Phenol Removal through Chemical Oxidation using Fenton Reagent

In this study, phenol, aromatic, and non‐biodegradable organic matter were investigated and found to be removed from the model solution through chemical oxidation using Fenton reagent. The effects of the initial phenol concentration, hydrogen peroxide, and ferrous sulfate concentrations on the removal efficiency were investigated. Performance of the chemical oxidation process was monitored with phenol and COD (Chemical Oxygen Demand) analyses. In the experimental studies, phenol removal of over 98 % and COD removal of nearly 70 % were achieved. The optimum conditions for Fenton reaction both for initial phenol concentrations of 200 and 500 mg/L were found at a ratio [Fe²⁺]/[H₂O₂] (mol/mol) equal to 0.11. According to the results, chemical oxidation using Fenton reagent was found to be too effective, especially for phenol removal. However, this method has limited removal efficiency for COD.     

Investigation of solidification cracking susceptibility during laser beam welding using an in-situ observation technique

In recent years, laser beam welding has found wide applications in many industrial fields. Solidification cracks are one of the most frequently encountered welding defects that hinder obtaining a safe weld joint. Decades of research have shown that one of the main causes of such cracks are the strain and the strain rate. Obtaining meaningful measurements of these strains has always been a major challenge for scientists, because of the specific environment of the measurement range and the many obstacles, as well as the high temperature and the plasma plume. In this study, a special experimental setup with a high-speed camera was employed to measure the strain during the welding process. The hot cracking susceptibility was investigated for 1.4301 stainless steel, and the critical strain required for solidification crack formation was locally and globally determined.     

Exploring the dynamics of the Turkish construction industry using input–output analysis

Construction is commonly regarded as an important industry in economic policy making owing to its strong interactions with other sectors in the economy. Using six national input–output (IO) tables compiled to date and economic data for the period between 1969 and 2006, the behaviour of the Turkish construction sector and its relationships to investment, income and to other sectors in the economy are examined. Analysis reveals that the construction industry is losing its propulsive role and that it tends to exaggerate the fluctuations of the economy. The examination of lead and lag times between changes in GNP, construction activity and investments show that public sector spending cuts, in particular, have significant effects on the amplitude and the timing of slumps of the industry. The analysis of linkage indicators indicates that for the whole period under consideration the construction industry has high linkages with only one other industry. Thus the ‘leading’ role it plays in the economy is questioned.     

Creating a high-quality wool-oriented Turkish merino herd and investigation of mechanical and dyeability properties of fabrics produced from Turkish merino in comparison with Australian merino

Today, the need for quality wool suitable for worsted fabric production in the world is mainly met by Australian merino wool. In Turkey, which has a significant sheep population, in addition to domestic breeds, approximately 10% of the total sheep population (around four million head) is composed of merino cross breeds. However, the fleece quality is far from meeting Australian merino wool standards. Therefore, the aim of this study is to ensure a merino herd with high-quality wool in Turkey. For this aim, by carrying out field studies in the Thrace region of Turkey where Turkish Merino sheep are widely bred, sheep with fleece that can meet the demands of the worsted industry were determined. As a result of field studies in which thousands of sheep were examined, it was determined that 43 female and 10 male sheep had fleece that would meet these standards. Then the breeders of the sheep, which had quality fleece, were persuaded and these sheep were purchased, and “Turkey's wool-oriented Turkish (Karacabey) Merino Herd” consisting of 30 sheep and three rams was formed in the farm of Tekirdağ Namık Kemal University. In the second part of this study, a 100% wool fabric produced by using Australian merino was taken as a reference and it was aimed to produce the same fabric from Turkish merino wool. For this aim, the wool-oriented Turkish Merino herd, which was bred at the university farm for 1 year, was shorn in May 2022. Then, Turkish and Australian merino wools were first converted into worsted yarn and then into woven fabric. The results of mechanical (tensile strength, pilling, abrasion resistance, felting shrinkage, Hofmann dimensional change, bending stiffness) and dyeability (dye-uptake, CIE L*a*b* and colour yield (K/S) values; washing, rubbing and light fastness values) properties of fabrics produced from Turkish and Australian merino wool is presented.     

Reliability analysis of the complex mode indicator function and Hilbert Transform techniques for operational modal analysis

This study presents application of the CMIF and the Hilbert Transform techniques onto simulated response data obtained using a numerical model of a typical school building from Turkey. White noise is added to the data in order to achieve a noise to signal ratio of 5%. 100 Monte Carlo analysis sequences are carried out and the modal parameters (the frequencies, the mode shapes and the damping ratios) are identified at each Monte Carlo run for both techniques. The results are compared with the identifications obtained from the simulated data using stochastic subspace based system identification technique. The overall results of the study show that the mode shapes are clearly identified the best by using the CMIF technique. The damping ratios are estimated better by using the stochastic subspace based system identification technique whereas the frequencies are best determined by the CMIF. The results also show that both the CMIF and the Hilbert Transform techniques are sensitive to the type of window used as well as the averaging and the decimation process. It is apparent that the CMIF technique is as robust as the frequently used stochastic subspace based system identification technique and can be confidently used for modal parameter estimation of stiff low to mid rise reinforced concrete structures.     

Automation of the stabilization diagrams for subspace based system identification

For the continuous real-time monitoring of structures, the realization of a fully automatic real time system identification without any human intervention is the most crucial step. In this study, a new technique for the automation of the stability diagrams is developed that uses the modal phase collinearity (MPC) in order to quantify the spatial consistency of the identification results. In the new technique, the stabilization diagram is modeled as a histogram composed of overlapping bins. New strategies for the multiple occurrence of poles in the neighboring bins and double poles within a bin are developed. A new cluster validity index is proposed which can solve the problem caused by the scale of measurements and which can be directly calculated from non-normalized data. The threshold limits are defined for the proposed index. The results of the study show that the automation of the pole selection process from the stabilization diagrams is successfully realized. It is also shown that for local modes, the MPC value will be substantially smaller as compared to the global modes and can be used as a quick, efficient and powerful measure of global versus local response behavior.     

Ectropy of diversity measures for populations in Euclidean space

Measures to evaluate the diversity of a set of points (population) in Euclidean space play an important role in a variety of areas of science and engineering. Well-known measures are often used without a clear insight into their quality and many of them do not appropriately penalize populations with a few distant groups of collocated or closely located points. To the best of our knowledge, there is a lack of rigorous criteria to compare diversity measures and help select an appropriate one. In this work we define a mathematical notion of ectropy for classifying diversity measures in terms of the extent to which they tend to penalize point collocation, we investigate the advantages and disadvantages of several known measures and we propose some novel ones that exhibit a good ectropic behavior. In particular, we introduce a quasi-entropy measure based on a geometric covering problem, three measures based on discrepancy from uniform distribution and one based on Euclidean minimum spanning trees. All considered measures are tested and compared on a large set of random and structured populations. Special attention is also devoted to the complexity of computing the measures. Most of the novel measures compare favorably with the classical ones in terms of ectropy. The measure based on Euclidean minimum spanning trees turns out to be the most promising one in terms of the tradeoff between the ectropic behavior and the computational complexity.     

Removal of Nitrate from Aqueous Solutions by Electrodialysis

In this work the removal of the nitrate from water was carried out by electrodialysis. In the experiments the effect of the applied voltage, pH value, initial nitrate concentration and duration of treatment on the removal rate of nitrate have been investigated. The results obtained from experiments have indicated that nitrate can be removed effectively applying electrodialysis.