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41.
S.A. Yashnik Z.R. Ismagilov V.V. Kuznetsov V.V. Ushakov V.A. Rogov I.A. Ovsyannikova 《Catalysis Today》2006,117(4):525-535
A synergetic effect in the catalytic activity has been found after palladium introduction in Mn–Al–O systems. The magnitude of the synergetic effect depends on the types of the oxidic manganese species: oxide Mn3O4, spinel (Mn, Mg)[Mn, Al]2O4 or hexaaluminate (Mn, Mg)LaAl11O19. The synergetic effect of Pd and manganese-containing compounds is observed only if palladium is introduced to the low-temperature precursor of the manganese alumina spinel or manganese hexaaluminate. The synergetic effect is not observed when high-temperature samples with formed spinel or hexaaluminate phases are modified with Pd. 相似文献
42.
Cerium chromites, non-substituted and substituted with alkali-earth metals, are synthesized in the self-propagating high-temperature synthesis mode using solid interaction oxidizes. The characteristic temperatures and specifics of interaction between the components are determined for all systems considered. The structural and physicochemical parameters, including the spectroscopic characteristics of the synthesis products depending on the alkaline-earth metal substituent and the degree of substitution, are investigated. 相似文献
43.
Laurence J. Hardwick Matthias Hahn Michael Holzapfel Hilmi Buqa Petr Novák 《Electrochimica acta》2006,52(2):675-680
An initial Raman study on the effects of intercalation for aprotic electrolyte-based electrochemical double-layer capacitors (EDLCs) is reported. In situ Raman microscopy is employed in the study of the electrochemical intercalation of tetraethylammonium (Et4N+) and tetrafluoroborate (BF4−) into and out of microcrystalline graphite. During cyclic voltammetry experiments, the insertion of Et4N+ into graphite for the negative electrode occurs at an onset potential of +1.0 V versus Li/Li+. For the positive electrode, BF4− was shown to intercalate above +4.3 V versus Li/Li+. The characteristic G-band doublet peak (E2g2(i) (1578 cm−1) and E2g2(b) (1600 cm−1)) showed that various staged compounds were formed in both cases and the return of the single G-band (1578 cm−1) demonstrates that intercalation was fully reversible. The disappearance of the D-band (1329 cm−1) in intercalated graphite is also noted and when the intercalant is removed a more intense D-band reappears, indicating possible lattice damage. For cation intercalation, such irreversible changes of the graphite structure are confirmed by scanning electron microscopy (SEM). 相似文献
44.
45.
G. V. Kuznetsov G. Ya. Mamontov G. V. Taratushkina 《Combustion, Explosion, and Shock Waves》2004,40(1):70-76
The problem of ignition of a condensed substance by single particles heated up to high temperatures is solved within the framework of the twodimensional heattransfer model. Numerical studies are performed for typical materials: polyvinyl nitrate and carbonic particles. Regimes of ignition of a condensed substance by a single particle at relatively low temperatures are adequate in terms of the ignition delay to regimes of heating of the condensed substance by a gas flow without particles; at high temperatures, they correspond to regimes of heating by a metal plate with a fixed temperature. In a certain (rather narrow) range of particle temperatures, the use of the twodimensional heattransfer model yields ignitiondelay values substantially different from other regimes. 相似文献
46.
Mehdi Kaytoue Sergei O. Kuznetsov Juraj Macko Amedeo Napoli 《Annals of Mathematics and Artificial Intelligence》2014,70(1-2):55-79
Biclustering numerical data became a popular data-mining task at the beginning of 2000’s, especially for gene expression data analysis and recommender systems. A bicluster reflects a strong association between a subset of objects and a subset of attributes in a numerical object/attribute data-table. So-called biclusters of similar values can be thought as maximal sub-tables with close values. Only few methods address a complete, correct and non-redundant enumeration of such patterns, a well-known intractable problem, while no formal framework exists. We introduce important links between biclustering and Formal Concept Analysis (FCA). Indeed, FCA is known to be, among others, a methodology for biclustering binary data. Handling numerical data is not direct, and we argue that Triadic Concept Analysis (TCA), the extension of FCA to ternary relations, provides a powerful mathematical and algorithmic framework for biclustering numerical data. We discuss hence both theoretical and computational aspects on biclustering numerical data with triadic concept analysis. These results also scale to n-dimensional numerical datasets. 相似文献
47.
An s – t-network with highly reliable edges with repair and variable external load is considered. A fast simulation method is proposed to evaluate the probability of functional failure when the real capacity of the network is less than the required capacity. It is proved that under some conditions the estimate has a bounded relative error as edges reliability increases. The numerical example illustrates the efficiency of the method. 相似文献
48.
Development of Monolithic Catalysts with Low Noble Metal Content for Diesel Vehicle Emission Control
S.A. Yashnik V.V. Kuznetsov Z.R. Ismagilov V.V. Ushakov N.M. Danchenko S.P. Denisov 《Topics in Catalysis》2004,(1):293-298
Monolith washcoated catalysts with potential for diesel emission control have been developed. Two types of catalysts have been prepared for further study: (1) MnO
x
supported on granulated -Al2O3, (2) MnO
x
supported on cordierite monolith washcoated with -Al2O3. Both catalysts have been calcined at 500 and 900 °C and subsequently modified by doping with 0.1–1.0 wt% of Pt or Pd. The influence of the concentration of both manganese oxide (0–10 wt%) and noble metals Pt and Pd in the range 0–1.0 wt% on the catalytic activity in methane oxidation has been studied. Comparison of the catalytic activity of MnO
x
/Al2O3 and MnO
x
+ Pt(Pd)/Al2O3 with that of a standard 1 wt%Pt/Al2O3 catalyst shows the existence of a synergetic effect. This effect is more pronounced for the samples calcined at 900 °C. The developed monolithic catalysts MnO
x
+ Pt(Pd)/Al2O3 demonstrate higher activity and thermal stability (up to 900 °C) compared to the commercial monolithic catalyst (TWC's). 相似文献
49.
Polypropylene (PP) nanocomposites were prepared by melt intercalation in an intermeshing corotating twin‐screw extruder. The effect of molecular weight of PP‐MA (maleic anhydride‐ modified polypropylene) on clay dispersion and mechanical properties of nanocomposites was investigated. After injection molding, the tensile properties and impact strength were measured. The best overall mechanical properties were found for composites containing PP‐MA having the highest molecular weight. The basal spacing of clay in the composites was measured by X‐ray diffraction (XRD). Nanoscale morphology of the samples was observed by transmission electron microscopy (TEM). The crystallization kinetics was measured by differential scanning calorimetry (DSC) and optical microscopy at a fixed crystallization temperature. Increasing the clay content in PP‐ MA330k/clay, a well‐dispersed two‐component system, caused the impact strength to decrease while the crystallization kinetics and the spherulite size remained almost the same. On the other hand, PP/PP‐MA330k/clay, an intercalated three‐component system containing some dispersed clay as well as the clay tactoids, showed a much smaller size of spherulites and a slight increase in impact strength with increasing the clay content. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1562–1570, 2002 相似文献
50.
Conclusions -- Some basic special features in devising a panel-free technology in the manufacture of synthetic fibres and yarns have been examined.-- Some advantages of an approach based on parallel designing of the technological process and the control system over the traditional approach have been shown.-- The new methodical approach has found application in developing automation systems at a number of synthetic fibre and yarn manufacturing plants.Translated from Khimicheskie Volokna, No. 5, pp. 47–48, September–October, 1990. 相似文献