excellent agreement was achieved between the LZ model and the data. Crystal growth velocities in off-eutectic Ni83Sn17 and Ni80Sn20 compositions were measured using a high-speed camera technique. The present data of the off-eutectic compositions and the recent data of the eutectic composition were modeled using the LZ model and the LKT/BCT model of free dendritic growth. The modeling revealed that the competition between the free eutectic growth and the single-phase growth is controlled by the highest interface temperature criterion. A coupled zone of the α-Ni-Ni3Sn eutectic was calculated using this criterion. The coupled zone agrees well with studies of solidified structures of undercooled samples. 相似文献
83.
选用两种钢渣配料生产水泥熟料,在生产试验中优选出两种钢渣的最佳配料方案,分析了钢渣对熟料煅烧过程、物理性能和能耗的影响。结果表明,钢渣中铁含量20%时,钢渣可作为铁质校正原料,三率值最佳取值,KH为0.91~0.93,SM为2.5~2.7,IM为1.5~1.6;钢渣配料,熟料煅烧生产状况良好,能明显提高熟料的产量,提高熟料的强度,降低熟料烧成煤耗,且碱度大的钢渣,熟料C_3S含量较高,煤耗降低也较多。 相似文献
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Xi Du Liaolin Zhang Guoping Dong Kaniyarakkal Sharafudeen Jian Wen Dongdan Chen Qi Qian Jianrong Qiu 《Journal of the American Ceramic Society》2014,97(1):185-188
ZnO–TeO2–P2O5 glasses were prepared by melt‐quenching method. The color of the glass samples changed from colorless to pale red and dark red with increasing TeO2 content. Coloration mechanism and nonlinear optical properties of ZnO–TeO2–P2O5 glasses have been investigated. Raman spectra and transmission electron microscope measurements indicated the precipitation of ZnTe quantum dots in the glasses and ZnTe quantum dots are the origin of coloration. Z‐scan technique was used to examine the nonlinear optical properties of the glasses. The glass sample with 30 mol% TeO2 exhibits large third‐order nonlinear optical susceptibility of 10?11 esu. 相似文献
86.
To improve the paper properties of the poly(1,3,4‐oxadiazoles) (POD), the POD pulps were prepared by prechemical and mechanical methods to increase their polarity, contact area, and interaction. The fibrillated degree of the staple fibers was evaluated by the Canadian Standard Freeness and the specific surface area, while the surface free energy was calculated by the Micro–wilhelmy method. Meanwhile, the functional groups and compositions on the surface of the POD fibers were confirmed by the FTIR–ATR and the X‐ray photoelectron spectroscopy, and the surface morphological structure and the crystalline structure of the POD fibers were observed by the fiber analyzer, scanning electron microscope, and Wide‐angle X‐ray diffraction, respectively. It was found that the pronounced abrasive and distinctive grooves were formed on the surface of the POD fibers after prechemical and mechanical treatment. The surface free energy of POD fibers increased 8.41%, and the polar part increased by 32.10% after treatment. It was confirmed that the polar functional groups and fibril were formed after chemical and mechanical treatment, so the interaction of the POD fibers was highly enhanced, and as a result the apparent density, tensile strength, fold endurance, and tear strength of the paper formed by those treated fibers were all improved apparently. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39818. 相似文献
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Rui-xia Shi Jianrong Wang Jia Li Yan-sheng Yin 《International Journal of Refractory Metals and Hard Materials》2011,29(6):692-697
The oxidation behavior of hot-pressed Al2O3–TiC–Co composites prepared from cobalt-coated powders has been studied in air in the temperature range from 200 °C to 1000 °C for 25 h. The oxidation resistance of Al2O3–TiC–Co composites increases with the increase of sintering temperature at 800 °C and 1000 °C. The oxidation surfaces were studied by XRD and SEM. The oxidation kinetics of Al2O3–TiC–Co composites follows a rate that is faster than the parabolic-rate law at 800 °C and 1000 °C. The mechanism of oxidation has been analyzed using thermodynamic and kinetic considerations. 相似文献