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Qiushi Huang Chuanhua Li Yuankun Tu Yu Jiang Ping Mei Xuemin Yan 《Ceramics International》2021,47(2):1602-1608
In the development of fuel cells, it is the key to large-scale commercialization of fuel cells to rationally design and synthesize efficient and non-noble metals-based bifunctional electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). In this paper, spinel CoFe2O4/carbon nanotube composites (CoFe2O4/CNTs/FA) were synthesized by solvothermal and calcination method. XRD, TEM, XPS and BET characterizations indicate that the addition of complexing agent fumaric acid can improve the crystal growth kinetics and morphology of CoFe2O4/CNTs nanohybirds. The as-synthesized CoFe2O4/CNTs/FA pyrolyzed at 500 °C have an outstanding bifunctional catalytic activity for ORR and OER with the potential of 1.62V (vs. RHE) at a current density of 10 mA/cm2 and half-wave potential E1/2 = 0.808V (vs. RHE) in alkaline electrolyte, respectively. It is obviously better than unloaded CoFe2O4 nanoparticles and commercial CNTs. CoFe2O4/CNTs/FA also exhibit better methanol tolerance ability and durability than commercial Pt/C and RuO2 catalyst. This investigation broadens an idea of simple compounding of spinel with carbon-based materials to improve electrochemical properties. 相似文献
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Qiushi Xu Xiaoping Guan Raffaella Ocone Ning Yang 《American Institute of Chemical Engineers》2023,69(11):e18207
By applying digital image analysis on the bubble characteristics in a two dimensional wet-particle fluidized-bed, we report two-stage evolution of bubble characteristics with increasing liquid content. In the first stage, bubble number and uniformity of bubble fraction increase, while bubble average diameter and aspect ratio decrease. In the second stage, these characteristics shift toward an opposite direction. This two-stage evolution of bubble characteristics are analogous to that of reducing particle size in dry-particle fluidization, and the fluidizing properties of particles shifts from Geldart Group B to Group A and then to Group C. Furthermore, liquid addition causes a continuous decrease of bubble fraction and bubble flow rate. This is different from dry-particle fluidization, in which reducing particle size causes an increase trend. An explanation for this difference is that liquid addition increases the equivalent size of agglomerates in wet-particle fluidization, which is opposite to the effect of reducing particle size. 相似文献
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河道一维非恒定流数值模拟深化研究 总被引:1,自引:0,他引:1
传统的河道一维非恒定流数值计算一般采用特征线法和以Preissmann方法为代表的有限差分法.特征线法计算精度比较高,但受时间步长的限制,用于河道一维非恒定流计算时计算效率却不太高.而Preissmann方法相比特征线法计算效率有所提高,但在求解过程中特征量的守恒性却没有做出相应要求.为了兼顾数值计算的效率和特征量的守恒,建立了基于有限体积法的河道一维非恒定流数值计算方法,并分别选取淮河干流洪水和史灌河洪水进行了验证计算,验证计算成果表明所采用的方法特征量守恒性较好,洪峰水位计算值与实测值吻合也较好,可用于河道一维非恒定流计算. 相似文献
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Timing Zhang Weimin Zhao Qiushi Deng Wei Jiang Yonglin Wang Yong Wang Wenchun Jiang 《International Journal of Hydrogen Energy》2017,42(39):25102-25113
Hydrogen embrittlement (HE) of high-grade pipeline welded joint is a threat to hydrogen gas transport. In this research, slow strain rate tension (SSRT) tests in high-pressure hydrogen gas, combined with hydrogen permeation tests and microstructure analysis were conducted on X80 steel, intercritical heated-affected zone (ICHAZ), fine-grained heat-affected zone (FGHAZ) and coarse-grained heat-affected zone (CGHAZ). The change of HE susceptibility from high to low was CGHAZ, FGHAZ, ICHAZ, and base metal. Microstructure was the important factor influencing hydrogen permeation and susceptibility to HE. Susceptibility to HE was increased in the order of “fine-grained massive ferrite (MF) and acicular ferrite (AF)”, “fine-grained granular bainite (GB) and MF”, “coarse-grained GB and bainite ferrite (BF) embedded with martensite-austenite (M-A) constitute”. The fine-grained MF and AF in base metal with lower hydrogen diffusivity can impede the embrittlement behaviour, while the coarse-grained GB and BF with higher hydrogen diffusivity in CGHAZ increased its susceptibility to HE. 相似文献
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利用MOCVD在InP半绝缘衬底上生长N型InP,在KOH溶液中电化学腐蚀形成纳米多孔结构的。通过实验证实在半绝缘衬底上的InP纳米孔腐蚀具有可行性,并且得到了腐蚀质量较好、图形清晰、结构规整的纳米孔材料。在对其进行霍尔测试,得到了腐蚀孔对于n型InP材料表面电学性质的改变,实现了低掺杂浓度(10~(18)cm~(-3))的InP通过表面纳米孔腐蚀的方式提高载流子浓度,改善n型InP层表面电学性能。 相似文献